FR2526414A1 - Matieres synthetiques cristallines et poreuses constituees par des oxydes de silicium et de bore, leur procede de preparation et leur utilisation - Google Patents
Matieres synthetiques cristallines et poreuses constituees par des oxydes de silicium et de bore, leur procede de preparation et leur utilisation Download PDFInfo
- Publication number
- FR2526414A1 FR2526414A1 FR8307488A FR8307488A FR2526414A1 FR 2526414 A1 FR2526414 A1 FR 2526414A1 FR 8307488 A FR8307488 A FR 8307488A FR 8307488 A FR8307488 A FR 8307488A FR 2526414 A1 FR2526414 A1 FR 2526414A1
- Authority
- FR
- France
- Prior art keywords
- crystalline
- synthetic materials
- porous synthetic
- chosen
- molar ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010703 silicon Substances 0.000 title claims abstract description 9
- 229910052810 boron oxide Inorganic materials 0.000 title claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 title claims description 4
- 239000000463 material Substances 0.000 title abstract description 7
- 238000000034 method Methods 0.000 title description 6
- 238000002360 preparation method Methods 0.000 title description 6
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 claims abstract description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 229920002994 synthetic fiber Polymers 0.000 claims description 15
- 239000002585 base Substances 0.000 claims description 10
- 238000001228 spectrum Methods 0.000 claims description 8
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 8
- 238000002441 X-ray diffraction Methods 0.000 claims description 7
- 150000001768 cations Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 6
- -1 alkali metal cation Chemical class 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 150000001638 boron Chemical class 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 235000010338 boric acid Nutrition 0.000 claims description 2
- IJRVQAXSAHHCNH-UHFFFAOYSA-M butyl(trimethyl)azanium;hydroxide Chemical group [OH-].CCCC[N+](C)(C)C IJRVQAXSAHHCNH-UHFFFAOYSA-M 0.000 claims description 2
- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical class O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims 4
- QCOGKXLOEWLIDC-UHFFFAOYSA-O butyl(methyl)azanium Chemical compound CCCC[NH2+]C QCOGKXLOEWLIDC-UHFFFAOYSA-O 0.000 claims 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- HVMLGVVFRKCJOV-UHFFFAOYSA-N dibutyl(dimethyl)azanium Chemical compound CCCC[N+](C)(C)CCCC HVMLGVVFRKCJOV-UHFFFAOYSA-N 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 abstract description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical class [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 4
- JLMKXBLSZPRYPU-UHFFFAOYSA-N [OH-].C(CCC)[NH2+]C Chemical compound [OH-].C(CCC)[NH2+]C JLMKXBLSZPRYPU-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 150000003376 silicon Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 2
- 239000005695 Ammonium acetate Substances 0.000 description 2
- 108091065810 E family Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000019257 ammonium acetate Nutrition 0.000 description 2
- 229940043376 ammonium acetate Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 2
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 2
- QVOFCQBZXGLNAA-UHFFFAOYSA-M tributyl(methyl)azanium;hydroxide Chemical compound [OH-].CCCC[N+](C)(CCCC)CCCC QVOFCQBZXGLNAA-UHFFFAOYSA-M 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 101100424627 Caenorhabditis elegans mec-12 gene Proteins 0.000 description 1
- 229910002483 Cu Ka Inorganic materials 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-O Methylammonium ion Chemical compound [NH3+]C BAVYZALUXZFZLV-UHFFFAOYSA-O 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1009—Compounds containing boron and oxygen having molecular-sieve properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/08—Compounds containing halogen
- C01B33/10—Compounds containing silicon, fluorine, and other elements
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21132/82A IT1157932B (it) | 1982-05-07 | 1982-05-07 | Materiali sintetici, cristallini, porosi costituiti da ossidi di silicio e boro, loro metodo di preparazione e loro usi |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2526414A1 true FR2526414A1 (fr) | 1983-11-10 |
| FR2526414B1 FR2526414B1 (enrdf_load_stackoverflow) | 1985-04-19 |
Family
ID=11177209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8307488A Granted FR2526414A1 (fr) | 1982-05-07 | 1983-05-05 | Matieres synthetiques cristallines et poreuses constituees par des oxydes de silicium et de bore, leur procede de preparation et leur utilisation |
Country Status (23)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1986007045A1 (fr) * | 1985-05-28 | 1986-12-04 | Institut Francais Du Petrole | Zeolites du type borosilicate contenant du fluor |
| EP0265018A2 (en) | 1986-10-22 | 1988-04-27 | ENIRICERCHE S.p.A. | Bonded zeolites and process for preparing them |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU634962B2 (en) * | 1988-06-10 | 1993-03-11 | Kohmix Co., Ltd. | Water-Soluble, film-forming inorganic compounds |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2429182A1 (fr) * | 1978-06-22 | 1980-01-18 | Snam Progetti | Materiaux synthetiques a base de silice |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN146957B (enrdf_load_stackoverflow) * | 1976-10-18 | 1979-10-20 | Standard Oil Co | |
| US4331641A (en) * | 1979-11-07 | 1982-05-25 | National Distillers & Chemical Corp. | Synthetic crystalline metal silicate compositions and preparation thereof |
-
1982
- 1982-05-07 IT IT21132/82A patent/IT1157932B/it active
-
1983
- 1983-04-11 GR GR71163A patent/GR78258B/el unknown
- 1983-04-21 AU AU13839/83A patent/AU1383983A/en not_active Abandoned
- 1983-04-22 ZW ZW91/83A patent/ZW9183A1/xx unknown
- 1983-04-26 ZA ZA832934A patent/ZA832934B/xx unknown
- 1983-04-26 GB GB08311310A patent/GB2120226B/en not_active Expired
- 1983-04-27 YU YU00954/83A patent/YU95483A/xx unknown
- 1983-05-01 IL IL68543A patent/IL68543A0/xx unknown
- 1983-05-03 DK DK195883A patent/DK195883A/da not_active Application Discontinuation
- 1983-05-03 BR BR8302358A patent/BR8302358A/pt unknown
- 1983-05-04 NL NL8301590A patent/NL8301590A/nl not_active Application Discontinuation
- 1983-05-05 NO NO831584A patent/NO831584L/no unknown
- 1983-05-05 SE SE8302576A patent/SE8302576L/ not_active Application Discontinuation
- 1983-05-05 DE DE19833316488 patent/DE3316488A1/de not_active Ceased
- 1983-05-05 FR FR8307488A patent/FR2526414A1/fr active Granted
- 1983-05-06 BE BE0/210720A patent/BE896686A/fr not_active IP Right Cessation
- 1983-05-06 PT PT76656A patent/PT76656B/pt unknown
- 1983-05-06 ES ES522608A patent/ES8406380A1/es not_active Expired
- 1983-05-06 LU LU84790A patent/LU84790A1/fr unknown
- 1983-05-06 PL PL24183883A patent/PL241838A1/xx unknown
- 1983-05-06 DD DD83250710A patent/DD209795A5/de unknown
- 1983-05-06 JP JP58078389A patent/JPS58208129A/ja active Pending
- 1983-05-07 KR KR1019830001960A patent/KR840004534A/ko not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2429182A1 (fr) * | 1978-06-22 | 1980-01-18 | Snam Progetti | Materiaux synthetiques a base de silice |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1986007045A1 (fr) * | 1985-05-28 | 1986-12-04 | Institut Francais Du Petrole | Zeolites du type borosilicate contenant du fluor |
| FR2582639A1 (fr) * | 1985-05-28 | 1986-12-05 | Centre Nat Rech Scient | Nouveau procede de synthese de zeolites du type borosilicate, produits ainsi obtenus et leur utilisation |
| EP0265018A2 (en) | 1986-10-22 | 1988-04-27 | ENIRICERCHE S.p.A. | Bonded zeolites and process for preparing them |
Also Published As
| Publication number | Publication date |
|---|---|
| ES522608A0 (es) | 1984-08-01 |
| IT8221132A0 (it) | 1982-05-07 |
| NO831584L (no) | 1983-11-08 |
| AU1383983A (en) | 1983-11-10 |
| YU95483A (en) | 1985-10-31 |
| ZW9183A1 (en) | 1983-07-20 |
| DE3316488A1 (de) | 1983-11-10 |
| DK195883A (da) | 1983-11-08 |
| DK195883D0 (da) | 1983-05-03 |
| IL68543A0 (en) | 1983-09-30 |
| GB2120226A (en) | 1983-11-30 |
| IT1157932B (it) | 1987-02-18 |
| KR840004534A (ko) | 1984-10-22 |
| PT76656A (en) | 1983-06-01 |
| GB2120226B (en) | 1985-10-23 |
| BR8302358A (pt) | 1984-01-10 |
| GB8311310D0 (en) | 1983-06-02 |
| PL241838A1 (en) | 1984-06-18 |
| NL8301590A (nl) | 1983-12-01 |
| ZA832934B (en) | 1984-04-25 |
| GR78258B (enrdf_load_stackoverflow) | 1984-09-26 |
| ES8406380A1 (es) | 1984-08-01 |
| PT76656B (en) | 1986-04-16 |
| JPS58208129A (ja) | 1983-12-03 |
| BE896686A (fr) | 1983-11-07 |
| SE8302576D0 (sv) | 1983-05-05 |
| LU84790A1 (fr) | 1984-03-07 |
| SE8302576L (sv) | 1983-11-08 |
| DD209795A5 (de) | 1984-05-23 |
| FR2526414B1 (enrdf_load_stackoverflow) | 1985-04-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |