FR2505876A1 - Selective winning of lead from sulphide ores - by leaching with hot aq. hydro:fluorosilicic acid soln. contg. hydrogen peroxide and air so only lead is dissolved - Google Patents
Selective winning of lead from sulphide ores - by leaching with hot aq. hydro:fluorosilicic acid soln. contg. hydrogen peroxide and air so only lead is dissolved Download PDFInfo
- Publication number
- FR2505876A1 FR2505876A1 FR8109440A FR8109440A FR2505876A1 FR 2505876 A1 FR2505876 A1 FR 2505876A1 FR 8109440 A FR8109440 A FR 8109440A FR 8109440 A FR8109440 A FR 8109440A FR 2505876 A1 FR2505876 A1 FR 2505876A1
- Authority
- FR
- France
- Prior art keywords
- lead
- solution
- dissolved
- electrolysis
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 16
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 239000002253 acid Substances 0.000 title claims description 10
- 238000002386 leaching Methods 0.000 title abstract description 3
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 title 1
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 15
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012141 concentrate Substances 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 22
- 238000004090 dissolution Methods 0.000 claims description 11
- 150000004763 sulfides Chemical class 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 6
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 13
- 239000002184 metal Substances 0.000 abstract description 13
- 150000002739 metals Chemical class 0.000 abstract description 9
- 229910003638 H2SiF6 Inorganic materials 0.000 abstract description 3
- 229910052949 galena Inorganic materials 0.000 abstract description 3
- ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000001590 oxidative effect Effects 0.000 description 8
- 229910052981 lead sulfide Inorganic materials 0.000 description 7
- 229940056932 lead sulfide Drugs 0.000 description 7
- 239000002609 medium Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000009854 hydrometallurgy Methods 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NJQIFQZKRYNHTE-UHFFFAOYSA-L [Mn](=O)(=O)(Cl)Cl Chemical compound [Mn](=O)(=O)(Cl)Cl NJQIFQZKRYNHTE-UHFFFAOYSA-L 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B13/00—Obtaining lead
- C22B13/04—Obtaining lead by wet processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/18—Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8109440A FR2505876A1 (en) | 1981-05-12 | 1981-05-12 | Selective winning of lead from sulphide ores - by leaching with hot aq. hydro:fluorosilicic acid soln. contg. hydrogen peroxide and air so only lead is dissolved |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8109440A FR2505876A1 (en) | 1981-05-12 | 1981-05-12 | Selective winning of lead from sulphide ores - by leaching with hot aq. hydro:fluorosilicic acid soln. contg. hydrogen peroxide and air so only lead is dissolved |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2505876A1 true FR2505876A1 (en) | 1982-11-19 |
| FR2505876B1 FR2505876B1 (Direct) | 1983-08-12 |
Family
ID=9258351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8109440A Granted FR2505876A1 (en) | 1981-05-12 | 1981-05-12 | Selective winning of lead from sulphide ores - by leaching with hot aq. hydro:fluorosilicic acid soln. contg. hydrogen peroxide and air so only lead is dissolved |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2505876A1 (Direct) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1984001964A1 (fr) * | 1982-11-18 | 1984-05-24 | Extramet Sa | Procede d'extraction selective du plomb a partir des sulfures de plomb |
| EP0109468A1 (fr) * | 1982-11-18 | 1984-05-30 | Extramet | Procédé d'extraction sélective du plomb à partir des sulfures de plomb |
| WO1987002068A1 (fr) * | 1985-09-27 | 1987-04-09 | Extramet | Procede de separation et de recuperation de metaux dans des melanges de sulfures metalliques tels que les minerais de plomb |
| EP0508960A1 (en) * | 1991-03-13 | 1992-10-14 | M.A. Industries Inc. | A hydrometallurgical method of producing metallic lead from materials containing oxides, particularly from the active material of accumulators |
| US5262020A (en) * | 1991-03-13 | 1993-11-16 | M.A. Industries, Inc. | Hydrometallurgical method of producing metallic lead from materials containing oxides, particularly from the active material of accumulators |
| TR26430A (tr) * | 1992-09-10 | 1995-03-15 | Ma Ind Inc | ÖZELLIKLE AKüMüLATÖRLERIN AKTIF MALZEMELERINDEN OLMAK üZERE OKSIDLERI IHTIVA EDEN MALZEMELERDEN METALIK KURSUN üRETMEK ICIN HIDROMETALLÖRJIK BIR USUL |
-
1981
- 1981-05-12 FR FR8109440A patent/FR2505876A1/fr active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1984001964A1 (fr) * | 1982-11-18 | 1984-05-24 | Extramet Sa | Procede d'extraction selective du plomb a partir des sulfures de plomb |
| EP0109468A1 (fr) * | 1982-11-18 | 1984-05-30 | Extramet | Procédé d'extraction sélective du plomb à partir des sulfures de plomb |
| WO1987002068A1 (fr) * | 1985-09-27 | 1987-04-09 | Extramet | Procede de separation et de recuperation de metaux dans des melanges de sulfures metalliques tels que les minerais de plomb |
| FR2589885A1 (fr) * | 1985-09-27 | 1987-05-15 | Extramet Sarl | Procede de separation et de recuperation de metaux, dans des melanges de sulfures metalliques, tels que des minerais de plomb |
| EP0508960A1 (en) * | 1991-03-13 | 1992-10-14 | M.A. Industries Inc. | A hydrometallurgical method of producing metallic lead from materials containing oxides, particularly from the active material of accumulators |
| US5262020A (en) * | 1991-03-13 | 1993-11-16 | M.A. Industries, Inc. | Hydrometallurgical method of producing metallic lead from materials containing oxides, particularly from the active material of accumulators |
| TR26430A (tr) * | 1992-09-10 | 1995-03-15 | Ma Ind Inc | ÖZELLIKLE AKüMüLATÖRLERIN AKTIF MALZEMELERINDEN OLMAK üZERE OKSIDLERI IHTIVA EDEN MALZEMELERDEN METALIK KURSUN üRETMEK ICIN HIDROMETALLÖRJIK BIR USUL |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2505876B1 (Direct) | 1983-08-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ER | Errata listed in the french official journal (bopi) |
Free format text: 46/82 |
|
| TP | Transmission of property | ||
| ST | Notification of lapse |