FR2498215A1 - Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre - Google Patents
Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre Download PDFInfo
- Publication number
- FR2498215A1 FR2498215A1 FR8101183A FR8101183A FR2498215A1 FR 2498215 A1 FR2498215 A1 FR 2498215A1 FR 8101183 A FR8101183 A FR 8101183A FR 8101183 A FR8101183 A FR 8101183A FR 2498215 A1 FR2498215 A1 FR 2498215A1
- Authority
- FR
- France
- Prior art keywords
- dyes
- resin
- thermosetting
- cathionic
- epichlorohydrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003647 oxidation Effects 0.000 title claims abstract description 17
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 17
- 239000000988 sulfur dye Substances 0.000 title claims description 7
- 239000000835 fiber Substances 0.000 title claims description 6
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000013011 aqueous formulation Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000007800 oxidant agent Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 14
- 239000000975 dye Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 229920001187 thermosetting polymer Polymers 0.000 claims description 11
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000004043 dyeing Methods 0.000 claims description 7
- 229920000768 polyamine Polymers 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001281 polyalkylene Polymers 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- -1 alkali metal bromates Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000005956 quaternization reaction Methods 0.000 claims 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical compound [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 abstract description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004153 Potassium bromate Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229940094037 potassium bromate Drugs 0.000 description 3
- 235000019396 potassium bromate Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 101100407060 Caenorhabditis elegans par-6 gene Proteins 0.000 description 1
- 206010012289 Dementia Diseases 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical class OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/222—Oxidising agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8101183A FR2498215A1 (fr) | 1981-01-19 | 1981-01-19 | Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre |
| US06/425,075 US4456453A (en) | 1981-01-19 | 1982-01-15 | Method of oxidizing and simultaneously fixing sulfur dyestuffs on cellulosic fibers |
| DE19823231607 DE3231607A1 (de) | 1981-01-19 | 1982-01-15 | Verfahren zur gleichzeitigen oxidation und fixierung von auf cellulosefasern mit schwefelfarbstoffen erzeugten faerbungen |
| PCT/FR1982/000009 WO1982002565A1 (fr) | 1981-01-19 | 1982-01-15 | Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre |
| JP57500369A JPS57502174A (enExample) | 1981-01-19 | 1982-01-15 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8101183A FR2498215A1 (fr) | 1981-01-19 | 1981-01-19 | Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2498215A1 true FR2498215A1 (fr) | 1982-07-23 |
| FR2498215B1 FR2498215B1 (enExample) | 1983-04-22 |
Family
ID=9254413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8101183A Granted FR2498215A1 (fr) | 1981-01-19 | 1981-01-19 | Procede d'oxydation et de fixation simultanees des teintures realisees sur fibres cellulosiques avec des colorants au soufre |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4456453A (enExample) |
| JP (1) | JPS57502174A (enExample) |
| FR (1) | FR2498215A1 (enExample) |
| WO (1) | WO1982002565A1 (enExample) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2270366A1 (enExample) * | 1974-05-10 | 1975-12-05 | Olin Corp | |
| DE2702710A1 (de) * | 1976-03-24 | 1977-09-29 | Sandoz Ag | Faerbeverfahren |
| JPS5367575A (en) * | 1976-08-23 | 1978-06-16 | Bicosa Recherches | Steppup transformer and electronic ignition lighter using same |
| DE2703699A1 (de) * | 1977-01-29 | 1978-08-03 | Cassella Farbwerke Mainkur Ag | Verfahren zum faerben und bedrucken cellulosehaltiger textilmaterialien mit wasserloeslichen thioschwefelsaeurederivaten von schwefelfarbstoffen ohne zusatz von reduktionsmitteln |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3334138A (en) * | 1963-08-02 | 1967-08-01 | Crompton & Knowles Corp | Polymeric quaternary ammonium compound |
| US3702351A (en) * | 1970-06-09 | 1972-11-07 | Protex Manuf Prod Chimiq | Cationic thermosetting resins containing the reaction product of a carboxyl terminated polyester with an epoxy amine adduct treated with epichlorohydrin |
| JPS5344589B2 (enExample) * | 1973-09-18 | 1978-11-30 | ||
| US4042319A (en) * | 1976-10-12 | 1977-08-16 | Kewanee Industries | Dye-bath oxidants |
-
1981
- 1981-01-19 FR FR8101183A patent/FR2498215A1/fr active Granted
-
1982
- 1982-01-15 US US06/425,075 patent/US4456453A/en not_active Expired - Fee Related
- 1982-01-15 JP JP57500369A patent/JPS57502174A/ja active Pending
- 1982-01-15 WO PCT/FR1982/000009 patent/WO1982002565A1/fr not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2270366A1 (enExample) * | 1974-05-10 | 1975-12-05 | Olin Corp | |
| DE2702710A1 (de) * | 1976-03-24 | 1977-09-29 | Sandoz Ag | Faerbeverfahren |
| JPS5367575A (en) * | 1976-08-23 | 1978-06-16 | Bicosa Recherches | Steppup transformer and electronic ignition lighter using same |
| DE2703699A1 (de) * | 1977-01-29 | 1978-08-03 | Cassella Farbwerke Mainkur Ag | Verfahren zum faerben und bedrucken cellulosehaltiger textilmaterialien mit wasserloeslichen thioschwefelsaeurederivaten von schwefelfarbstoffen ohne zusatz von reduktionsmitteln |
Non-Patent Citations (3)
| Title |
|---|
| CA1975 * |
| EXBK/73 * |
| EXBK/78 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1982002565A1 (fr) | 1982-08-05 |
| US4456453A (en) | 1984-06-26 |
| JPS57502174A (enExample) | 1982-12-09 |
| FR2498215B1 (enExample) | 1983-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |