FR2935139B1 - Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage - Google Patents

Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage

Info

Publication number
FR2935139B1
FR2935139B1 FR0804642A FR0804642A FR2935139B1 FR 2935139 B1 FR2935139 B1 FR 2935139B1 FR 0804642 A FR0804642 A FR 0804642A FR 0804642 A FR0804642 A FR 0804642A FR 2935139 B1 FR2935139 B1 FR 2935139B1
Authority
FR
France
Prior art keywords
hydrocracking
tungsten
type heteropolyanion
keggin
keggin lacunar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0804642A
Other languages
English (en)
French (fr)
Other versions
FR2935139A1 (fr
Inventor
Audrey Bonduelle
Fabrice Bertoncini
Tayed Karima Ben
Carole Lamonier
Michel Fournier
Edmond Payen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0804642A priority Critical patent/FR2935139B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to EP09784313.0A priority patent/EP2315721B1/fr
Priority to BRPI0917285-8A priority patent/BRPI0917285B1/pt
Priority to PCT/FR2009/000941 priority patent/WO2010020714A1/fr
Priority to CA2733579A priority patent/CA2733579C/fr
Priority to JP2011523433A priority patent/JP5647122B2/ja
Priority to KR1020117006081A priority patent/KR101583105B1/ko
Priority to RU2011110473/05A priority patent/RU2509729C2/ru
Priority to US13/059,254 priority patent/US8633128B2/en
Publication of FR2935139A1 publication Critical patent/FR2935139A1/fr
Priority to ZA2011/00868A priority patent/ZA201100868B/en
Application granted granted Critical
Publication of FR2935139B1 publication Critical patent/FR2935139B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00—Compounds of tungsten
    • C01G41/006—Compounds containing tungsten, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G41/00—Compounds of tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0213—Preparation of the impregnating solution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
FR0804642A 2008-08-19 2008-08-19 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage Expired - Fee Related FR2935139B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR0804642A FR2935139B1 (fr) 2008-08-19 2008-08-19 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage
US13/059,254 US8633128B2 (en) 2008-08-19 2009-07-29 Lacunary Keggin type heteropolyanion based on tungsten for hydrocracking
PCT/FR2009/000941 WO2010020714A1 (fr) 2008-08-19 2009-07-29 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage
CA2733579A CA2733579C (fr) 2008-08-19 2009-07-29 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage
JP2011523433A JP5647122B2 (ja) 2008-08-19 2009-07-29 水素化分解のためのタングステンをベースとする空隙ケギンタイプのヘテロポリアニオン
KR1020117006081A KR101583105B1 (ko) 2008-08-19 2009-07-29 수소화분해를 위한 텅스텐기반 베이컨시-케긴-타입 헤테로폴리음이온
EP09784313.0A EP2315721B1 (fr) 2008-08-19 2009-07-29 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage
BRPI0917285-8A BRPI0917285B1 (pt) 2008-08-19 2009-07-29 Heteropoliânion de tipo keggin lacunar à base de tungstênio para hidrocraqueamento, seu processo de preparação e sua utilização, bem como catalisador
RU2011110473/05A RU2509729C2 (ru) 2008-08-19 2009-07-29 Лакунарный гетерополианион структуры кеггина на основе вольфрама для гидрокрекинга
ZA2011/00868A ZA201100868B (en) 2008-08-19 2011-02-02 Tungsten-based vacancy-keggin-type heteropolyanion for hydrocracking

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0804642A FR2935139B1 (fr) 2008-08-19 2008-08-19 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage

Publications (2)

Publication Number Publication Date
FR2935139A1 FR2935139A1 (fr) 2010-02-26
FR2935139B1 true FR2935139B1 (fr) 2011-06-10

Family

ID=40566151

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0804642A Expired - Fee Related FR2935139B1 (fr) 2008-08-19 2008-08-19 Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage

Country Status (10)

Country Link
US (1) US8633128B2 (enExample)
EP (1) EP2315721B1 (enExample)
JP (1) JP5647122B2 (enExample)
KR (1) KR101583105B1 (enExample)
BR (1) BRPI0917285B1 (enExample)
CA (1) CA2733579C (enExample)
FR (1) FR2935139B1 (enExample)
RU (1) RU2509729C2 (enExample)
WO (1) WO2010020714A1 (enExample)
ZA (1) ZA201100868B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2935139B1 (fr) * 2008-08-19 2011-06-10 Inst Francais Du Petrole Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage
FR2969514B1 (fr) * 2010-12-22 2013-04-12 IFP Energies Nouvelles Procede de preparation d'un materiau spherique a porosite hierarchisee comprenant des particules metalliques piegees dans une matrice a base de silicium
FR2969641B1 (fr) * 2010-12-22 2012-12-28 IFP Energies Nouvelles Procede de production de base carburant a partir de charge issue de la biomasse utilisant un catalyseur a base d'heteropolyanions pieges dans un support oxyde mesostructure
FR2969645B1 (fr) 2010-12-22 2012-12-28 IFP Energies Nouvelles Procede d'hydrodesulfuration de coupes gazoles utilisant un catalyseur a base d'heteropolyanions pieges dans un support silicique mesostructure
FR2969509B1 (fr) 2010-12-22 2012-12-28 IFP Energies Nouvelles Materiau spherique a base d'heteropolyanions pieges dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage
FR2969511B1 (fr) * 2010-12-22 2012-12-28 IFP Energies Nouvelles Materiau spherique comprenant des nanoparticules metalliques piegees dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage
FR2969647B1 (fr) * 2010-12-22 2012-12-21 IFP Energies Nouvelles Procede d'hydrocraquage de coupes hydrocarbonees utilisant un catalyseur a base d'heteropolyanions pieges dans un support oxyde mesostructure
US9340733B2 (en) * 2010-12-22 2016-05-17 Centre National De La Recherche Scientifique Process for Hydrodesulphuration of gasoil cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support
FR2969513B1 (fr) * 2010-12-22 2013-04-12 IFP Energies Nouvelles Procede de preparation d'un materiau spherique a porosite hierarchisee comprenant des particules metalliques piegees dans une matrice mesostructuree
FR2984911B1 (fr) * 2011-12-22 2014-08-29 IFP Energies Nouvelles Procede de conversion de charges paraffiniques issues de la biomasse en bases distillats moyens mettant en oeuvre au moins un catalyseur a base de zeolithe izm-2
FR2984760B1 (fr) 2011-12-22 2014-01-17 IFP Energies Nouvelles Catalyseur utilisable en hydroconversion comprenant au moins une zeolithe et des metaux des groupes viii et vib et preparation du catalyseur
FR2984759B1 (fr) * 2011-12-22 2013-12-20 IFP Energies Nouvelles Catalyseur comprenant au moins une zeolithe nu-86, au moins une zeolithe usy et une matrice minerale poreuse et procede d'hydroconversion de charges hydrocarbonees utilisant ce catalyseur
FR3074699B1 (fr) 2017-12-13 2019-12-20 IFP Energies Nouvelles Procede d'hydroconversion de charge hydrocarbonee lourde en reacteur hybride

Family Cites Families (15)

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Publication number Priority date Publication date Assignee Title
US2547380A (en) * 1945-10-01 1951-04-03 Union Oil Co Catalyst for hydrocarbon conversion
US2608534A (en) * 1949-04-18 1952-08-26 Union Oil Co Heteropoly acids or salts thereof as catalysts
CA2056511C (en) * 1990-12-24 1999-06-01 Clyde Lee Aldridge Supported hydrogenation and hydrotreating catalysts and process
US5319119A (en) * 1991-03-15 1994-06-07 Asahi Kasei Kogyo Kabushiki Kaisha Oleophilic molybdenum compound for use in hydroconversion of a hydrocarbon and a method for producing the same
JPH09286757A (ja) * 1996-04-19 1997-11-04 Mitsubishi Chem Corp 芳香族カルボン酸の製造方法
FR2749778B1 (fr) * 1996-06-13 1998-08-14 Elf Antar France Procede de preparation de catalyseurs d'hydrotraitement
FR2764211B1 (fr) * 1997-06-09 1999-10-08 Elf Antar France Procede de preparation de catalyseurs d'hydrotraitement
US6043184A (en) * 1998-01-05 2000-03-28 Sunoco, Inc. (R&M) Heteropoly acids supported on polyoxometallate salts and their preparation
US6387841B1 (en) * 1999-08-23 2002-05-14 Rohm And Haas Company Polyoxometallate supported catalysts
JP2002205964A (ja) * 2000-11-10 2002-07-23 Nippon Shokubai Co Ltd 芳香族カルボニル化合物の製造方法
JP2002167359A (ja) * 2000-11-30 2002-06-11 Teijin Ltd 芳香族カーボネートの製造方法
JP4259873B2 (ja) * 2001-03-12 2009-04-30 株式会社日本触媒 エポキシ化合物を製造するための触媒及びそれを使用するエポキシ化合物の製造方法
JP4030317B2 (ja) * 2001-03-12 2008-01-09 株式会社日本触媒 エポキシ化合物を製造するための触媒及びそれを使用するエポキシ化合物の製造方法
US6841668B2 (en) * 2002-04-11 2005-01-11 Ciba Specialty Chemicals Corporation Polyoxometalate catalysts for the preparation of sterically hindered N-substituted aryloxyamines
FR2935139B1 (fr) * 2008-08-19 2011-06-10 Inst Francais Du Petrole Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage

Also Published As

Publication number Publication date
CA2733579C (fr) 2014-12-23
EP2315721B1 (fr) 2013-04-10
ZA201100868B (en) 2011-09-28
KR101583105B1 (ko) 2016-01-07
BRPI0917285B1 (pt) 2020-01-07
BRPI0917285A2 (pt) 2015-11-10
EP2315721A1 (fr) 2011-05-04
US8633128B2 (en) 2014-01-21
RU2011110473A (ru) 2012-09-27
CA2733579A1 (fr) 2010-02-25
JP2012500174A (ja) 2012-01-05
WO2010020714A1 (fr) 2010-02-25
US20110230691A1 (en) 2011-09-22
FR2935139A1 (fr) 2010-02-26
KR20110050519A (ko) 2011-05-13
JP5647122B2 (ja) 2014-12-24
RU2509729C2 (ru) 2014-03-20

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