FR2493308A1 - Installation integree pour la synthese du methanol a partir de la houille gazeifiee - Google Patents
Installation integree pour la synthese du methanol a partir de la houille gazeifiee Download PDFInfo
- Publication number
- FR2493308A1 FR2493308A1 FR8120265A FR8120265A FR2493308A1 FR 2493308 A1 FR2493308 A1 FR 2493308A1 FR 8120265 A FR8120265 A FR 8120265A FR 8120265 A FR8120265 A FR 8120265A FR 2493308 A1 FR2493308 A1 FR 2493308A1
- Authority
- FR
- France
- Prior art keywords
- methanol
- coal
- methane
- synthesis
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title abstract description 96
- 230000015572 biosynthetic process Effects 0.000 title abstract description 28
- 238000003786 synthesis reaction Methods 0.000 title abstract description 28
- 238000009434 installation Methods 0.000 title abstract description 14
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 32
- 239000003245 coal Substances 0.000 abstract description 23
- 238000010494 dissociation reaction Methods 0.000 abstract description 17
- 230000005593 dissociations Effects 0.000 abstract description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 15
- 238000002309 gasification Methods 0.000 abstract description 15
- 239000001257 hydrogen Substances 0.000 abstract description 14
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000000926 separation method Methods 0.000 abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 230000010354 integration Effects 0.000 abstract description 3
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 3
- 229910002090 carbon oxide Inorganic materials 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 28
- 238000005984 hydrogenation reaction Methods 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000571 coke Substances 0.000 description 5
- 239000001307 helium Substances 0.000 description 5
- 229910052734 helium Inorganic materials 0.000 description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
- 238000004064 recycling Methods 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- -1 oxy- Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0966—Hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3041054A DE3041054C2 (de) | 1980-10-31 | 1980-10-31 | Verfahren zur Herstellung von Methanol aus vergaster Kohle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2493308A1 true FR2493308A1 (fr) | 1982-05-07 |
| FR2493308B1 FR2493308B1 (enrdf_load_stackoverflow) | 1985-01-11 |
Family
ID=6115650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8120265A Granted FR2493308A1 (fr) | 1980-10-31 | 1981-10-28 | Installation integree pour la synthese du methanol a partir de la houille gazeifiee |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS57106629A (enrdf_load_stackoverflow) |
| AU (1) | AU541196B2 (enrdf_load_stackoverflow) |
| DE (1) | DE3041054C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2493308A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2086389B (enrdf_load_stackoverflow) |
| ZA (1) | ZA817535B (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3415224A1 (de) * | 1984-04-21 | 1985-10-24 | Kraftwerk Union AG, 4330 Mülheim | Gasturbinen- und dampfkraftwerk mit einer integrierten kohlevergasungsanlage |
| US4618732A (en) * | 1985-05-20 | 1986-10-21 | Gesser Hyman D | Direct conversion of natural gas to methanol by controlled oxidation |
| US5427762A (en) * | 1987-05-27 | 1995-06-27 | Hydrocarb Corporation | Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol |
| ZA908290B (en) * | 1989-10-20 | 1991-09-25 | Hydrocarb Corp | Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol |
| DE69229839T2 (de) * | 1991-01-29 | 2000-02-10 | Mitsubishi Heavy Ind Ltd | Methode zur Herstellung von Methanol unter Verwendung der Wärme eines Kernkraftwerkes |
| JP2007254306A (ja) * | 2006-03-20 | 2007-10-04 | Mitsubishi Heavy Ind Ltd | メタノール合成装置及び方法 |
| CN101191084B (zh) * | 2007-11-16 | 2010-12-08 | 清华大学 | 以甲烷重整方式利用煤气化显热的多联产能源方法及系统 |
| EP2641889B1 (en) * | 2010-11-19 | 2017-12-20 | Mitsui Chemicals, Inc. | Methanol production process |
| JP2012201610A (ja) * | 2011-03-24 | 2012-10-22 | Hiroshima Univ | アルコール製造方法及びその装置 |
| CN103524299B (zh) * | 2012-07-06 | 2017-08-25 | 杭州林达化工技术工程有限公司 | 一种合成甲醇和合成甲烷联产设备 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE964234C (de) * | 1951-10-12 | 1957-05-23 | Metallgesellschaft Ag | Verfahren zur Erhoehung der Ausbeute von Kohlenwasserstoffen oder sauerstoffhaltigenKohlenwasserstoffen bei der Kohlenoxydhydrierung |
| FR1203696A (fr) * | 1957-03-27 | 1960-01-20 | Ici Ltd | Perfectionnements à la fabrication d'hydrocarbures non saturés et de méthanol |
| FR2207392A1 (enrdf_load_stackoverflow) * | 1972-11-17 | 1974-06-14 | Blaupunkt Werke Gmbh | |
| FR2339586A1 (fr) * | 1976-01-29 | 1977-08-26 | Metallgesellschaft Ag | Procede pour la preparation du methanol |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2837988A1 (de) * | 1978-08-31 | 1980-03-13 | Ght Hochtemperaturreak Tech | Kohlevergasung |
-
1980
- 1980-10-31 DE DE3041054A patent/DE3041054C2/de not_active Expired
-
1981
- 1981-10-26 GB GB8132172A patent/GB2086389B/en not_active Expired
- 1981-10-28 FR FR8120265A patent/FR2493308A1/fr active Granted
- 1981-10-30 JP JP56174392A patent/JPS57106629A/ja active Granted
- 1981-10-30 ZA ZA817535A patent/ZA817535B/xx unknown
- 1981-10-30 AU AU77000/81A patent/AU541196B2/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE964234C (de) * | 1951-10-12 | 1957-05-23 | Metallgesellschaft Ag | Verfahren zur Erhoehung der Ausbeute von Kohlenwasserstoffen oder sauerstoffhaltigenKohlenwasserstoffen bei der Kohlenoxydhydrierung |
| FR1203696A (fr) * | 1957-03-27 | 1960-01-20 | Ici Ltd | Perfectionnements à la fabrication d'hydrocarbures non saturés et de méthanol |
| FR2207392A1 (enrdf_load_stackoverflow) * | 1972-11-17 | 1974-06-14 | Blaupunkt Werke Gmbh | |
| FR2339586A1 (fr) * | 1976-01-29 | 1977-08-26 | Metallgesellschaft Ag | Procede pour la preparation du methanol |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2086389B (en) | 1984-06-13 |
| DE3041054A1 (de) | 1982-06-09 |
| JPH0250888B2 (enrdf_load_stackoverflow) | 1990-11-05 |
| AU541196B2 (en) | 1984-12-20 |
| JPS57106629A (en) | 1982-07-02 |
| FR2493308B1 (enrdf_load_stackoverflow) | 1985-01-11 |
| ZA817535B (en) | 1982-10-27 |
| AU7700081A (en) | 1982-05-06 |
| GB2086389A (en) | 1982-05-12 |
| DE3041054C2 (de) | 1987-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |