FR2855517B1 - Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium - Google Patents

Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium

Info

Publication number
FR2855517B1
FR2855517B1 FR0306336A FR0306336A FR2855517B1 FR 2855517 B1 FR2855517 B1 FR 2855517B1 FR 0306336 A FR0306336 A FR 0306336A FR 0306336 A FR0306336 A FR 0306336A FR 2855517 B1 FR2855517 B1 FR 2855517B1
Authority
FR
France
Prior art keywords
titanium
aluminum
animal oils
heterogeneous catalysts
catalysts based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0306336A
Other languages
English (en)
Other versions
FR2855517A1 (fr
Inventor
Thierry Lacome
Gerard Hillion
Bruno Delfort
Renaud Revel
Serge Leporq
Gustave Acakpo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0306336A priority Critical patent/FR2855517B1/fr
Priority to EP04291303A priority patent/EP1505048A1/fr
Priority to US10/853,725 priority patent/US7592470B2/en
Publication of FR2855517A1 publication Critical patent/FR2855517A1/fr
Application granted granted Critical
Publication of FR2855517B1 publication Critical patent/FR2855517B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10—Ester interchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR0306336A 2003-05-26 2003-05-26 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium Expired - Fee Related FR2855517B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR0306336A FR2855517B1 (fr) 2003-05-26 2003-05-26 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium
EP04291303A EP1505048A1 (fr) 2003-05-26 2004-05-19 Procédé de transestérification d'huiles végétales ou animales au moyen de catalyseurs hétérogènes à base de titane, de zirconium ou d'antimoine et d'aluminium
US10/853,725 US7592470B2 (en) 2003-05-26 2004-05-26 Process for transesterification of vegetable or animal oils using heterogeneous catalysts based on titanium, zirconium or antimony and aluminium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0306336A FR2855517B1 (fr) 2003-05-26 2003-05-26 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium

Publications (2)

Publication Number Publication Date
FR2855517A1 FR2855517A1 (fr) 2004-12-03
FR2855517B1 true FR2855517B1 (fr) 2007-04-20

Family

ID=33427433

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0306336A Expired - Fee Related FR2855517B1 (fr) 2003-05-26 2003-05-26 Procede de transesterification d'huiles vegetales ou animales au moyen de catalyseurs heterogenes a base de titane et d'aluminium

Country Status (2)

Country Link
US (1) US7592470B2 (fr)
FR (1) FR2855517B1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2336279A1 (fr) 2009-12-16 2011-06-22 IFP Energies nouvelles Procédé de production d'esters alkyliques à partir d'huile végétale ou animale et d'un monoalcool aliphatique avec purification à chaud en lit fixe

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021697A1 (fr) * 2003-08-29 2005-03-10 Nippon Shokubai Co., Ltd. Procede de production d'alkyl esters d'acide gras et/ou de glycerine et composition renfermant lesdits esters
EP1725636A1 (fr) * 2004-02-24 2006-11-29 Institut Français du Pétrole Procedede fabrication de biocarburants ; transformation de triglycerides en au moins deux familles de biocarburants monoesters d'acides gras et ethers et/ou acetals solubles du glycerol
US8445709B2 (en) * 2006-08-04 2013-05-21 Mcneff Research Consultants, Inc. Systems and methods for refining alkyl ester compositions
US7897798B2 (en) * 2006-08-04 2011-03-01 Mcneff Research Consultants, Inc. Methods and apparatus for producing alkyl esters from lipid feed stocks and systems including same
US8585976B2 (en) * 2007-02-13 2013-11-19 Mcneff Research Consultants, Inc. Devices for selective removal of contaminants from a composition
US8017796B2 (en) * 2007-02-13 2011-09-13 Mcneff Research Consultants, Inc. Systems for selective removal of contaminants from a composition and methods of regenerating the same
US7943791B2 (en) * 2007-09-28 2011-05-17 Mcneff Research Consultants, Inc. Methods and compositions for refining lipid feed stocks
KR101109045B1 (ko) * 2008-01-07 2012-01-31 주식회사 엘지화학 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법
US8097049B2 (en) * 2008-02-07 2012-01-17 The Dallas Group Of America, Inc. Biodiesel purification by a continuous regenerable adsorbent process
EP2303827B1 (fr) * 2008-06-25 2019-10-16 Benefuel Inc. Procédé de fabrication d' alkylesters d' acides gras
US8361174B2 (en) * 2008-10-07 2013-01-29 Sartec Corporation Catalysts, systems, and methods for producing fuels and fuel additives from polyols
US9102877B2 (en) 2008-11-12 2015-08-11 Sartec Corporation Systems and methods for producing fuels from biomass
US20110054200A1 (en) * 2009-09-01 2011-03-03 Catilin, Inc. Systems and Processes for Biodiesel Production
US9433924B2 (en) 2009-11-09 2016-09-06 Wayne State University Metaloxide—ZrO2 catalysts for the esterification and transesterification of free fatty acids and triglycerides to obtain bio-diesel
FR2960874B1 (fr) * 2010-06-02 2012-06-15 Inst Francais Du Petrole Procede de fabrication d'esters alcooliques a partir de triglycerides et d'alcools au moyen de catalyseurs heterogenes a base de metallophosphates azotes
FR2962434B1 (fr) * 2010-07-08 2013-09-06 Arkema France Procede de purification d'un ester alkylique d'acide gras par extraction liquide/liquide
MY163273A (en) 2011-03-09 2017-08-30 Benefuel Inc Systems and methods for making bioproducts
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
CN109516915A (zh) * 2018-10-15 2019-03-26 沈阳化工大学 一种由酯交换路径合成二甘醇二甲酸酯的方法
CN114292689B (zh) * 2021-12-07 2023-03-31 广州崃克保新材料科技有限公司 一种脱模剂组合物

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB143321A (en) * 1919-02-21 1920-05-21 George Calvert Improvements in the treatment of oils, fats and the like
GB712747A (en) * 1951-01-04 1954-07-28 Schlueter Werner Improvements in and relating to preparations of fatty acid esters
GB795573A (en) * 1955-05-10 1958-05-28 Belge Produits Chimiques Sa An improved process for the preparation of higher aliphatic alcohols
FR2752242B1 (fr) * 1996-08-08 1998-10-16 Inst Francais Du Petrole Procede de fabrication d'esters a partir d'huiles vegetales ou animales et d'alcools
FR2772756B1 (fr) * 1997-12-18 2000-02-11 Inst Francais Du Petrole Procede de fabrication d'esters de corps gras et les esters de haute purete obtenus
JP4251575B2 (ja) * 2003-06-30 2009-04-08 株式会社ジャパンエナジー エステル交換反応によるエステルの製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2336279A1 (fr) 2009-12-16 2011-06-22 IFP Energies nouvelles Procédé de production d'esters alkyliques à partir d'huile végétale ou animale et d'un monoalcool aliphatique avec purification à chaud en lit fixe

Also Published As

Publication number Publication date
FR2855517A1 (fr) 2004-12-03
US7592470B2 (en) 2009-09-22
US20050266139A1 (en) 2005-12-01

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Effective date: 20160129