FR2582234B1 - Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur - Google Patents

Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur

Info

Publication number
FR2582234B1
FR2582234B1 FR8507772A FR8507772A FR2582234B1 FR 2582234 B1 FR2582234 B1 FR 2582234B1 FR 8507772 A FR8507772 A FR 8507772A FR 8507772 A FR8507772 A FR 8507772A FR 2582234 B1 FR2582234 B1 FR 2582234B1
Authority
FR
France
Prior art keywords
catalyst
preparation
thermal stability
high thermal
type zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
FR8507772A
Other languages
English (en)
Other versions
FR2582234A1 (fr
Inventor
Francois Fajula
Francois Figueras
Latifa Moudafi
Mercedes Vera Pacheco
Serge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to FR8507772A priority Critical patent/FR2582234B1/fr
Priority to US06/865,179 priority patent/US4891200A/en
Priority to IT8620511A priority patent/IT1208615B/it
Priority to DE3616983A priority patent/DE3616983C2/de
Priority to BE0/216685A priority patent/BE904797A/fr
Priority to JP61116327A priority patent/JPH0751443B2/ja
Priority to NL8601313A priority patent/NL193425C/nl
Priority to BR8602326A priority patent/BR8602326A/pt
Priority to GB08612508A priority patent/GB2175890B/en
Publication of FR2582234A1 publication Critical patent/FR2582234A1/fr
Application granted granted Critical
Publication of FR2582234B1 publication Critical patent/FR2582234B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/34—Type ZSM-4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/26—Mazzite, e.g. ZSM-4, omega

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
FR8507772A 1985-05-23 1985-05-23 Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur Expired - Lifetime FR2582234B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR8507772A FR2582234B1 (fr) 1985-05-23 1985-05-23 Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur
US06/865,179 US4891200A (en) 1985-05-23 1986-05-19 Omega type zeolite having high thermal stability, its process of preparation and its utilization
DE3616983A DE3616983C2 (de) 1985-05-23 1986-05-21 Omegazeolith mit erhöhter Wärmebeständigkeit, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator
BE0/216685A BE904797A (fr) 1985-05-23 1986-05-21 Zeolite de type omega a stabilite thermique elevee son procede de preparation et son utilisation comme catalyseur.
IT8620511A IT1208615B (it) 1985-05-23 1986-05-21 Zeolite di tipo omega a stabilita'termica elevata, procedimento per la sua preparazione e suo impiegocome catalizzatore.
JP61116327A JPH0751443B2 (ja) 1985-05-23 1986-05-22 熱安定性ｗ型ゼオライト、その製造方法及び利用方法
NL8601313A NL193425C (nl) 1985-05-23 1986-05-22 Werkwijze voor het bereiden van een zeoliet en zijn toepassing als katalysator.
BR8602326A BR8602326A (pt) 1985-05-23 1986-05-22 Zeolito de elevada estabilidade termica,processo para sintese do mesmo,processo catalitico para hidratacao de olefinas em alcoois e processo catalitico para isomerizacao de xilenos
GB08612508A GB2175890B (en) 1985-05-23 1986-05-22 Omega type zeolite having high thermal stability, its process of preparation and its utilization

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8507772A FR2582234B1 (fr) 1985-05-23 1985-05-23 Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur

Publications (2)

Publication Number Publication Date
FR2582234A1 FR2582234A1 (fr) 1986-11-28
FR2582234B1 true FR2582234B1 (fr) 1993-03-12

Family

ID=9319500

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8507772A Expired - Lifetime FR2582234B1 (fr) 1985-05-23 1985-05-23 Zeolite de type omega a stabilite thermique elevee, son procede de preparation et son utilisation comme catalyseur

Country Status (9)

Country Link
US (1) US4891200A (fr)
JP (1) JPH0751443B2 (fr)
BE (1) BE904797A (fr)
BR (1) BR8602326A (fr)
DE (1) DE3616983C2 (fr)
FR (1) FR2582234B1 (fr)
GB (1) GB2175890B (fr)
IT (1) IT1208615B (fr)
NL (1) NL193425C (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2651221B1 (fr) * 1989-08-30 1991-11-08 Elf Aquitaine Nouvelle zeolithe de la famille de la mazzite son procede de synthese et son utilisation comme catalyseur.
US5236877A (en) * 1990-12-04 1993-08-17 W. R. Grace & Co.-Conn. Dual zeolite fluid cracking catalyst composition for improved gasoline octane
US5139761A (en) * 1990-12-17 1992-08-18 Uop Modified zeolite omega and processes for preparing and using same
US5230790A (en) * 1990-12-17 1993-07-27 Uop Hydrocarbon conversion processes using modified zeolite Omega
AU643908B1 (en) * 1990-12-17 1993-11-25 Uop Modified zeolite omega and methods for preparing and for using same
FR2698862B1 (fr) * 1992-12-08 1995-01-13 Elf Aquitaine Procédé de synthèse d'un aluminosilicate cristallin enrichi en silice, ayant la structure de la mazzite, l'aluminosilicate obtenu et son utilisation comme catalyseur de transformation des hydrocarbures.
FR2744441B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines
FR2744458B1 (fr) 1996-02-05 1998-03-27 Inst Francais Du Petrole Procede d'isomerisation de paraffines par distillation reactive
FR2749577B1 (fr) * 1996-06-06 1998-07-31 Elf Aquitaine Mazzite activee enrichie en silice, procede d'obtention et application
NO302559B1 (no) * 1996-06-27 1998-03-23 Norsk Leca As Fremstilling av uorganisk kationebytter fra kuler av ekspandert leire samt anvendelse av de fremstilte kationbyttere
FR2750893B1 (fr) * 1996-07-12 1998-10-30 Elf Aquitaine Procede de synthese de zeolithe avec agitation homogene du milieu, dispositif et application
CN1093511C (zh) * 1999-08-17 2002-10-30 中国石油化工集团公司 一种制备ω沸石的方法
US6451283B1 (en) * 2000-03-23 2002-09-17 Engelhard Corporation Macroscopic aggregates of microcrystalline zeolites
US6419895B1 (en) * 2000-11-03 2002-07-16 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-4
US6572776B2 (en) * 2000-12-14 2003-06-03 Engelhard Corporation Method of static water softening using zeolites of novel morphology
US6685910B2 (en) 2000-12-14 2004-02-03 Engelhard Corporation Macroscopic aggregates of microcrystalline zeolites for static water softening applications
US8158104B2 (en) * 2010-07-01 2012-04-17 Uop Llc UZM-7 aluminosilicate zeolite, method of preparation and processes using UZM-7

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511975A (en) * 1939-03-18 1950-06-20 Barr & Stroud Ltd Micrometer eyepiece for optical measuring instruments
US3185544A (en) * 1962-07-02 1965-05-25 Grace W R & Co Preparation of crystalline zeolites of uniform and controlled particle size
US3414602A (en) * 1965-07-01 1968-12-03 Union Carbide Corp Zeolite n and process for preparing same
DE1567714C3 (de) * 1965-11-24 1979-01-18 Mobil Oil Corp., New York, N.Y. (V.St.A.) Kristalliner Aluminosilicatzeolith
US3578723A (en) * 1968-04-18 1971-05-11 Mobil Oil Corp Isomerization and disproportionation of aromatic hydrocarbons
US3923639A (en) * 1968-04-18 1975-12-02 Mobil Oil Corp Converting hydrocarbons with zeolite ZSM-4
CA950888A (en) * 1968-12-30 1974-07-09 Charles J. Plank Crystallization of zeolite
NL7018223A (fr) * 1969-12-18 1971-06-22
US3914331A (en) * 1970-12-23 1975-10-21 Mobil Oil Corp Disproportionation of aliphatic compounds
US4091007A (en) * 1972-12-01 1978-05-23 Mobil Oil Corporation Preparation of zeolites
US3947482A (en) * 1974-03-20 1976-03-30 W. R. Grace & Co. Method for producing open framework zeolites
US4021447A (en) * 1975-04-30 1977-05-03 Mobil Oil Corporation Synthesis of zeolite ZSM-4
US4241036A (en) * 1975-10-23 1980-12-23 Union Carbide Corporation Synthetic crystalline zeolite and process for preparing same
CA1166620A (fr) * 1981-07-01 1984-05-01 English Clays Lovering Pochin & Company Limited Fabrication de zeolites
NZ208048A (en) * 1983-05-26 1986-10-08 Mobil Oil Corp Method for synthesising zeolites,incorporating alumina source of limited solubility
US4552731A (en) * 1983-11-10 1985-11-12 Exxon Research And Engineering Co. Process for preparing crystalline zeolite composition ERC-2

Also Published As

Publication number Publication date
NL193425B (nl) 1999-06-01
IT1208615B (it) 1989-07-10
US4891200A (en) 1990-01-02
GB2175890A (en) 1986-12-10
DE3616983C2 (de) 1997-03-13
JPS62275015A (ja) 1987-11-30
BR8602326A (pt) 1987-01-21
NL8601313A (nl) 1986-12-16
NL193425C (nl) 1999-10-04
GB2175890B (en) 1988-08-17
DE3616983A1 (de) 1986-11-27
BE904797A (fr) 1986-09-15
GB8612508D0 (en) 1986-07-02
JPH0751443B2 (ja) 1995-06-05
FR2582234A1 (fr) 1986-11-28
IT8620511A0 (it) 1986-05-21

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