FR2877347A1 - Polyolefines riches en structure syndiotactique et procede pour leur production - Google Patents

Info

Publication number

FR2877347A1

FR2877347A1 FR0510606A FR0510606A FR2877347A1 FR 2877347 A1 FR2877347 A1 FR 2877347A1 FR 0510606 A FR0510606 A FR 0510606A FR 0510606 A FR0510606 A FR 0510606A FR 2877347 A1 FR2877347 A1 FR 2877347A1

Authority

FR

France

Prior art keywords

polymer

weight

rich

less

polyolefin

Prior art date

2004-10-28

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Withdrawn

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• 229920000098 polyolefin Polymers 0.000 title claims abstract description 220
• 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
• 238000000034 method Methods 0.000 title claims description 104
• 230000008569 process Effects 0.000 title claims description 49
• 239000000203 mixture Substances 0.000 claims abstract description 407
• 229920000642 polymer Polymers 0.000 claims abstract description 400
• 239000004711 α-olefin Substances 0.000 claims abstract description 72
• 230000004927 fusion Effects 0.000 claims abstract description 51
• -1 polypropylene Polymers 0.000 claims description 303
• 239000000853 adhesive Substances 0.000 claims description 274
• 230000001070 adhesive effect Effects 0.000 claims description 274
• 229920001155 polypropylene Polymers 0.000 claims description 164
• 239000004743 Polypropylene Substances 0.000 claims description 163
• 239000000654 additive Substances 0.000 claims description 114
• 239000001993 wax Substances 0.000 claims description 101
• 239000000463 material Substances 0.000 claims description 93
• 125000000524 functional group Chemical group 0.000 claims description 89
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 83
• 239000000835 fiber Substances 0.000 claims description 75
• 239000002904 solvent Substances 0.000 claims description 73
• 230000000996 additive effect Effects 0.000 claims description 70
• 229920005989 resin Polymers 0.000 claims description 70
• 239000011347 resin Substances 0.000 claims description 70
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 66
• 239000000047 product Substances 0.000 claims description 66
• 229920001577 copolymer Polymers 0.000 claims description 63
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 63
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 59
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 52
• 239000000178 monomer Substances 0.000 claims description 52
• 238000007306 functionalization reaction Methods 0.000 claims description 51
• 239000004698 Polyethylene Substances 0.000 claims description 50
• 229920000573 polyethylene Polymers 0.000 claims description 50
• 239000003054 catalyst Substances 0.000 claims description 49
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 49
• 239000005977 Ethylene Substances 0.000 claims description 48
• 229920001971 elastomer Polymers 0.000 claims description 48
• 238000002844 melting Methods 0.000 claims description 37
• 230000008018 melting Effects 0.000 claims description 37
• 229920002959 polymer blend Polymers 0.000 claims description 37
• 239000000945 filler Substances 0.000 claims description 36
• 239000000565 sealant Substances 0.000 claims description 34
• 239000003795 chemical substances by application Substances 0.000 claims description 31
• 239000002023 wood Substances 0.000 claims description 31
• 239000003921 oil Substances 0.000 claims description 30
• 239000004836 Glue Stick Substances 0.000 claims description 29
• 150000002148 esters Chemical class 0.000 claims description 29
• 239000002253 acid Substances 0.000 claims description 28
• 125000001931 aliphatic group Chemical group 0.000 claims description 28
• 238000002156 mixing Methods 0.000 claims description 28
• VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 26
• 239000000806 elastomer Substances 0.000 claims description 26
• 238000004806 packaging method and process Methods 0.000 claims description 26
• 229920005604 random copolymer Polymers 0.000 claims description 25
• 239000003999 initiator Substances 0.000 claims description 24
• 238000002425 crystallisation Methods 0.000 claims description 23
• 230000008025 crystallization Effects 0.000 claims description 23
• 239000003963 antioxidant agent Substances 0.000 claims description 22
• 239000004927 clay Substances 0.000 claims description 22
• 238000009826 distribution Methods 0.000 claims description 22
• 239000004014 plasticizer Substances 0.000 claims description 22
• 239000005060 rubber Substances 0.000 claims description 22
• 150000001875 compounds Chemical class 0.000 claims description 21
• 239000000049 pigment Substances 0.000 claims description 20
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 19
• 239000000155 melt Substances 0.000 claims description 19
• 239000008096 xylene Substances 0.000 claims description 19
• 239000004831 Hot glue Substances 0.000 claims description 18
• 239000012190 activator Substances 0.000 claims description 18
• 150000008064 anhydrides Chemical class 0.000 claims description 18
• 125000003118 aryl group Chemical group 0.000 claims description 18
• 239000003431 cross linking reagent Substances 0.000 claims description 18
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
• XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 17
• 239000004594 Masterbatch (MB) Substances 0.000 claims description 17
• 229920001519 homopolymer Polymers 0.000 claims description 17
• 229920000915 polyvinyl chloride Polymers 0.000 claims description 17
• 239000004800 polyvinyl chloride Substances 0.000 claims description 17
• 235000007586 terpenes Nutrition 0.000 claims description 17
• 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 16
• 150000003505 terpenes Chemical class 0.000 claims description 16
• 239000002318 adhesion promoter Substances 0.000 claims description 15
• 229920013639 polyalphaolefin Polymers 0.000 claims description 15
• LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 14
• 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 13
• 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 13
• 150000001412 amines Chemical class 0.000 claims description 13
• 229910052799 carbon Inorganic materials 0.000 claims description 13
• 239000002671 adjuvant Substances 0.000 claims description 12
• GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 12
• 125000005842 heteroatom Chemical group 0.000 claims description 12
• 229910052901 montmorillonite Inorganic materials 0.000 claims description 12
• 239000004094 surface-active agent Substances 0.000 claims description 12
• 239000002981 blocking agent Substances 0.000 claims description 11
• 229930195733 hydrocarbon Natural products 0.000 claims description 11
• 150000002430 hydrocarbons Chemical class 0.000 claims description 11
• 230000003472 neutralizing effect Effects 0.000 claims description 11
• 239000002667 nucleating agent Substances 0.000 claims description 11
• 229920001083 polybutene Polymers 0.000 claims description 11
• 229920000139 polyethylene terephthalate Polymers 0.000 claims description 11
• 239000004215 Carbon black (E152) Substances 0.000 claims description 10
• 230000003078 antioxidant effect Effects 0.000 claims description 10
• 229920000515 polycarbonate Polymers 0.000 claims description 10
• 239000004417 polycarbonate Substances 0.000 claims description 10
• 239000005020 polyethylene terephthalate Substances 0.000 claims description 10
• 238000002360 preparation method Methods 0.000 claims description 10
• 239000003381 stabilizer Substances 0.000 claims description 10
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
• 239000006057 Non-nutritive feed additive Substances 0.000 claims description 9
• 239000004952 Polyamide Substances 0.000 claims description 9
• 230000015572 biosynthetic process Effects 0.000 claims description 9
• IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 9
• 230000003197 catalytic effect Effects 0.000 claims description 9
• 239000000314 lubricant Substances 0.000 claims description 9
• 229920002647 polyamide Polymers 0.000 claims description 9
• 150000003839 salts Chemical class 0.000 claims description 9
• 229920002554 vinyl polymer Polymers 0.000 claims description 9
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
• 239000012963 UV stabilizer Substances 0.000 claims description 8
• 229920006271 aliphatic hydrocarbon resin Polymers 0.000 claims description 8
• 239000012141 concentrate Substances 0.000 claims description 8
• 150000001451 organic peroxides Chemical class 0.000 claims description 8
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
• XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 7
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 7
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 7
• 239000004793 Polystyrene Substances 0.000 claims description 7
• 150000007513 acids Chemical class 0.000 claims description 7
• 150000001408 amides Chemical class 0.000 claims description 7
• 239000003086 colorant Substances 0.000 claims description 7
• 229910052760 oxygen Inorganic materials 0.000 claims description 7
• 229920002223 polystyrene Polymers 0.000 claims description 7
• AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 claims description 6
• 229920002943 EPDM rubber Polymers 0.000 claims description 6
• 229920002367 Polyisobutene Polymers 0.000 claims description 6
• 150000001491 aromatic compounds Chemical class 0.000 claims description 6
• 239000004203 carnauba wax Substances 0.000 claims description 6
• 235000013869 carnauba wax Nutrition 0.000 claims description 6
• 239000005038 ethylene vinyl acetate Substances 0.000 claims description 6
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
• 239000010445 mica Substances 0.000 claims description 6
• 229910052618 mica group Inorganic materials 0.000 claims description 6
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
• 229920006267 polyester film Polymers 0.000 claims description 6
• 150000003097 polyterpenes Chemical class 0.000 claims description 6
• 239000002562 thickening agent Substances 0.000 claims description 6
• KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 claims description 5
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
• VYWRBUBXZALATG-UHFFFAOYSA-N 2-hydroxyoctadecanamide Chemical compound CCCCCCCCCCCCCCCCC(O)C(N)=O VYWRBUBXZALATG-UHFFFAOYSA-N 0.000 claims description 5
• DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 5
• 239000003623 enhancer Substances 0.000 claims description 5
• 229910052698 phosphorus Inorganic materials 0.000 claims description 5
• 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
• 239000003755 preservative agent Substances 0.000 claims description 5
• 239000006254 rheological additive Substances 0.000 claims description 5
• 229910052710 silicon Inorganic materials 0.000 claims description 5
• 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 5
• 239000003784 tall oil Substances 0.000 claims description 5
• OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 4
• XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 4
• KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 claims description 4
• RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 4
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
• 239000004909 Moisturizer Substances 0.000 claims description 4
• OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
• KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 4
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 4
• 150000008065 acid anhydrides Chemical class 0.000 claims description 4
• 239000002199 base oil Substances 0.000 claims description 4
• 229910052796 boron Inorganic materials 0.000 claims description 4
• 229910052794 bromium Inorganic materials 0.000 claims description 4
• 150000003857 carboxamides Chemical class 0.000 claims description 4
• 239000004359 castor oil Substances 0.000 claims description 4
• 235000019438 castor oil Nutrition 0.000 claims description 4
• 229910052801 chlorine Inorganic materials 0.000 claims description 4
• GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 4
• NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
• 239000012467 final product Substances 0.000 claims description 4
• 229910052731 fluorine Inorganic materials 0.000 claims description 4
• ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
• 229910001701 hydrotalcite Inorganic materials 0.000 claims description 4
• 229960001545 hydrotalcite Drugs 0.000 claims description 4
• 229910052740 iodine Inorganic materials 0.000 claims description 4
• 229920001580 isotactic polymer Polymers 0.000 claims description 4
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
• 239000004200 microcrystalline wax Substances 0.000 claims description 4
• 235000019808 microcrystalline wax Nutrition 0.000 claims description 4
• 230000001333 moisturizer Effects 0.000 claims description 4
• 229910052757 nitrogen Inorganic materials 0.000 claims description 4
• 150000007524 organic acids Chemical class 0.000 claims description 4
• 150000002895 organic esters Chemical class 0.000 claims description 4
• 229920005629 polypropylene homopolymer Polymers 0.000 claims description 4
• 229910052717 sulfur Inorganic materials 0.000 claims description 4
• CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 4
• KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 4
• DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims description 3
• LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 claims description 3
• KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 3
• MFGALGYVFGDXIX-UHFFFAOYSA-N 2,3-Dimethylmaleic anhydride Chemical compound CC1=C(C)C(=O)OC1=O MFGALGYVFGDXIX-UHFFFAOYSA-N 0.000 claims description 3
• WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 claims description 3
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
• CXJAFLQWMOMYOW-UHFFFAOYSA-N 3-chlorofuran-2,5-dione Chemical compound ClC1=CC(=O)OC1=O CXJAFLQWMOMYOW-UHFFFAOYSA-N 0.000 claims description 3
• OEMSKMUAMXLNKL-UHFFFAOYSA-N 5-methyl-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C)=CCC2C(=O)OC(=O)C12 OEMSKMUAMXLNKL-UHFFFAOYSA-N 0.000 claims description 3
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
• 235000014466 Douglas bleu Nutrition 0.000 claims description 3
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
• IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 3
• JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
• 229930182556 Polyacetal Natural products 0.000 claims description 3
• 240000001416 Pseudotsuga menziesii Species 0.000 claims description 3
• 235000005386 Pseudotsuga menziesii var menziesii Nutrition 0.000 claims description 3
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 3
• 150000001298 alcohols Chemical class 0.000 claims description 3
• HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 3
• 235000013871 bee wax Nutrition 0.000 claims description 3
• 239000012166 beeswax Substances 0.000 claims description 3
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
• 239000011575 calcium Substances 0.000 claims description 3
• 229910052791 calcium Inorganic materials 0.000 claims description 3
• VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims description 3
• 239000004204 candelilla wax Substances 0.000 claims description 3
• 235000013868 candelilla wax Nutrition 0.000 claims description 3
• 229940073532 candelilla wax Drugs 0.000 claims description 3
• 239000012185 ceresin wax Substances 0.000 claims description 3
• HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 3
• 229940018557 citraconic acid Drugs 0.000 claims description 3
• 229920003020 cross-linked polyethylene Polymers 0.000 claims description 3
• 239000004703 cross-linked polyethylene Substances 0.000 claims description 3
• LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 3
• 150000005690 diesters Chemical class 0.000 claims description 3
• FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
• WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 claims description 3
• 238000005194 fractionation Methods 0.000 claims description 3
• 239000001530 fumaric acid Substances 0.000 claims description 3
• 230000009477 glass transition Effects 0.000 claims description 3
• 229910052621 halloysite Inorganic materials 0.000 claims description 3
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