FR2518218A1 - Materiau candoluminescent, son procede de preparation et son utilisation comme manchon de lampe a gaz - Google Patents
Materiau candoluminescent, son procede de preparation et son utilisation comme manchon de lampe a gaz Download PDFInfo
- Publication number
- FR2518218A1 FR2518218A1 FR8123202A FR8123202A FR2518218A1 FR 2518218 A1 FR2518218 A1 FR 2518218A1 FR 8123202 A FR8123202 A FR 8123202A FR 8123202 A FR8123202 A FR 8123202A FR 2518218 A1 FR2518218 A1 FR 2518218A1
- Authority
- FR
- France
- Prior art keywords
- oxide
- salts
- oxides
- zirconium
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 claims abstract description 40
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000292 calcium oxide Substances 0.000 claims abstract description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 14
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 12
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001928 zirconium oxide Inorganic materials 0.000 claims abstract description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 6
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims abstract description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 22
- 239000004753 textile Substances 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 13
- 238000002485 combustion reaction Methods 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052684 Cerium Inorganic materials 0.000 claims description 11
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 11
- 235000013980 iron oxide Nutrition 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 159000000007 calcium salts Chemical class 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 159000000003 magnesium salts Chemical class 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 159000000014 iron salts Chemical class 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 4
- 150000000703 Cerium Chemical class 0.000 claims 2
- 150000003754 zirconium Chemical class 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 12
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 12
- 239000000243 solution Substances 0.000 description 32
- 239000004744 fabric Substances 0.000 description 13
- 229910052776 Thorium Inorganic materials 0.000 description 10
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 9
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 8
- 229910003452 thorium oxide Inorganic materials 0.000 description 8
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 7
- 238000005470 impregnation Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000002285 radioactive effect Effects 0.000 description 3
- XQVKLMRIZCRVPO-UHFFFAOYSA-N 4-[(2-arsonophenyl)diazenyl]-3-hydroxynaphthalene-2,7-disulfonic acid Chemical compound C12=CC=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(O)=C1N=NC1=CC=CC=C1[As](O)(O)=O XQVKLMRIZCRVPO-UHFFFAOYSA-N 0.000 description 2
- 241000679125 Thoron Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000010987 cubic zirconia Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000005338 frosted glass Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- WABPQHHGFIMREM-OUBTZVSYSA-N lead-208 Chemical compound [208Pb] WABPQHHGFIMREM-OUBTZVSYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000003758 nuclear fuel Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000035935 pregnancy Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21H—INCANDESCENT MANTLES; OTHER INCANDESCENT BODIES HEATED BY COMBUSTION
- F21H1/00—Incandescent mantles; Selection of imbibition liquids therefor
- F21H1/02—Incandescent mantles; Selection of imbibition liquids therefor characterised by the material thereof
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Glass Compositions (AREA)
- Disintegrating Or Milling (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8123202A FR2518218A1 (fr) | 1981-12-11 | 1981-12-11 | Materiau candoluminescent, son procede de preparation et son utilisation comme manchon de lampe a gaz |
| DE8282402227T DE3262717D1 (en) | 1981-12-11 | 1982-12-06 | Candoluminescent material, method of preparation and use as an incandescent mantle |
| EP82402227A EP0082062B1 (fr) | 1981-12-11 | 1982-12-06 | Matériau candoluminescent, son procédé de préparation et son utilisation comme manchon de lampe à gaz |
| AT82402227T ATE12303T1 (de) | 1981-12-11 | 1982-12-06 | Candolumineszierendes material, verfahren zu seiner herstellung und seine anwendung als gasgluehlichtstrumpf. |
| MT920A MTP920B (en) | 1981-12-11 | 1982-12-06 | Candolumenescent material,its prepartros process and its use as a gaslamp mantle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8123202A FR2518218A1 (fr) | 1981-12-11 | 1981-12-11 | Materiau candoluminescent, son procede de preparation et son utilisation comme manchon de lampe a gaz |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2518218A1 true FR2518218A1 (fr) | 1983-06-17 |
| FR2518218B1 FR2518218B1 (enrdf_load_stackoverflow) | 1984-02-03 |
Family
ID=9264927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8123202A Granted FR2518218A1 (fr) | 1981-12-11 | 1981-12-11 | Materiau candoluminescent, son procede de preparation et son utilisation comme manchon de lampe a gaz |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0082062B1 (enrdf_load_stackoverflow) |
| AT (1) | ATE12303T1 (enrdf_load_stackoverflow) |
| DE (1) | DE3262717D1 (enrdf_load_stackoverflow) |
| FR (1) | FR2518218A1 (enrdf_load_stackoverflow) |
| MT (1) | MTP920B (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2762003A1 (fr) * | 1997-04-15 | 1998-10-16 | Commissariat Energie Atomique | Materiau candoluminescent, son procede de preparation et son utilisation dans des manchons durs pour l'eclairage public au gaz |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4532073A (en) * | 1983-02-25 | 1985-07-30 | Commissariat A L'energie Atomique | Candoluminescent material and its preparation |
| FR2560604B1 (fr) * | 1984-03-02 | 1986-09-05 | Commissariat Energie Atomique | Nouveau materiau candoluminescent et son procede de preparation |
| DE19715413C1 (de) * | 1997-04-10 | 1998-10-15 | Auergesellschaft Gmbh | Verfahren zur Herstellung eines thoriumfreien Gasglühkörpers sowie mit dem Verfahren hergestellter Gasglühkörper |
| GB9812110D0 (en) | 1998-06-06 | 1998-08-05 | Levelrecall Limited | Yttrium oxide based gas mantle |
| EP1331435A1 (de) | 2002-01-23 | 2003-07-30 | MSA Auer GmbH | Gasglühkörper und Verfahren zu dessen Herstellung |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE105172C (enrdf_load_stackoverflow) * | ||||
| FR403195A (fr) * | 1909-01-22 | 1909-10-27 | Vivian Byam Lewes | Perfectionnements apportés aux manchons à gaz à incandescence |
-
1981
- 1981-12-11 FR FR8123202A patent/FR2518218A1/fr active Granted
-
1982
- 1982-12-06 AT AT82402227T patent/ATE12303T1/de not_active IP Right Cessation
- 1982-12-06 MT MT920A patent/MTP920B/xx unknown
- 1982-12-06 EP EP82402227A patent/EP0082062B1/fr not_active Expired
- 1982-12-06 DE DE8282402227T patent/DE3262717D1/de not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE105172C (enrdf_load_stackoverflow) * | ||||
| FR403195A (fr) * | 1909-01-22 | 1909-10-27 | Vivian Byam Lewes | Perfectionnements apportés aux manchons à gaz à incandescence |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2762003A1 (fr) * | 1997-04-15 | 1998-10-16 | Commissariat Energie Atomique | Materiau candoluminescent, son procede de preparation et son utilisation dans des manchons durs pour l'eclairage public au gaz |
| EP0872686A1 (fr) * | 1997-04-15 | 1998-10-21 | Commissariat A L'energie Atomique | Matériau candoluminescent, son procédé de préparation et son utilisation dans des manchons durs pour l'éclairage public au gaz |
| US5904881A (en) * | 1997-04-15 | 1999-05-18 | Commissariat A L'energie Atomique | Procedure for preparing a incandescent material and its use in hard mantles for gas lighting of public places |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3262717D1 (en) | 1985-04-25 |
| EP0082062A1 (fr) | 1983-06-22 |
| EP0082062B1 (fr) | 1985-03-20 |
| MTP920B (en) | 1984-02-13 |
| ATE12303T1 (de) | 1985-04-15 |
| FR2518218B1 (enrdf_load_stackoverflow) | 1984-02-03 |
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