FR2509741A1 - Melange stabilisant non toxique destine a des polymeres halogenes - Google Patents
Melange stabilisant non toxique destine a des polymeres halogenes Download PDFInfo
- Publication number
- FR2509741A1 FR2509741A1 FR8212344A FR8212344A FR2509741A1 FR 2509741 A1 FR2509741 A1 FR 2509741A1 FR 8212344 A FR8212344 A FR 8212344A FR 8212344 A FR8212344 A FR 8212344A FR 2509741 A1 FR2509741 A1 FR 2509741A1
- Authority
- FR
- France
- Prior art keywords
- tin
- dodecyl
- weight
- polymers
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000087 stabilizing effect Effects 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 229920000642 polymer Polymers 0.000 title claims abstract description 7
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 4
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 4
- -1 RADICAL ETHYL-2 HEXYL Chemical class 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims abstract description 3
- 239000012778 molding material Substances 0.000 claims abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 235000013305 food Nutrition 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract description 3
- 238000004806 packaging method and process Methods 0.000 abstract description 3
- 239000000825 pharmaceutical preparation Substances 0.000 abstract description 3
- 229940127557 pharmaceutical product Drugs 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000005022 packaging material Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- VDEKURXOWJYWCG-UHFFFAOYSA-N dodecyltin Chemical compound CCCCCCCCCCCC[Sn] VDEKURXOWJYWCG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 8
- 230000009471 action Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 241000700159 Rattus Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RPPZINJJZONDRV-UHFFFAOYSA-K 2-[bis(carboxymethylsulfanyl)-dodecylstannyl]sulfanylacetic acid Chemical class CCCCCCCCCCCC[Sn](SCC(O)=O)(SCC(O)=O)SCC(O)=O RPPZINJJZONDRV-UHFFFAOYSA-K 0.000 description 2
- CMCOFAYLDYIEBR-UHFFFAOYSA-L 2-[carboxymethylsulfanyl(dioctyl)stannyl]sulfanylacetic acid Chemical class [O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCC[Sn+2]CCCCCCCC CMCOFAYLDYIEBR-UHFFFAOYSA-L 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- TVMDUMQNXXNGMG-UHFFFAOYSA-N dodecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCOC(=O)CS TVMDUMQNXXNGMG-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- IGMYAFRPSRRXNA-UHFFFAOYSA-L 2-[dibutyl(carboxymethylsulfanyl)stannyl]sulfanylacetic acid Chemical class [O-]C(=O)CS.[O-]C(=O)CS.CCCC[Sn+2]CCCC IGMYAFRPSRRXNA-UHFFFAOYSA-L 0.000 description 1
- SPIUEOWNLJQKJK-UHFFFAOYSA-J 2-sulfanylacetate tin(4+) Chemical class [Sn+4].[O-]C(=O)CS.[O-]C(=O)CS.[O-]C(=O)CS.[O-]C(=O)CS SPIUEOWNLJQKJK-UHFFFAOYSA-J 0.000 description 1
- IUNVCWLKOOCPIT-UHFFFAOYSA-N 6-methylheptylsulfanyl 2-hydroxyacetate Chemical compound CC(C)CCCCCSOC(=O)CO IUNVCWLKOOCPIT-UHFFFAOYSA-N 0.000 description 1
- HRDANFPMJJNXTQ-UHFFFAOYSA-L CCCC[Sn+2].CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O Chemical compound CCCC[Sn+2].CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O HRDANFPMJJNXTQ-UHFFFAOYSA-L 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- DFUSECKIHAOCCK-UHFFFAOYSA-N [Sn].OC(=O)CS.OC(=O)CS Chemical compound [Sn].OC(=O)CS.OC(=O)CS DFUSECKIHAOCCK-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AVWIXKISMQYFFD-UHFFFAOYSA-K butyltin(3+) 8-methyl-2-sulfanylnonanoate Chemical compound CCCC[Sn+3].CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O AVWIXKISMQYFFD-UHFFFAOYSA-K 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YDONZZJDQWRUEX-UHFFFAOYSA-N dodecyl(oxo)tin Chemical class CCCCCCCCCCCC[Sn]=O YDONZZJDQWRUEX-UHFFFAOYSA-N 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- WDRMFQRBFDVBPJ-UHFFFAOYSA-N hexadecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CS WDRMFQRBFDVBPJ-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 231100000037 inhalation toxicity test Toxicity 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 229940127554 medical product Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- LXDHBOICPCPCKD-UHFFFAOYSA-N tetradecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCOC(=O)CS LXDHBOICPCPCKD-UHFFFAOYSA-N 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical class OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28419681A | 1981-07-17 | 1981-07-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2509741A1 true FR2509741A1 (fr) | 1983-01-21 |
| FR2509741B1 FR2509741B1 (Direct) | 1985-01-18 |
Family
ID=23089251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8212344A Granted FR2509741A1 (fr) | 1981-07-17 | 1982-07-15 | Melange stabilisant non toxique destine a des polymeres halogenes |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0070497B1 (Direct) |
| JP (1) | JPS5859248A (Direct) |
| BE (1) | BE893860A (Direct) |
| DE (2) | DE3223733A1 (Direct) |
| FR (1) | FR2509741A1 (Direct) |
| GB (1) | GB2102433B (Direct) |
| IT (1) | IT1156101B (Direct) |
| NL (1) | NL8202252A (Direct) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2599373B1 (fr) * | 1986-05-30 | 1989-06-16 | Ciba Geigy Ag | Compositions a base de poly-(chlorure de vinyle) stabilisees par des composes laurylstanniques, application de ces compositions et procede pour stabiliser des matieres a mouler |
| USD1048760S1 (en) * | 2023-02-06 | 2024-10-29 | Katayoon Ardehali | Wall mount adaptor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2109945A5 (Direct) * | 1970-10-02 | 1972-05-26 | Interstab Ltd | |
| GB1510974A (en) * | 1975-05-19 | 1978-05-17 | M & T Chemicals Inc | Stabilized vinyl chloride resins |
| EP0032106A2 (de) * | 1979-12-07 | 1981-07-15 | Ciba-Geigy Ag | Gemische von n-Octylzinn-Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren für halogenhaltige Thermoplaste |
-
1982
- 1982-06-03 NL NL8202252A patent/NL8202252A/nl not_active Application Discontinuation
- 1982-06-25 DE DE19823223733 patent/DE3223733A1/de not_active Withdrawn
- 1982-06-28 IT IT22080/82A patent/IT1156101B/it active
- 1982-07-13 EP EP82106237A patent/EP0070497B1/de not_active Expired
- 1982-07-13 DE DE8282106237T patent/DE3260900D1/de not_active Expired
- 1982-07-14 JP JP57121374A patent/JPS5859248A/ja active Granted
- 1982-07-15 FR FR8212344A patent/FR2509741A1/fr active Granted
- 1982-07-16 BE BE0/208610A patent/BE893860A/fr not_active IP Right Cessation
- 1982-07-16 GB GB08220659A patent/GB2102433B/en not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2109945A5 (Direct) * | 1970-10-02 | 1972-05-26 | Interstab Ltd | |
| GB1510974A (en) * | 1975-05-19 | 1978-05-17 | M & T Chemicals Inc | Stabilized vinyl chloride resins |
| EP0032106A2 (de) * | 1979-12-07 | 1981-07-15 | Ciba-Geigy Ag | Gemische von n-Octylzinn-Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren für halogenhaltige Thermoplaste |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2102433B (en) | 1985-01-30 |
| NL8202252A (nl) | 1983-02-16 |
| BE893860A (fr) | 1983-01-17 |
| IT8222080A0 (it) | 1982-06-28 |
| EP0070497B1 (de) | 1984-10-03 |
| GB2102433A (en) | 1983-02-02 |
| DE3223733A1 (de) | 1983-05-26 |
| DE3260900D1 (en) | 1984-11-08 |
| JPS5859248A (ja) | 1983-04-08 |
| JPH0160178B2 (Direct) | 1989-12-21 |
| IT1156101B (it) | 1987-01-28 |
| EP0070497A1 (de) | 1983-01-26 |
| FR2509741B1 (Direct) | 1985-01-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |