FR2850386B1 - Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle - Google Patents

Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle

Info

Publication number
FR2850386B1
FR2850386B1 FR0300918A FR0300918A FR2850386B1 FR 2850386 B1 FR2850386 B1 FR 2850386B1 FR 0300918 A FR0300918 A FR 0300918A FR 0300918 A FR0300918 A FR 0300918A FR 2850386 B1 FR2850386 B1 FR 2850386B1
Authority
FR
France
Prior art keywords
metallocenes
cyclopentadienyl
bridges
group iii
iii based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0300918A
Other languages
English (en)
Other versions
FR2850386A1 (fr
Inventor
Jean Francois Carpentier
Evgueni Kirillov
Abbas Razavi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Research and Technology Feluy SA
Centre National de la Recherche Scientifique CNRS
Original Assignee
Atofina Research SA
Centre National de la Recherche Scientifique CNRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0300918A priority Critical patent/FR2850386B1/fr
Application filed by Atofina Research SA, Centre National de la Recherche Scientifique CNRS filed Critical Atofina Research SA
Priority to KR1020057013842A priority patent/KR20050094466A/ko
Priority to PCT/EP2004/000643 priority patent/WO2004067591A1/fr
Priority to JP2006501607A priority patent/JP2006515887A/ja
Priority to US10/543,670 priority patent/US7309748B2/en
Priority to EP04704606A priority patent/EP1594906A1/fr
Priority to CNB2004800029095A priority patent/CN100339402C/zh
Publication of FR2850386A1 publication Critical patent/FR2850386A1/fr
Application granted granted Critical
Publication of FR2850386B1 publication Critical patent/FR2850386B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
FR0300918A 2003-01-28 2003-01-28 Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle Expired - Fee Related FR2850386B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR0300918A FR2850386B1 (fr) 2003-01-28 2003-01-28 Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle
PCT/EP2004/000643 WO2004067591A1 (fr) 2003-01-28 2004-01-23 Metallocene ionique ponte du groupe iii a base de ligands de cyclopentadienyl-fluorenyle
JP2006501607A JP2006515887A (ja) 2003-01-28 2004-01-23 シクロペンタジエニル−フルオレニル配位子が基になったイオン性橋かけiii族メタロセン
US10/543,670 US7309748B2 (en) 2003-01-28 2004-01-23 Group III bridged ionic metallocene based on cyclopentadienyl-fluorenyl ligands
KR1020057013842A KR20050094466A (ko) 2003-01-28 2004-01-23 시클로펜타디에닐-플루오레닐 리간드에 기초한 iii족다리걸친 이온성 메탈로센
EP04704606A EP1594906A1 (fr) 2003-01-28 2004-01-23 Metallocene ionique ponte du groupe iii a base de ligands de cyclopentadienyl-fluorenyle
CNB2004800029095A CN100339402C (zh) 2003-01-28 2004-01-23 基于环戊二烯基-芴基配体的ⅲ族桥连的金属茂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0300918A FR2850386B1 (fr) 2003-01-28 2003-01-28 Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle

Publications (2)

Publication Number Publication Date
FR2850386A1 FR2850386A1 (fr) 2004-07-30
FR2850386B1 true FR2850386B1 (fr) 2007-05-11

Family

ID=32669271

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0300918A Expired - Fee Related FR2850386B1 (fr) 2003-01-28 2003-01-28 Metallocenes pontes du groupe iii a base de ligands cyclopentadienyle-fluorenyle

Country Status (7)

Country Link
US (1) US7309748B2 (fr)
EP (1) EP1594906A1 (fr)
JP (1) JP2006515887A (fr)
KR (1) KR20050094466A (fr)
CN (1) CN100339402C (fr)
FR (1) FR2850386B1 (fr)
WO (1) WO2004067591A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1582536A1 (fr) * 2004-03-31 2005-10-05 Total Petrochemicals Research Feluy Préparation d'un homopolymère de styrène et d'un copolymère de styrène et d'éthylène
JP4923553B2 (ja) * 2005-12-15 2012-04-25 宇部興産株式会社 共役ジエン重合体の製造方法
CN112707938A (zh) * 2021-01-06 2021-04-27 上海交通大学 一种四取代的二芴铁类化合物及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3269188B2 (ja) * 1993-07-13 2002-03-25 住友化学工業株式会社 カルボン酸誘導体の製造法
JPH07258319A (ja) * 1994-03-23 1995-10-09 Mitsubishi Rayon Co Ltd 有機金属触媒及びそれを用いたビニル系重合体の製造方法
CN1098284C (zh) * 1997-09-18 2003-01-08 中国石油化工总公司 烯烃聚合和共聚合用茂金属催化体系及其制备方法

Also Published As

Publication number Publication date
WO2004067591A1 (fr) 2004-08-12
US7309748B2 (en) 2007-12-18
EP1594906A1 (fr) 2005-11-16
US20060258827A1 (en) 2006-11-16
JP2006515887A (ja) 2006-06-08
CN1742028A (zh) 2006-03-01
FR2850386A1 (fr) 2004-07-30
KR20050094466A (ko) 2005-09-27
CN100339402C (zh) 2007-09-26

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Effective date: 20110930