FR2806399B1 - Procede d'obtention directe du peroxyde d'hydrogene - Google Patents

Procede d'obtention directe du peroxyde d'hydrogene

Info

Publication number
FR2806399B1
FR2806399B1 FR0003438A FR0003438A FR2806399B1 FR 2806399 B1 FR2806399 B1 FR 2806399B1 FR 0003438 A FR0003438 A FR 0003438A FR 0003438 A FR0003438 A FR 0003438A FR 2806399 B1 FR2806399 B1 FR 2806399B1
Authority
FR
France
Prior art keywords
hydrogen peroxide
direct production
direct
production
peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0003438A
Other languages
English (en)
Other versions
FR2806399A1 (fr
Inventor
Michel Devic
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0003438A priority Critical patent/FR2806399B1/fr
Application filed by Atofina SA filed Critical Atofina SA
Priority to CA002402803A priority patent/CA2402803C/fr
Priority to AU2001235685A priority patent/AU2001235685B2/en
Priority to KR1020027012211A priority patent/KR100584636B1/ko
Priority to PCT/FR2001/000449 priority patent/WO2001068519A1/fr
Priority to CNB01806101XA priority patent/CN1225403C/zh
Priority to EP01907809A priority patent/EP1263680A1/fr
Priority to JP2001567626A priority patent/JP4175534B2/ja
Priority to AU3568501A priority patent/AU3568501A/xx
Priority to US10/221,339 priority patent/US7060244B2/en
Publication of FR2806399A1 publication Critical patent/FR2806399A1/fr
Application granted granted Critical
Publication of FR2806399B1 publication Critical patent/FR2806399B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/013—Separation; Purification; Concentration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/029—Preparation from hydrogen and oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00141—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2208/00292—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids
    • B01J2208/003—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant solids involving reactant slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00031—Semi-batch or fed-batch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/00114—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant slurries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR0003438A 2000-03-17 2000-03-17 Procede d'obtention directe du peroxyde d'hydrogene Expired - Fee Related FR2806399B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR0003438A FR2806399B1 (fr) 2000-03-17 2000-03-17 Procede d'obtention directe du peroxyde d'hydrogene
AU3568501A AU3568501A (en) 2000-03-17 2001-02-15 Method for directly obtaining hydrogen peroxide
KR1020027012211A KR100584636B1 (ko) 2000-03-17 2001-02-15 과산화수소의 직접적인 수득 방법
PCT/FR2001/000449 WO2001068519A1 (fr) 2000-03-17 2001-02-15 Procede d'obtention directe du peroxyde d'hydrogene
CNB01806101XA CN1225403C (zh) 2000-03-17 2001-02-15 直接获得过氧化氢的方法
EP01907809A EP1263680A1 (fr) 2000-03-17 2001-02-15 Procede d'obtention directe du peroxyde d'hydrogene
CA002402803A CA2402803C (fr) 2000-03-17 2001-02-15 Procede d'obtention directe du peroxyde d'hydrogene
AU2001235685A AU2001235685B2 (en) 2000-03-17 2001-02-15 Method for directly obtaining hydrogen peroxide
US10/221,339 US7060244B2 (en) 2000-03-17 2001-02-15 Method for directly obtaining hydrogen peroxide
JP2001567626A JP4175534B2 (ja) 2000-03-17 2001-02-15 過酸化水素を直接得る方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0003438A FR2806399B1 (fr) 2000-03-17 2000-03-17 Procede d'obtention directe du peroxyde d'hydrogene

Publications (2)

Publication Number Publication Date
FR2806399A1 FR2806399A1 (fr) 2001-09-21
FR2806399B1 true FR2806399B1 (fr) 2002-09-13

Family

ID=8848206

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0003438A Expired - Fee Related FR2806399B1 (fr) 2000-03-17 2000-03-17 Procede d'obtention directe du peroxyde d'hydrogene

Country Status (9)

Country Link
US (1) US7060244B2 (fr)
EP (1) EP1263680A1 (fr)
JP (1) JP4175534B2 (fr)
KR (1) KR100584636B1 (fr)
CN (1) CN1225403C (fr)
AU (2) AU2001235685B2 (fr)
CA (1) CA2402803C (fr)
FR (1) FR2806399B1 (fr)
WO (1) WO2001068519A1 (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10052323A1 (de) 2000-10-21 2002-05-02 Degussa Kontinierliches Verfahren zur Hydrierung
FR2832937B1 (fr) 2001-12-04 2004-01-16 Technip France Procede et dispositif de reaction chimique entre un gaz et au moins un compose en solution, mis en oeuvre en presence d'un catalyseur solide
US7067103B2 (en) * 2003-03-28 2006-06-27 Headwaters Nanokinetix, Inc. Direct hydrogen peroxide production using staged hydrogen addition
US7569508B2 (en) * 2004-11-17 2009-08-04 Headwaters Technology Innovation, Llc Reforming nanocatalysts and method of making and using such catalysts
US7011807B2 (en) * 2003-07-14 2006-03-14 Headwaters Nanokinetix, Inc. Supported catalysts having a controlled coordination structure and methods for preparing such catalysts
US7655137B2 (en) 2003-07-14 2010-02-02 Headwaters Technology Innovation, Llc Reforming catalysts having a controlled coordination structure and methods for preparing such compositions
US7045479B2 (en) * 2003-07-14 2006-05-16 Headwaters Nanokinetix, Inc. Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions
US7144565B2 (en) * 2003-07-29 2006-12-05 Headwaters Nanokinetix, Inc. Process for direct catalytic hydrogen peroxide production
US7122166B2 (en) * 2004-05-11 2006-10-17 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Concentration of hydrogen peroxide
US7632775B2 (en) * 2004-11-17 2009-12-15 Headwaters Technology Innovation, Llc Multicomponent nanoparticles formed using a dispersing agent
JP4655755B2 (ja) * 2005-05-18 2011-03-23 住友化学株式会社 過酸化水素の製造方法
US7396795B2 (en) * 2005-08-31 2008-07-08 Headwaters Technology Innovation, Llc Low temperature preparation of supported nanoparticle catalysts having increased dispersion
US7718710B2 (en) * 2006-03-17 2010-05-18 Headwaters Technology Innovation, Llc Stable concentrated metal colloids and methods of making same
US7541309B2 (en) * 2006-05-16 2009-06-02 Headwaters Technology Innovation, Llc Reforming nanocatalysts and methods of making and using such catalysts
US7601668B2 (en) * 2006-09-29 2009-10-13 Headwaters Technology Innovation, Llc Methods for manufacturing bi-metallic catalysts having a controlled crystal face exposure
US8834357B2 (en) * 2008-11-12 2014-09-16 Boston Scientific Scimed, Inc. Steering mechanism
US20100152022A1 (en) * 2008-12-17 2010-06-17 Qi Sun Catalyst regeneration method
KR101474571B1 (ko) * 2009-05-13 2014-12-19 에스케이이노베이션 주식회사 고분자 전해질 다층박막 촉매 및 그 제조 방법
US8986534B2 (en) 2011-11-14 2015-03-24 Saudi Arabian Oil Company Method for removing oxygen from a reaction medium
DE102016204717A1 (de) 2016-03-22 2017-09-28 Siemens Aktiengesellschaft Reaktor zur Durchführung von gleichgewichtslimitierten Reaktionen
DE102016204718A1 (de) 2016-03-22 2017-09-28 Siemens Aktiengesellschaft Reaktor
CN107715917B (zh) * 2016-08-10 2020-04-21 中国科学院大连化学物理研究所 含磷酸性交联聚合物负载钯纳米催化剂及制备和应用
CN112642383A (zh) * 2020-12-22 2021-04-13 山东滨农科技有限公司 一种防护效果好的硝磺草酮合成的酰氯化装置

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900468A (en) * 1985-06-17 1990-02-13 The Clorox Company Stabilized liquid hydrogen peroxide bleach compositions
US5180514A (en) * 1985-06-17 1993-01-19 The Clorox Company Stabilizing system for liquid hydrogen peroxide compositions
US4772458A (en) * 1986-11-19 1988-09-20 E. I. Du Pont De Nemours And Company Catalytic process for making hydrogen peroxide from hydrogen and oxygen employing a bromide promoter
EP0351772A3 (fr) * 1988-07-19 1990-07-04 HENKEL CORPORATION (a Delaware corp.) Peroxyde d'hydrogène stabilisé
US5194242A (en) * 1990-09-11 1993-03-16 E. I. Du Pont De Nemours And Company Process for the production of hydrogen peroxide from hydrogen and oxygen
JPH0532404A (ja) * 1991-02-08 1993-02-09 Mitsubishi Gas Chem Co Inc 過酸化水素の製造方法
US5641467A (en) * 1994-08-16 1997-06-24 Princeton Advanced Technology, Inc. Method for producing hydrogen peroxide from hydrogen and oxygen
US6042804A (en) * 1994-08-16 2000-03-28 Advanced Peroxide Technology, Inc. Method for producing hydrogen peroxide from hydrogen and oxygen
CA2197655A1 (fr) * 1994-08-16 1996-02-22 Harold A. Huckins Methode et appareil pour l'obtention de peroxyde d'hydrogene a partir d'hydrogene et d'oxygene
EP0930269B1 (fr) * 1998-01-16 2002-11-27 Ausimont S.p.A. Procédé de production industrielle d' eau oxygénée de haute pureté
FR2774674B1 (fr) * 1998-02-10 2000-03-24 Atochem Elf Sa Procede de preparation d'une solution aqueuse de peroxyde d'hydrogene directement a partir d'hydrogene et d'oxygene et dispositif permettant sa mise en oeuvre

Also Published As

Publication number Publication date
CA2402803C (fr) 2007-10-16
WO2001068519A1 (fr) 2001-09-20
EP1263680A1 (fr) 2002-12-11
US7060244B2 (en) 2006-06-13
AU3568501A (en) 2001-09-24
US20030086853A1 (en) 2003-05-08
FR2806399A1 (fr) 2001-09-21
KR100584636B1 (ko) 2006-05-30
KR20020092387A (ko) 2002-12-11
AU2001235685B2 (en) 2004-09-30
CN1411422A (zh) 2003-04-16
JP2003527283A (ja) 2003-09-16
JP4175534B2 (ja) 2008-11-05
CA2402803A1 (fr) 2001-09-20
CN1225403C (zh) 2005-11-02

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Effective date: 20151130