FR2853244A1 - Compositions, especially cosmetic make-up, cleansing or care compositions, having volatile silicone lipid phase containing volatile non-cyclic silicone oil with specific evaporation profile - Google Patents

Abstract

Novel compositions (A) comprise a physiologically acceptable medium including a volatile silicone lipid phase containing volatile non-cyclic silicone oil(s) (I), where the evaporation profile of the silicone phase is such that 2-9 (preferably 2.3-6, especially 3-4.7) mg/cm 2> of (I) is evaporated in 30 minutes. An independent claim is included for compositions (A') comprising a physiologically acceptable medium including a volatile lipid phase containing volatile non-cyclic oil(s) (I') having a surface tension of less than 21 (preferably less than 20) mN/m, where the evaporation profile of the lipid phase is such that 2-9 mg/cm 2> of (I') is evaporated in 30 minutes.

Description

<Desc / Clms Page number 1>

The present invention relates to a cosmetic composition comprising a volatile silicone oil. The subject of the invention is also a process for the non-therapeutic makeup or care of human keratin materials comprising the application of the composition to keratin materials.

Volatile silicone oils are commonly used in cosmetic compositions for their good cosmetic properties, including a pleasant feel on contact with the skin. These oils also evaporate quickly after application to keratin materials. However, their rate of evaporation must not be too high to allow the user to have sufficient time to apply the cosmetic product to the keratin materials, in particular in a uniform manner.

The volatile silicone oils most used in cosmetics are cyclic silicones having from 4 to 6 siloxane groups (generally designated D4, D5, D6) and containing only methyl groups.

The object of the present invention is therefore to provide an alternative for formulating compositions comprising volatile oils, and especially volatile oils compatible with the ingredients usually used in cosmetic compositions.

The inventors have discovered that such a composition is obtained by using one or more particular volatile silicone oil (s) conferring a particular evaporation profile on the volatile fatty phase.

More specifically, the subject of the invention is a composition comprising, in a physiologically acceptable medium, a silicone volatile fatty phase comprising at least one non-cyclic volatile silicone oil, the silicone volatile fatty phase having an evaporation profile such as The mass of volatile silicone oil evaporated after 30 minutes ranges from 2 mg / cm 2 to 9 mg / cm 2.

The subject of the invention is also a composition comprising, in a physiologically acceptable medium, a volatile fatty phase comprising at least one non-cyclic volatile oil having a surface tension of less than 21 mN / m, the volatile fatty phase having a profile of evaporation such that the mass of non-cyclic volatile oil evaporated after 30 minutes ranges from 2 mg / cm 2 to 9 mg / cm 2.

The subject of the invention is also a cosmetic process for making up or non-therapeutic treatment of keratin materials, comprising applying to the keratin materials a composition as defined above.

<Desc / Clms Page number 2>

By "volatile oil" is meant an oil (or non-aqueous medium) capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. The volatile oil is a volatile cosmetic oil which is liquid at ambient temperature, in particular having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40 000 Pa (10 300 mm Hg), and preferably ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 100 mm Hg), and preferably ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mm Hg), mm Hg).

The composition according to the invention comprises a physiologically acceptable medium, in particular a cosmetically or dermatologically acceptable medium, that is to say a medium that is compatible with keratin materials such as the skin, the mucous membranes, the hair, the eyelashes, the eyebrows and the eyebrows. nails.

The composition according to the invention contains a silicone volatile volatile phase comprising at least one non-cyclic volatile silicone oil, the silicone volatile fatty phase having an evaporation profile such that the mass of volatile silicone oil evaporated after 30 minutes goes from 2 mg / cm 2 to 9 mg / cm 2, preferably from 2 mg / cm 2 to 8 mg / cm 2, preferably from 2 mg / cm 2 to 7 mg / cm 2, more preferably from 2.3 mg / cm 2 to 6 mg / cm 2, and even more preferably ranges from 3 mg / cm 2 to 5.5 mg / cm 2, and especially ranges from 3 mg / cm 2 to 4.7 mg / cm 2.

The rate of evaporation of the oil is measured according to the protocol described below.

Furthermore, according to another embodiment of the invention, the composition contains a volatile fatty phase comprising at least one non-cyclic volatile oil having a surface tension of less than 21 mN / m, the volatile fatty phase having a profile of evaporation such that the mass of volatile oil evaporated after 30 minutes ranges from 2 mg / cm 2 to 9 mg / cm 2, preferably ranges from 2 mg / cm 2 to 8 mg / cm 2, preferably from 2 mg / cm 2 to 7 mg / cm 2 mg / cm 2, more preferably ranges from 2.3 mg / cm 2 to 6 mg / cm 2, and even more preferably ranges from 3 mg / cm 2 to 5.5 mg / cm 2, and in particular ranges from 3 mg / cm 2 to 4.7 mg / cm 2. mg / cm2.

Such non-cyclic volatile oil is in particular chosen from non-cyclic silicone volatile oils.

The surface tension of a volatile oil is measured according to the protocol described below.

The non-cyclic silicone volatile oils are chosen from linear or branched volatile silicone oils.

<Desc / Clms Page number 3>

The non-cyclic volatile silicone oil may be chosen from: the non-cyclic linear silicones of formula (I):
R3SiO- (R2SiO) n-SiR3 (I) in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having from 1 to 10 carbon atoms, preferably from 1 to 6 carbon atoms, optionally substituted with one or more fluorine atoms or with one or more hydroxyl groups, or - a hydroxyl group, one of the R radicals possibly being a phenyl group, n is an integer ranging from 0 to 8, preferably ranging from 2 to 6 and more preferably from 3 to 5, the silicone compound of formula (I) containing at most 18 carbon atoms.

the branched silicones of formula (II) or (III) below:
R3SiO - [(R3SiO) RSiO] - (R2SiO) x-SiR3 (II) [R3SiO] 4Si (III) in which R, identical or different, denotes: a saturated or unsaturated hydrocarbon radical having from 1 to 10 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or - a hydroxyl group, one of the R radicals possibly being a phenyl group, x is an integer ranging from 0 to 8, the silicone compound of formula (II) or (III) containing at most 18 carbon atoms.

Preferably, for the compounds of formulas (1), (II), (III), the ratio between the number of carbon atoms and the number of silicon atoms is between 2.25 and 4.33. Advantageously, the compounds of formulas (1), (II) or (III) contain at most 17 carbon atoms, preferably at most 16 carbon atoms, and preferably at most 15 carbon atoms.

The silicones of formulas (I) to (III) may be prepared according to the known processes for the synthesis of silicone compounds.

<Desc / Clms Page number 4>

 When the volatile silicone alone has the evaporation profile as defined previously for the volatile fatty phase, it may be present as the only volatile silicone oil in the composition, and in particular constitute the entire volatile phase of the composition.

When the volatile silicone alone does not have the evaporation profile as defined previously for the volatile fatty phase, it is then used in a mixture with another volatile silicone having an evaporation profile conforming to that described above, of such that the volatile silicone mixture has said evaporation profile.

Examples of non-cyclic volatile silicone that can be used according to the invention are given below; these silicones can be used alone or in a mixture so as to obtain the evaporation profile defined above.

Among the silicones of formula (I), mention may be made of: a) The following disiloxanes: hexamethyldisiloxane (surface tension = 15.9 mN / m), in particular sold under the name DC 200 FLUID 0. 65 cst by the company Dow Corning 1,3-di-tert-butyl-1,1,3,3-tetramethyl disiloxane; 1,3-dipropyl 1,1,3,3-tetramethyl disiloxane; heptyl pentamethyl disiloxane; 1,1,1-triethyl 3,3,3-trimethyl disiloxane; hexaethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (2-methylpropyl) disiloxane; pentamethyl octyl disiloxane; 1,1,1-trimethyl 3,3,3-tris (1-methylethyl) disiloxane; 1-butyl-3-ethyl-1,1,3-trimethyl-3-propyl disiloxane; pentamethyl pentyl disiloxane; 1-butyl 1,1,3,3-tetramethyl-3- (1-methylethyl) disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylpropyl) disiloxane; 1,1,3-triethyl-1,3,3-tripropyl disiloxane; (3,3-dimethylbutyl) pentamethyl disiloxane; (3-methylbutyl) pentamethyl disiloxane; (3-methylpentyl) pentamethyl disiloxane; 1,1,1-triethyl 3,3-dimethyl-3-propyl disiloxane; 1- (1,1-dimethylethyl) 1,1,3,3,3-pentamethyl disiloxane; 1,1,1-trimethyl 3,3,3-tripropyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrakis (1-methylethyl) disiloxane; 1,1-dibutyl 1,3,3,3-tetramethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-dipropyl disiloxane;

<Desc / Clms Page number 5>

 1,1,3,3-tetramethyl-1,3-bis (3-methylbutyl) disiloxane; butyl pentamethyl disiloxane; pentaethyl methyl disiloxane; 1,1,3,3-tetramethyl-1,3-dipentyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrapropyl disiloxane; 1,1,1,3-tetraethyl 3,3-dimethyl disiloxane; 1,1,1-triethyl 3,3,3-tripropyl disiloxane; 1,3-dibutyl 1,1,3,3-tetramethyl disiloxane; hexyl pentamethyl disiloxane; b) the following trisiloxanes: octamethyltrisiloxane (surface tension = 17.4 mN / m), sold especially under the name DC 200 FLUID 1 cst by the company Dow Corning 3-pentyl 1,1,1,3,5,5 5-heptamethyl trisiloxane; 1-hexyl-1,1,3,3,5,5,5-heptamethyl trisiloxane; 1,1,1,3,3,5,5-heptamethyl-5-octyl trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-octyl trisiloxane, especially sold under the name "Silsoft 034" by the company OSI; 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane (surface tension = 20.5 mN / m), especially sold under the name "DC 2-1731" by the company Dow Corning; 1,1,3,3,5,5-hexamethyl 1,5-dipropyl trisiloxane; 3- (1-ethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane; 1,5-diethyl-1,1,3,3,5,5-hexamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,3,5,5,5-heptamethyl trisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 1,1,1,3,3,5,5-hexamethyl 1,5-bis (1-methylpropyl) trisiloxane; 1,5-bis (1,1-dimethylethyl) -1,1,3,3,5,5-hexamethyltrisiloxane; 3- (3,3-dimethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) trisiloxane; 1-butyl 1,1,3,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyl trisiloxane; 3-isohexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,3,5-triethyl-1,1,3,5,5-pentamethyltrisiloxane; 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl 3,3-dipropyl trisiloxane; 3,3-diethyl 1,1,1,5,5,5-hexamethyltrisiloxane; 1,5-dibutyl 1,1,3,3,5,5-hexamethyltrisiloxane;

<Desc / Clms Page number 6>

 1,1,1,5,5,5-hexaethyl-3,3-dimethyltrisiloxane; 3,3-dibutyl 1,1,1,5,5,5-hexamethyltrisiloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1-ethyl-1,1,3,3,5,5,5-heptamethyltrisiloxane; c) the following tetrasiloxanes: decamethyltetrasiloxane (surface tension = 18 mN / m), in particular sold under the name DC 200 FLUID 1.5 cst by the company Dow Corning; 1,1,3,3,5,5,7,7-octamethyl 1,7-dipropyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl 5- (1-methylethyl) tetrasiloxane; 1-butyl 1,1,3,3,5,5,7,7,7-nonamethyl tetrasiloxane; 3,5-diethyl-1,1,1,3,5,7,7,7-octamethyl tetrasiloxane; 1,3,5,7-tetraethyl-1,1,3,5,7,7-hexamethyltetrasiloxane; 3,3,5,5-tetraethyl 1,1,1,7,7,7-hexamethyltetrasiloxane; 1,1,1,3,3,5,5,7,7-nonamethyl 7-phenyltetrasiloxane; 3,3-diethyl 1,1,1,5,5,7,7,7-octamethyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl-5-phenyltetrasiloxane; d) the following pentasiloxanes: dodecamethylpentasiloxane (surface tension = 18.7 mN / m), sold in particular under the name DC 200 Fluid 2 cst by the company Dow Corning; 1,1,3,3,5,5,7,7,9,9-decamethyl-1,9-dipropyl pentasiloxane; 3,3,5,5,7,7-hexaethyl-1,1,1,9,9,9-hexamethylpentasiloxane; 1,1,1,3,3,5,7,7,9,9,9-undecamethyl 5-phenyl pentasiloxane; 1-butyl 1,1,3,3,5,5,7,7,9,9,9-undecamethylpentasiloxane; 3,3-diethyl-1,1,1,5,5,7,7,9,9,9-decamethylpentasiloxane; 1,3,5,7,9-pentaethyl 1,1,3,5,7,9,9-heptamethylpentasiloxane; 3,5,7-triethyl 1,1,1,3,5,7,9,9,9-nonamethylpentasiloxane; 1,1,1-triethyl 3,3,5,5,7,7,9,9,9-nonamethylpentasiloxane; e) the following hexasiloxanes: 1-butyl-1,1,3,3,5,5,7,7,9,9,11,11,11-tridecamethyl hexasiloxane; 3,5,7,9-tetraethyl 1,1,1,3,5,7,9,11,11,11-decamethyl hexasiloxane; tetradecamethyl hexasiloxane; f) hexadecamethylheptasiloxane; g) octadecamethyl octasiloxane.

Among the silicones of formula (II), mention may be made of: a) the following tetrasiloxanes: 2- [3,3,3-trimethyl-1,1-bis [(trimethylsilyl) oxy] disiloxanyl] ethyl;

<Desc / Clms Page number 7>

 1,1,1,5,5,5-hexamethyl-3- (2-methylpropyl) 3 - [(trimethylsilyl) oxy] trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-butyl 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,5,5,5-hexamethyl-3-propyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-ethyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1-triethyl-3,5,5,5-tetramethyl-3- (trimethylsiloxy) trisiloxane; 3-methyl-1,1,1,5,5,5-hexamethyl-3- [trimethylsilyl] oxy] trisiloxane; 3 - [(dimethylphenylsilyl) oxy] 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3- (2-methylpentyl) 3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,5,5,5-hexamethyl-3- (4-methylpentyl) -3 - [(trimethylsilyl) oxy] trisiloxane; 3-hexyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; b) the following pentasiloxanes: 1,1,1,3,5,5,7,7,7-nonamethyl 3- (trimethylsiloxy) tetrasiloxane; 1,1,1,3,3,7,7,7-octamethyl-5-phenyl-5 - [(trimethylsilyl) oxy] tetrasiloxane; c) the following heptasiloxanes: 1,1,1,3,5,5,7,7,9,9,11,11,11-tridecamethyl-3 - [(trimethylsilyl) oxy] hexasiloxane.

Among the silicones of formula (III), mention may be made of: 1,1,1,5,5,5-hexamethyl 3,3-bis (trimethylsiloxy) trisiloxane.

It is also possible to use other volatile silicone oils chosen from: a) the following tetrasiloxanes: 2,2,8,8-tetramethyl-5 - [(pentamethyldisiloxanyl) methyl] -3,7-dioxa-2,8-disilanonane; 2,2,5,8,8-pentamethyl-5 - [(trimethylsilyl) methoxy] 4,6-dioxa-2,5,8-trisilanonane; 1,3-dimethyl-1,3-bis [(trimethylsilyl) methyl] 1,3-disiloxanediol; 3-ethyl-1,1,1,5,5,5-hexamethyl-3- [3- (trimethylsiloxy) propyl] trisiloxane; 1,1,1,5,5,5-hexamethyl-3-phenyl-3 - [(trimethylsilyl) oxy] trisiloxane (Dow 556 Fluid); b) the following pentasiloxanes: 2,2,7,7,9,9,11,11,16,16-decamethyl-3,8,10,15-tetraoxa-2,7,9,11,16pentasilaheptadecane; tetrakis [(trimethylsilyl) methyl] silicic acid ester; c) the following hexasiloxanes: 3,5-diethyl 1,1,1,7,7,7-hexamethyl 3,5-bis [(trimethylsilyl) oxy] tetrasiloxane, 1,1,1,3,5,7 7,7-octamethyl 3,5-bis [(trimethylsilyl) oxy] tetrasiloxane; d) heptasiloxane: 1,1,1,3,7,7,7-heptamethyl 3,5,5-tris [(trimethylsilyl) oxy] tetrasiloxane;

<Desc / Clms Page number 8>

 e) the following octasiloxanes: 1,1,1,3,5,5,9,9,9-nonamethyl-3,7,7-tris [(trimethylsilyl) oxy] pentasiloxane; 1,1,1,3,5,7,9,9,9-nonamethyl 3,5,7-tris [(trimethylsilyl) oxy] pentasiloxane; 1,1,1,7,7,7-hexamethyl 3,3,5,5-tetrakis [(trimethylsilyl) oxy] tetrasiloxane.

As the preferred silicone volatile oil, it is possible to use: decamethyltetrasiloxane; dodecamethylpentasiloxane; 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane; and their mixtures.

Preferably, the volatile fatty phase of the composition according to the invention comprises a mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane, especially in a weight ratio dodecamethylpentasiloxane / decamethyltetrasiloxane ranging from 55/45 to 80/20, preferably from 60/40 to 75 / 25, and better from 60/40 to 70/30.

The subject of the invention is therefore also a composition comprising, in a physiologically acceptable medium, a silicone-containing volatile fatty phase comprising a mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane in a weight ratio of dodecamethylpentasiloxane / decamethyltetrasiloxane ranging from 55/45 to 80/20, preferably ranging from 60/40 to 75/25, and better from 60/40 to 70/30.

Advantageously, the volatile silicone phase of the composition is formed essentially, if not solely, of the mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane described above.

According to another embodiment of the invention, the volatile fatty phase comprises a mixture of dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5heptamethyltrisiloxane, especially in a dodecamethylpentasiloxane / 3-butyl weight ratio. 1,1,1,3,5,5,5-heptamethyl trisiloxane ranging from 75/25 to 50/50, preferably from 70/30 to 55/45, and more preferably from 65/35 to 55/45.

The subject of the invention is therefore also a composition comprising, in a physiologically acceptable medium, a volatile silicone fatty phase comprising a mixture of dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5heptamethyltrisiloxane in a ratio weight of dodecamethylpentasiloxane / 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane ranging from 75/25 to 50/50, preferably from 70/30 to 55/45, and more preferably from 65/50 to 35 to 55/45.

<Desc / Clms Page number 9>

Advantageously, the volatile silicone phase of the composition is formed essentially, if not solely, of the mixture of dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane described above.

According to another embodiment of the invention, the volatile fatty phase comprises a mixture of decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethylhexyl trisiloxane, especially in a weight ratio of decamethyltetrasiloxane / 1.1 , 1,3,5,5,5-heptamethyl-3-hexyl trisiloxane ranging from 25/75 to 45/55, preferably from 30/70 to 40/60, and more preferably from 35/65 to 40/60.

The subject of the invention is therefore also a composition comprising, in a physiologically acceptable medium, a volatile silicone fatty phase comprising a mixture of decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethylhexyltrisiloxane in a ratio of weight of decamethyltetrasiloxane / 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane ranging from 25/75 to 45/55, preferably from 30/70 to 40/60, and more preferably from 35/60 to 65 to 40/60.

Advantageously, the silicone-containing volatile fatty phase of the composition is formed essentially, or even solely, of the mixture of decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane described above.

According to another embodiment of the invention, the volatile fatty phase comprises a mixture of 3-hexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-butyl 1,1,1,3 , 5,5,5-heptamethyl trisiloxane, especially in a weight ratio 3hexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane / 3-butyl 1,1,1,3,5,5,5- heptamethyl trisiloxane ranging from 45/55 to 70/30, preferably from 50/50 to 65/35, and more preferably from 55/45 to 60/40.

The subject of the invention is therefore also a composition comprising, in a physiologically acceptable medium, a volatile silicone fatty phase comprising a mixture of 3-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane and 3- butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane in a weight ratio of 3-hexyl-1,1,1,3,5,5,5-heptamethyl-trisiloxane / 3-butyl-1,1,1, 3,5,5,5-heptamethyl trisiloxane ranging from 45/55 to 70/30, preferably from 50/50 to 65/35, and more preferably from 55/45 to 60/40.

Advantageously, the silicone volatile fatty phase of the composition is formed essentially, or even solely, of the mixture of 3-hexyl 1,1,1,3,5,5,5heptamethyltrisiloxane and 3-butyl 1,1,1,3, 5,5,5-heptamethyl trisiloxane described above.

According to one particular embodiment of the invention, the volatile silicone fatty phase of the composition according to the invention contains from 0 to 5% by weight, based on

<Desc / Clms Page number 10>

 to the total weight of the volatile silicone silicone phase, cyclic silicone volatile oil, and preferably from 0 to 1% by weight.

The non-cyclic volatile silicone oil, alone or as a mixture, may be present in a content ranging from 1% to 80% by weight, relative to the total weight of the composition, preferably ranging from 1% to 65% by weight. and preferably ranging from 1% to 50% by weight.

The composition according to the invention may further comprise a non-silicone volatile oil, chosen in particular from volatile hydrocarbon or fluorinated oils.

Hydrocarbon oil is understood to mean an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and not containing silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

The hydrocarbon-based volatile oil may be chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof, and in particular branched C 8 -C 16 alkanes, for example C 6 -C 16 isoalkanes (also known as isoparaffins) and isododecane. isodecane, isohexadecane and for example the oils sold under the trade names of Isopars 'or Permethyls', branched C8-C16 esters such as isohexyl neo-pentanoate and mixtures thereof; isododecane is preferably used.

The non-silicone volatile oil may be present in a content ranging from 0.1% to 50% by weight, relative to the total weight of the composition, preferably ranging from 0.1% to 40% by weight, and preferably ranging from from 0.1% to 30% by weight.

The composition according to the invention may also comprise at least one non-volatile oil.

As non-volatile oil, mention may be made of hydrocarbon-based oils of mineral or synthetic origin, such as linear or branched hydrocarbons such as paraffin oil or its derivatives, liquid petroleum jelly, polydecenes, hydrogenated polyisobutene such as marketed Parleam. by the company Nippon Oil Fats, squalane of synthetic or vegetable origin; oils of animal origin such as mink, turtle oil, perhydrosqualene; vegetable oils of hydrocarbon origin with a high triglyceride content consisting of esters of fatty acids and of glycerol, the fatty acids of which may have various chain lengths, the latter may be linear or branched, saturated or unsaturated, in particular triglycerides fatty acid, especially of 4 to 22 carbon atoms, such as the triglycerides of heptanoic acid, octanoic acid, and caprylic / caprylic acids or else the hydroxylated triglycerides, such as

<Desc / Clms Page number 11>

 sweet almond, calophyllum, palm, grape seed, sesame, arara, rapeseed, sunflower, cotton, apricot, castor oil, alfalfa, squash, blackcurrant, macadamia , muscat rose, hazelnut, avocado, jojoba, olive, sprouts of cereals (corn, wheat, barley, rye), shea butter; fatty acid esters, in particular from 4 to 22 carbon atoms, and in particular octanoic acid, heptanoic acid, lanolic acid, oleic acid, lauric acid, stearic acid, propylene glycol dioctanoate, propylene glycol monoisostearate, polyglyceryl diisostearate, neopentyl glycol diheptanoate; synthetic esters of formula R 1 COOR 2 in which R 1 represents the residue of a linear or branched higher fatty acid containing from 7 to 40 carbon atoms and R 2 represents a branched hydrocarbon-based chain containing from 3 to 40 carbon atoms, for example Purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12-C15 alcohol benzoate, 2-hexyl ethyl palmitate, 2-octyl dodecyl stearate, Erucate 2-octyl dodecyl, isostearyl isostearate, 2-octyldodecyl benzoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, isopropyl myristate, isopropyl palmitate, butyl stearate , hexyl laurate, diisopropyl adipate, 2-ethyl hexyl palmitate, 2-hexyl decyl laurate, 2-octyl decyl palmitate, 2-octyldodecyl myristate, 2-diethylhexyl succinate, diisostearyl malate, isodecyl neopentanoate; hydroxylated esters such as isostearyl lactate, octyl hydroxystearate, octyldodecyl hydroxystearate, diisostearyl malate, triisocetyl citrate, glycerol or diglycerine triisostearate; diethylene glycol diisononanoate; pentaerythritol esters; esters of aromatic acids and alcohols comprising 4 to 22 carbon atoms, in particular tridecyl trimellitate; higher C8-C26 fatty acids such as oleic acid, linoleic acid, linolenic acid or isostearic acid; higher C8-C26 fatty alcohols such as oleic alcohol, linoleic or linolenic alcohol, isostearyl alcohol or octyl dodecanol; synthetic ethers containing at least 7 carbon atoms, silicone oils such as polydimethylsiloxanes (PDMS) which are liquid at room temperature, linear, optionally phenylated, such as phenyl trimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes, liquid 2-phenylethyl trimethylsiloxysilicates, optionally substituted with aliphatic and / or aromatic groups such as alkyl, alkoxy or phenyl groups, during and / or at the end of the siticylated chain, groups containing from 2 to 24 carbon atoms and optionally fluorinated, or by functional groups such as hydroxyl, thiol and / or amine groups; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes such as dimethicone copolyols or alkylmethicone copolyols; liquid fluorinated silicones; and their mixtures.

<Desc / Clms Page number 12>

The non-volatile oil may be present in a content ranging from 0.1% to 60% by weight, relative to the total weight of the composition, preferably ranging from 0.5% to
50% by weight, and preferably ranging from 1% to 40% by weight.

The composition according to the invention may comprise at least one aqueous phase containing water. The water may be floral water such as cornflower water and / or mineral water such as VITTEL water, LUCAS water or LA water.
ROCHE POSAY and / or thermal water.

 The aqueous phase may also comprise organic solvents which are water-soluble (at 25 ° C.), for example primary alcohols such as ethanol and isopropanol, glycols such as glycerol, propylene glycol or butylene glycol. col, dipropylene glycol, diethylene glycol, glycol ethers, C1 to C4 alkyl ethers of mono-, di- or tripropylene glycol, mono-, di- or triethylene glycol, and mixtures thereof.

 The composition may be an anhydrous composition, that is to say a composition containing less than 2% by weight of water, or even less than 0.5% of water, in particular water-free, the water being being not added during the preparation of the composition but corresponding to the residual water provided by the mixed ingredients.

 The composition may contain other usual cosmetic or dermatological ingredients that may be chosen especially from polymers, especially film-forming polymers, fixing polymers; surfactants; conditioners of the hair; dyestuffs; pearling agents; opacifics; organic solvents; the perfumes ; thickeners; gelling agents; waxes; pasty products; hair dyes; silicone resins; silicone gums; conservatives ; antioxidants, cosmetic active ingredients; solar filters; pH stabilizers; vitamins; moisturizers; antiperspirant agents; deodorants; self-tanning compounds; and their mixtures.

 Of course, those skilled in the art will take care to choose this or these optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the composition according to the invention are not, or not substantially, impaired by the envisaged addition.

 The composition may advantageously contain a dyestuff which may be chosen from lipophilic dyes, hydrophilic dyes, pigments and pearlescent agents normally used in cosmetic or dermatological compositions, and mixtures thereof. This coloring material is generally present in a proportion of from 0.01 to 40% of the total weight of the composition, preferably from 1 to 35% and better still from 5 to 25%.

<Desc / Clms Page number 13>

The composition according to the invention may be in liquid, pasty, solid, foam or spray form. It may be an emulsion or an anhydrous composition.

The composition according to the invention can be used for the makeup or the care or cleaning of keratin materials of a human being such as the skin (of the face, body, scalp, lips), the mucous membranes (inner edge of the eyelids), hair, nails, eyelashes, eyebrows.

The composition therefore has a particular application as a care composition for the body or the face; cleaning the body or the face such as a shower gel, bath gel, make-up remover; makeup composition for the body or the face such as foundation, lipstick, lip care, nail polish, nail care, mascara, eyeliner; perfume composition; capillary composition such as hair coloring composition, permanent hair deforming composition; sun protection composition; deodorant composition; cleaning or hair care composition such as shampoo, conditioner to be rinsed or not, rinse composition to be applied before or after coloring, bleaching, perming or straightening, or between the two stages of a perm or a straightening; hair composition for maintaining the hairstyle such as a hairspray, a gel, a mousse or a styling spray.

The manufacturing processes of the products according to the invention do not differ from the processes conventionally used in cosmetics and are perfectly known to those skilled in the art.

The invention is further illustrated by the examples described hereinafter.

Measurement of the evaporation rate of an oil: is introduced into a crystallizer (diameter: 7 cm) placed on a balance in an enclosure of about 0.3 m3 regulated in temperature (25 C) and hygrometry ( relative humidity 50%) 15 g of oil or oil mixture to be tested. The liquid is allowed to evaporate freely, without stirring, providing ventilation by a fan (PAPST-MOTOREN, reference 8550 N, rotating at 2700 revolutions / minute) arranged in a vertical position above the crystallizer containing the solvent, the blades being directed towards the crystallizer and at a distance of 20 cm from the bottom of the crystallizer. The mass of oil remaining in the crystallizer is measured at regular intervals. The evaporation rates are expressed in mg of evaporated oil per unit area (cm2) and per unit of time (minute).

<Desc / Clms Page number 14>

Measurement of the surface tension of a volatile oil: The surface tension is determined by the method known as the hanging drop. It is measured at 25 C plus or minus 1 C using a Fibro DAT 1100 tensiometer, sold by the company FIBRO (Sweden). A drop of volatile oil is formed using a syringe controlled by the tensiometer at the outlet of a teflon cannula of internal diameter equal to 200 m and internal diameter equal to 1.5 mm and held in position vertical. The volume of the drop is between 1 and 10 microliters, preferably between 5 and 10 microliters. The hanging drop is observed using a camera built into the meter and its shape is parameterized by the software of the FIBRO DAT 1100 tensiometer using a method of solving the Laplace equation. The result is given in mN / m.

Example 1: A foundation was prepared in the form of a water-in-oil emulsion having the following composition:

<Tb>
<tb> cetyl <SEP> dimethicone <SEP> copolyol
<tb> (ABIL <SEP> EM <SEP> 90 <SEP> of <SEP> the <SEP> Company <SEP> GOLDSCHMIDT) <SEP> 3 <SEP> g
<tb> Succinate <SEP> Isostearyl <SEP> Diglyceryl
<tb> (IMWITOR <SEP> 780K <SEP> of <SEP> The <SEP> Company <SEP> CONDEA) <SEP> 0.6 <SEP> g
<tb> Decamethyl <SEP> tetrasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 1.5 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 6.48g
<tb> Dodecamethyl <SEP> pentasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 2 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 12.02 <SEP> g
<tb> Isododecane <SEP> 7.1 <SEP> g
<tb> Mix <SEP> of <SEP> pigments <SEP> 10 <SEP> g <SEP>
<tb> (oxides <SEP> of <SEP> iron <SEP> and <SEP> oxides <SEP> of <SEP> titanium <SEP> hydrophobic)
<tb> Bentone <SEP> 1.6 <SEP> g
<tb> Powder <SEP> of <SEP> polyamide <SEP> 8 <SEP> g
<tb> (NYLON-12 <SEP> from <SEP> Dupont <SEP> from <SEP> Nemours)
<tb> Sulfate <SEP> of <SEP> Magnesium <SEP> 0.7 <SEP> g
<tb> Preservative <SEP> 0.45 <SEP> g
<tb> Fragrance <SEP> 0.5 <SEP> g
<tb> Water <SEP> qsp <SEP> 100 <SEP> g <SEP>
<Tb>
Example 2

<Desc / Clms Page number 15>

An oil-in-water foundation having the following composition was prepared: Decamethyltetrasiloxane

<Tb>
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 1.5 <SEP> is <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 3. <SEP> 3g
<tb> Dodecamethylpentasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 2 <SEP> is <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 7.7 <SEP> g
<tb> Polyisobutene <SEP> Hydrogenated <SEP> (Parleam, <SEP> NOF <SEP> COrporation) <SEP> 5 <SEP> g
<tb> palmitate <SEP> of ethyl-2 <SEP> hexyl <SEP> 11 <SEP> g
<tb> Isostearate <SEP> of <SEP> Glyceryl <SEP> 4 <SEP> g
<tb> Stearic acid <SEP><SEP> 2 <SEP> g
<tb> Triethanolamine <SEP> 1 <SEP> g
<tb> Powder <SEP> of <SEP> polyamide
<tb> (NYLON-12 <SEP> from <SEP> Dupont <SEP> from <SEP> Nemours) <SEP> 5 <SEP> g
<tb> Mix <SEP> of <SEP> pigments
<tb> (oxides <SEP> of <SEP> iron <SEP> and <SEP> oxides <SEP> of <SEP> titanium) <SEP> 10 <SEP> g <SEP>
<tb> Carboxymethylcellulose <SEP> 0.2 <SEP> g
<tb> Propylene <SEP> glycol <SEP> 5g
<tb> Glycerol <SEP> 2g
<tb> Fragrance <SEP> 0,5g
<tb> Preservatives <SEP> 0.4g
<tb> Water <SEP> qsp <SEP> 100 <SEP> g <SEP>
<Tb>
Example 3: A lipstick having the following composition was prepared:

<Tb>
<tb> Wax <SEP> of <SEP> polyethylene
<tb> (Performalene <SEP> 655, <SEP> New <SEP> Phase <SEP> Technologies) <SEP> 20g
<tb> Decamethyltetrasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 1.5 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 18,2g
<tb> Dodecamethylpentasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 2 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 4 <SEP> g
<tb> Cclopentadiméhylsiloxane
<tb> (DC <SEP> 245 <SEP> Fluid <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 6 <SEP> g
<tb> Isododecane <SEP> 51.8 <SEP> g <SEP>
<tb> DC <SEP> Red <SEP> n 7 <SEP> Calcium <SEP> Lake <SEP> (pigment) <SEP> 6 <SEP> g
<Tb>
Example 4: A care cream having the following composition was prepared:

<Desc / Clms Page number 16>

Fatty phase: Mixture of glyceryl monostearate and polyethylene glycol stearate 100 EO (50/50 by weight)

<Tb>
<tb> (ARLACEL <SEP> 165 <SEP> of <SEP> the <SEP> Company <SEP> HERE) <SEP> 2.5 <SEP> g <SEP>
<tb> - <SEP> Alcohol <SEP> stearyl alcohol <SEP> 0.5 <SEP> g
<tb> - <SEP> Stearic acid <SEP><SEP> 1 <SEP> g
<tb> - <SEP> Polyisobutene <SEP> Hydrogenated <SEP> (Parleam, <SEP> NOF <SEP> COrporation) <SEP> 9 <SEP> g
<tb> - <SEP> Decamethyltetrasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 1.5 <SEP> CST <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 2.1 <SEP> g
<tb> - <SEP> Dodecamethylpentasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 2 <SEP> CST <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 2.1 <SEP> g
<tb> Phase <SEP> aqueous
<tb> - <SEP><SEP> Polyacrylic Acid <SEP> Crosslinked <SEP> (Carbopol <SEP> 980) <SEP> 1 <SEP> g
<tb> - <SEP> Triethanolamine <SEP> 0.03 <SEP> g
<tb> - <SEP> Preservative <SEP> 0.3 <SEP> g
<tb> - <SEP> Water <SEP> qsp <SEP> 100 <SEP> g <SEP>
<Tb>
EXAMPLE 5 A makeup remover having the following composition was prepared:

<Tb>
<tb> Isopropyl Palmitate <SEP><SEP> 8 <SEP> g
<tb> Decamethyltetrasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 1.5 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 2.8g
<tb> Dodecamethylpentasiloxane
<tb> (DC <SEP> 200 <SEP> FLUID <SEP> 2 <SEP> cst <SEP> of <SEP> DOW <SEP> CORNING) <SEP> 5.2 <SEP> g
<tb> Alcohol <SEP> stearic <SEP> 8 <SEP> g
<tb> Stearate <SEP> of <SEP> sucrose <SEP> 2 <SEP> g
<tb> Stearic acid <SEP><SEP> 0.3 <SEP> g <SEP>
<tb> Soda <SEP> 0.06 <SEP> g
<tb> Glycerin <SEP> 5 <SEP> g <SEP>
<tb> Carbopol <SEP> 0.2 <SEP> g
<tb> Water <SEP> qsp <SEP> 100 <SEP> g <SEP>
<Tb>

Claims (45)

 1. A composition comprising, in a physiologically acceptable medium, a volatile silicone silicone phase comprising at least one non-cyclic silicone volatile oil, the silicone volatile phase having an evaporation profile such that the volatile silicone oil mass is evaporated at the end. 30 minutes range from 2 mg / cm 2 to 9 mg / cm 2. 2. Composition according to Claim 1, characterized in that the volatile silicone phase having an evaporation profile such that the volatile silicone oil mass evaporated after 30 minutes ranges from 2 mg / cm 2 to 8 mg / cm 2. and preferably ranges from 2 mg / cm 2 to 7 mg / cm 2. 3. Composition ~ according to claim 1 or 2, characterized in that the silicone volatile phase with an evaporation profile such that the volatile silicone oil mass evaporated after 30 minutes ranges from 2.3 mg / cm 2 at 6 mg / cm 2, preferably from 3 mg / cm 2 to 5.5 mg / cm 2, and preferably from 3 mg / cm 2 to 4.7 mg / cm 2. 4. Composition comprising, in a physiologically acceptable medium, a volatile fatty phase comprising at least one non-cyclic volatile oil having a surface tension of less than 21 mN / m, preferably less than 20 mN / m, the volatile fatty phase having a evaporation profile such that the mass of volatile non-cyclic oil evaporated after 30 minutes ranges from 2 mg / cm 2 to 9 mg / cm 2. 5. Composition according to the preceding claim, characterized in that the non-cyclic volatile oil is a non-cyclic silicone oil. 6. Composition according to any one of the preceding claims, characterized in that the non-cyclic volatile silicone oil is chosen from the silicones of formula (I): R3SiO- (R2SiO) n-SiR3 (I) in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having from 1 to 10 carbon atoms, preferably from 1 to 6 carbon atoms, optionally substituted with one or more fluorine atoms or with one or more hydroxyl groups, or - a hydroxyl group, one of the radicals R possibly being a phenyl group, <Desc / Clms Page number 18>  n is an integer ranging from 0 to 8, preferably ranging from 2 to 6, and better still ranging from 3 to 5, the silicone compound of formula (1) containing at most 18 carbon atoms, preferably at most 17 carbon atoms preferably at most 16 carbon atoms, and more preferably at most 15 carbon atoms. 7. Composition according to any one of claims 1 to 5, characterized in that the non-cyclic volatile silicone oil is chosen from the silicones of formula (II): R3SiO - [(R3SiO) RSiO] - (R2SiO) x-SiR3 (II) in which R, identical or different, denotes: a saturated or unsaturated hydrocarbon radical having from 1 to 10 carbon atoms, optionally substituted by one or more fluorine atoms or with one or more hydroxyl groups, or - a hydroxyl group, one of the R radicals possibly being a phenyl group, x is an integer ranging from 0 to 8, the silicone compound of formula (II) containing at least more than 18 carbon atoms, preferably at most 17 carbon atoms, preferably at most 16 carbon atoms, and more preferably at most 15 carbon atoms. 8. Composition according to any one of claims 1 to 5, characterized in that the non-cyclic volatile silicone oil is chosen from silicones of formula (III): [R3SiO] 4Si (III) in which R, identical or different, denotes: a hydrocarbon radical, saturated or unsaturated, having 1 to 10 carbon atoms, optionally substituted by one or more fluorine atoms or by one or more hydroxyl groups, or - a hydroxyl group, one of the radicals R which may be a phenyl group, the silicone compound of formula (III) containing at most 18 carbon atoms, preferably at most 17 carbon atoms, preferably at most 16 carbon atoms, and more preferably at most 15 carbon atoms. 9. Composition according to any one of claims 6 to 8, characterized in that for the compounds of formulas (1), (II), (III), the ratio between the number of carbon atoms and the number of silicon atom is between 2.25 and 4.33. <Desc / Clms Page number 19>  10. Composition according to Claim 6, characterized in that the silicone of formula (I) is chosen from: hexamethyldisiloxane; 1,3-di-tert-butyl-1,1,3,3-tetramethyl disiloxane; 1,3-dipropyl 1,1,3,3-tetramethyl disiloxane; heptyl pentamethyl disiloxane; 1,1,1-triethyl 3,3,3-trimethyl disiloxane; hexaethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (2-methylpropyl) disiloxane; pentamethyl octyl disiloxane; 1,1,1-trimethyl 3,3,3-tris (1-methylethyl) disiloxane; 1-butyl-3-ethyl-1,1,3-trimethyl-3-propyl disiloxane; pentamethyl pentyl disiloxane; 1-butyl 1,1,3,3-tetramethyl-3- (1-methylethyl) disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylpropyl) disiloxane; 1,1,3-triethyl-1,3,3-tripropyl disiloxane; (3,3-dimethylbutyl) pentamethyl disiloxane; (3-methylbutyl) pentamethyl disiloxane; (3-methylpentyl) pentamethyl disiloxane; 1,1,1-triethyl 3,3-dimethyl-3-propyl disiloxane; 1- (1,1-dimethylethyl) 1,1,3,3,3-pentamethyl disiloxane; 1,1,1-trimethyl 3,3,3-tripropyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrakis (1-methylethyl) disiloxane; 1,1-dibutyl 1,3,3,3-tetramethyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-bis (1-methylethyl) disiloxane; 1,1,1,3-tetramethyl 3,3-dipropyl disiloxane; 1,1,3,3-tetramethyl-1,3-bis (3-methylbutyl) disiloxane; butyl pentamethyl disiloxane; pentaethyl methyl disiloxane; 1,1,3,3-tetramethyl-1,3-dipentyl disiloxane; 1,3-dimethyl-1,1,3,3-tetrapropyl disiloxane; 1,1,1,3-tetraethyl 3,3-dimethyl disiloxane; 1,1,1-triethyl 3,3,3-tripropyl disiloxane; 1,3-dibutyl 1,1,3,3-tetramethyl disiloxane; hexyl pentamethyl disiloxane; octamethyltrisiloxane; 1-hexyl-1,1,3,3,5,5,5-heptamethyl trisiloxane; 1,1,1,3,3,5,5-heptamethyl-5-octyl trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-octyl trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane; 1,1,3,3,5,5-hexamethyl 1,5-dipropyl trisiloxane; 3- (1-ethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; <Desc / Clms Page number 20>  1,1,1,3,5,5,5-heptamethyl-3- (1-methylpentyl) trisiloxane; 1,5-diethyl-1,1,3,3,5,5-hexamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (1-methylpropyl) trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,3,5,5,5-heptamethyl trisiloxane; 1,1,1,5,5,5-hexamethyl-3,3-bis (1-methylethyl) trisiloxane; 1,1,1,3,3,5,5-hexamethyl 1,5-bis (1-methylpropyl) trisiloxane; 1,5-bis (1,1-dimethylethyl) -1,1,3,3,5,5-hexamethyltrisiloxane; 3- (3,3-dimethylbutyl) 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylbutyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (3-methylpentyl) trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3- (2-methylpropyl) trisiloxane; 1-butyl 1,1,3,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-propyl trisiloxane; 3-isohexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,3,5-triethyl-1,1,3,5,5-pentamethyltrisiloxane; 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-tert-pentyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl 3,3-dipropyl trisiloxane; 3,3-diethyl 1,1,1,5,5,5-hexamethyltrisiloxane; 1,5-dibutyl 1,1,3,3,5,5-hexamethyltrisiloxane; 1,1,1,5,5,5-hexaethyl-3,3-dimethyltrisiloxane; 3,3-dibutyl 1,1,1,5,5,5-hexamethyltrisiloxane; 3-ethyl-1,1,1,3,5,5,5-heptamethyltrisiloxane; 3-heptyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1-ethyl-1,1,3,3,5,5,5-heptamethyltrisiloxane; decamethyltetrasiloxane; 1,1,3,3,5,5,7,7-octamethyl 1,7-dipropyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl 5- (1-methylethyl) tetrasiloxane; 1-butyl 1,1,3,3,5,5,7,7,7-nonamethyl tetrasiloxane; 3,5-diethyl-1,1,1,3,5,7,7,7-octamethyl tetrasiloxane; 1,3,5,7-tetraethyl-1,1,3,5,7,7-hexamethyltetrasiloxane; 3,3,5,5-tetraethyl 1,1,1,7,7,7-hexamethyltetrasiloxane; 1,1,1,3,3,5,5,7,7-nonamethyl 7-phenyltetrasiloxane; 3,3-diethyl 1,1,1,5,5,7,7,7-octamethyl tetrasiloxane; 1,1,1,3,3,5,7,7,7-nonamethyl-5-phenyltetrasiloxane; dodecamethylpentasiloxane; 1,1,3,3,5,5,7,7,9,9-decamethyl-1,9-dipropyl pentasiloxane; 3,3,5,5,7,7-hexaethyl-1,1,1,9,9,9-hexamethylpentasiloxane; 1,1,1,3,3,5,7,7,9,9,9-undecamethyl 5-phenyl pentasiloxane; 1-butyl 1,1,3,3,5,5,7,7,9,9,9-undecamethylpentasiloxane; 3,3-diethyl-1,1,1,5,5,7,7,9,9,9-decamethylpentasiloxane; 1,3,5,7,9-pentaethyl 1,1,3,5,7,9,9-heptamethylpentasiloxane; 3,5,7-triethyl 1,1,1,3,5,7,9,9,9-nonamethylpentasiloxane; 1,1,1-triethyl 3,3,5,5,7,7,9,9,9-nonamethylpentasiloxane; 1-butyl 1,1,3,3,5,5,7,7,9,9,11,11,11-tridecamethyl hexasiloxane;

<Desc / Clms Page number 21>  3,5,7,9-tetraethyl 1,1,1,3,5,7,9,11,11,11-decamethyl hexasiloxane; tetradecamethyl hexasiloxane; hexadecamethylheptasiloxane; octadecamethyl octasiloxane. 11. Composition according to Claim 7, characterized in that the silicone of formula (II) is chosen from: 2- [3,3,3-trimethyl-1,1-bis [(trimethylsilyl) oxy] disiloxanyl] ethyl; 1,1,1,5,5,5-hexamethyl-3- (2-methylpropyl) 3 - [(trimethylsilyl) oxy] trisiloxane; 3- (1,1-dimethylethyl) 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-butyl 1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,5,5,5-hexamethyl-3-propyl-3 - [(trimethylsilyl) oxy] trisiloxane; 3-ethyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1-triethyl 3,5,5,5-tetramethyl-3- (trimethylsiloxy) trisiloxane; 3-methyl-1,1,1,5,5,5-hexamethyl-3- [trimethylsilyl] oxy] trisiloxane; 3 - [(dimethylphenylsilyl) oxy] 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,5,5,5-hexamethyl-3- (2-methylpentyl) 3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,5,5,5-hexamethyl-3- (4-methylpentyl) -3 - [(trimethylsilyl) oxy] trisiloxane; 3-hexyl-1,1,1,5,5,5-hexamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,3,5,5,5-heptamethyl-3 - [(trimethylsilyl) oxy] trisiloxane; 1,1,1,3,5,5,7,7,7-nonamethyl 3- (trimethylsiloxy) tetrasiloxane; 1,1,1,3,3,7,7,7-octamethyl-5-phenyl-5 - [(trimethylsilyl) oxy] tetrasiloxane; 1,1,1,3,5,5,7,7,9,9,11,11,11-tridecamethyl-3 - [(trimethylsilyl) oxy] hexasiloxane. 12. Composition according to claim 8, characterized in that the silicone of formula (III) is 1,1,1,5,5,5-hexamethyl 3,3-bis (trimethylsiloxy) trisiloxane. 13. Composition according to any one of claims 1 to 3 and 5, characterized in that the volatile silicone oil is chosen from: 2,2,8,8-tetramethyl-5 - [(pentamethyldisiloxanyl) methyl] - 3,7-dioxa-2,8-disilanonane; 2,2,5,8,8-pentamethyl-5 - [(trimethylsilyl) methoxy] 4,6-dioxa-2,5,8-trisilanonane; 1,3-dimethyl-1,3-bis [(trimethylsilyl) methyl] 1,3-disiloxanediol; 3-ethyl-1,1,1,5,5,5-hexamethyl-3- [3- (trimethylsiloxy) propyl] trisiloxane; 1,1,1,5,5,5-hexamethyl-3-phenyl-3 - [(trimethylsilyl) oxy] trisiloxane; 2,2,7,7,9,9,11,11,16,16-decamethyl-3,8,10,15-tetraoxa-2,7,9,11,16pentasilaheptadecane; tetrakis [(trimethylsilyl) methyl] silicic acid ester; 3,5-diethyl-1,1,1,7,7,7-hexamethyl-3,5-bis [(trimethylsilyl) oxy] tetrasiloxane, 1,1,1,3,5,7,7,7-octamethyl 3,5-bis [(trimethylsilyl) oxy] tetrasiloxane; 1,1,1,3,7,7,7-heptamethyl 3,5,5-tris [(trimethylsilyl) oxy] tetrasiloxane; 1,1,1,3,5,5,9,9,9-nonamethyl-3,7,7-tris [(trimethylsilyl) oxy] pentasiloxane; 1,1,1,3,5,7,9,9,9-nonamethyl 3,5,7-tris [(trimethylsilyl) oxy] pentasiloxane; 1,1,1,7,7,7-hexamethyl 3,3,5,5-tetrakis [(trimethylsilyl) oxy] tetrasiloxane. 14. Composition according to any one of claims 1 to 3 and 5 to 11, characterized in that the volatile silicone oil is chosen from: <Desc / Clms Page number 22>  decamethyltetrasiloxane; dodecamethylpentasiloxane; 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane; 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane; and their mixtures. 15. Composition according to any one of the preceding claims, characterized in that the volatile silicone fatty phase comprises a mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane. 16. Composition according to the preceding claim, characterized in that dodecamethylpentasiloxane and decamethyltetrasiloxane are present in a weight ratio of dodecamethylpentasiloxane / decamethyltetrasiloxane ranging from 55/45 to 80/20, preferably from 60/40 to 75/25, and preferably from 60/40 to 70/30. 17. A composition comprising, in a physiologically acceptable medium, a volatile silicone silicone phase comprising a mixture of dodecamethylpentasiloxane and decamethyltetrasiloxane in a weight ratio of dodecamethylpentasiloxane / decamethyltetrasiloxane ranging from 55/45 to 80/20. 18. Composition according to the preceding claim, characterized in that the weight ratio of dodecamethylpentasiloxane / decamethyltetrasiloxane ranges from 60/40 to 75/25, and preferably ranges from 60/40 to 70/30. 19. Composition according to any one of claims 1 to 14, characterized in that the volatile fatty phase comprises a mixture of dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane. 20. Composition according to the preceding claim, characterized in that dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane are present in a weight ratio of dodecamethylpentasiloxane / 3-butyl 1,1. , 1,3,5,5,5-heptamethyl trisiloxane ranging from 75/25 to 50/50, preferably ranging from 70/30 to 55/45, and preferably ranging from 65/35 to 55/45. 21. A composition comprising, in a physiologically acceptable medium, a volatile silicone silicone phase comprising a mixture of dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5-heptamethyltrisiloxane in a dodecamethylpentasiloxane / 3-weight ratio. butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane ranging from 75/25 to 50/50. <Desc / Clms Page number 23>  22. Composition according to the preceding claim, characterized in that the weight ratio of dodecamethylpentasiloxane / 3-butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane ranges from 70/30 to 55/45, and preferably ranges from 65/35 to 55/45. 23. Composition according to any one of claims 1 to 14, characterized in that the volatile fatty phase comprises a mixture of decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane. 24. Composition according to the preceding claim, characterized in that the decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane are present in a decamethyltetrasiloxane / 1,1,1 weight ratio, 3,5,5,5heptamethyl-3-hexyl trisiloxane ranging from 25/75 to 45/55, preferably ranging from 30/70 to 40/60, and preferably ranging from 35/65 to 40/60. 25. A composition comprising, in a physiologically acceptable medium, a volatile silicone silicone phase comprising a mixture of decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethyl-3-hexyltrisiloxane in a decamethyltetrasiloxane / 1 weight ratio, 1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane ranging from 25/75 to 45/55. 26. Composition according to the preceding claim, characterized in that the weight ratio of decamethyltetrasiloxane / 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane ranges from 30/70 to 40/60, and preferably ranges from 35/65 to 40/60. 27. Composition according to any one of claims 1 to 14, characterized in that the volatile fatty phase comprises a mixture of 3-hexyl 1,1,1,3,5,5,5-heptamethyl trisiloxane and 3- butyl 1,1,1,3,5,5,5-heptamethyl trisiloxane. 28. Composition according to the preceding claim, characterized in that 3-hexyl 1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-butyl 1,1,1,3,5,5, 5heptamethyl trisiloxane are present in a weight ratio of 3-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane / 3-butyl-1,1,1,3,5,5,5-heptamethyltrisiloxane ranging from 45 / 55 to 70/30, preferably ranging from 50/50 to 65/35, and preferably ranging from 55/45 to 60/40. 29. A composition comprising, in a physiologically acceptable medium, a silicone volatile phase comprising a mixture of 3-hexyl 1,1,1,3,5,5,5heptamethyltrisiloxane and 3-butyl 1,1,1,3, 5,5,5-heptamethyl trisiloxane in a weight ratio of 3-hexyl-1,1,1,3,5,5,5-heptamethyl-trisiloxane / 3-butyl-1,1,1,3,5,5,5-heptamethyl trisiloxane ranging from 45/55 to 70/30. <Desc / Clms Page number 24> 30. Composition according to the preceding claim, characterized in that the weight ratio 3-hexyl 1,1,1,3,5,5,5-heptamethyl trisiloxane / 3-butyl 1,1,1,3,5,5 The 5-heptamethyl trisiloxane ranges from 50/50 to 65/35, and preferably ranges from 55/45 to 60/40. 31. Composition according to any one of the preceding claims, characterized in that the volatile silicone fatty phase contains from 0 to 5% by weight, relative to the total weight of the silicone volatile phase, of cyclic silicone volatile oil, and preferably from 0 to 1% by weight. 32. Composition according to any one of the preceding claims, characterized in that the non-cyclic volatile silicone oil, alone or as a mixture, is present in a content ranging from 1% to 80% by weight, relative to the total weight. of the composition, preferably ranging from 1% to 65% by weight, and preferably ranging from 1% to 50% by weight. 33. Composition according to any one of Claims 15 to 18, characterized in that the dodecamethylpentasiloxane and the decamethyltetrasiloxane are present in a content ranging from 1% to 80% by weight, relative to the total weight of the composition, preferably ranging from from 1% to 65% by weight, and preferably from 1% to 50% by weight. 34. Composition according to any one of Claims 19 to 22, characterized in that dodecamethylpentasiloxane and 3-butyl 1,1,1,3,5,5,5heptamethyltrisiloxane are present in a content ranging from 1% to 80% by weight, relative to the total weight of the composition, preferably ranging from 1% to 65% by weight, and preferably ranging from 1% to 50% by weight. 35. Composition according to any one of claims 23 to 26, characterized in that the decamethyltetrasiloxane and 1,1,1,3,5,5,5-heptamethyl-3-hexyl trisiloxane are present in a content ranging from 1 % to 80% by weight, relative to the total weight of the composition, preferably ranging from 1% to 65% by weight, and preferably ranging from 1% to 50% by weight. 36. Composition according to any one of Claims 27 to 30, characterized in that 3-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane and 3-butyl-1,1,1, 3,5,5,5-heptamethyl trisiloxane are present in a content ranging from 1% to 80% by weight, relative to the total weight of the composition, preferably ranging from 1% to 65% by weight, and preferably ranging from 1% to 50% by weight. 37. Composition according to any one of the preceding claims, characterized in that it comprises a non-silicone volatile oil. <Desc / Clms Page number 25> 38. Composition according to the preceding claim, characterized in that the non-silicone volatile oil is a volatile hydrocarbon oil. 39. Composition according to the preceding claim, characterized in that the volatile hydrocarbon oil is chosen from isododecane, isodecane, isohexadécane, isohexyl neopentanoate and mixtures thereof. 40. Composition according to any one of claims 37 to 39, characterized in that the non-silicone volatile oil is present in a content ranging from 0.1% to 50% by weight, relative to the total weight of the composition. preferably from 0.1% to 40% by weight, and preferably ranging from 0.1% to 30% by weight. 41. Composition according to any one of the preceding claims, characterized in that it comprises a non-volatile oil. 42. Composition according to the preceding claim, characterized in that the non-volatile oil is present in a content ranging from 0.1% to 60% by weight, relative to the total weight of the composition, preferably ranging from 0, 5% to 50% by weight, and preferably ranging from 1% to 40% by weight. 43. Composition according to any one of the preceding claims, characterized in that it comprises a cosmetic or dermatological ingredient chosen from film-forming polymers, fixing polymers; surfactants; conditioners of the hair; dyestuffs; pearling agents; opacifiers; organic solvents; the perfumes ; thickeners; gelling agents; waxes; pasty products; hair dyes; silicone resins; silicone gums; conservatives ; antioxidants, cosmetic active ingredients; solar filters; pH stabilizers; vitamins; moisturizers; antiperspirant agents; deodorants; self-tanning compounds; and their mixtures. 44. Composition according to any one of the preceding claims, characterized in that it is in the form of a care composition of the body or face; cleaning the body or face such as a gel-shower, bath gel, make-up remover; makeup composition for the body or the face such as foundation, lipstick, lip care, nail polish, nail care, mascara, eyeliner; perfume composition; a capillary composition such as a hair coloring composition, a permanent hair deformation composition; sun protection; antiperspirant agents; deodorants; cleaning or hair-care composition such as shampoo, conditioner to be rinsed or not, composition to be rinsed before or after coloring, discoloration, perm or <Desc / Clms Page number 26>  straightening or between the two stages of a perm or straightening; hair composition for maintaining the hairstyle such as a hairspray, a gel, a mousse or a styling spray 45. A cosmetic process for making up or non-therapeutic treatment of keratin materials, comprising applying to the keratin materials a composition according to any one of the preceding claims.