FR2447915A1 - Pyrimidin-4-yl-phosphorothionates, leur preparation et leur utilisation comme insecticides, acaricides et/ou nematocides - Google Patents
Pyrimidin-4-yl-phosphorothionates, leur preparation et leur utilisation comme insecticides, acaricides et/ou nematocidesInfo
- Publication number
- FR2447915A1 FR2447915A1 FR8002389A FR8002389A FR2447915A1 FR 2447915 A1 FR2447915 A1 FR 2447915A1 FR 8002389 A FR8002389 A FR 8002389A FR 8002389 A FR8002389 A FR 8002389A FR 2447915 A1 FR2447915 A1 FR 2447915A1
- Authority
- FR
- France
- Prior art keywords
- formula
- compounds
- phosphorothionates
- pyrimidin
- bopi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000642 acaricide Substances 0.000 title abstract 2
- 239000002917 insecticide Substances 0.000 title abstract 2
- 239000005645 nematicide Substances 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- 150000002367 halogens Chemical group 0.000 abstract 2
- 150000008081 1H-pyrimidin-4-ones Chemical class 0.000 abstract 1
- DNCYBUMDUBHIJZ-UHFFFAOYSA-N 1h-pyrimidin-6-one Chemical compound O=C1C=CN=CN1 DNCYBUMDUBHIJZ-UHFFFAOYSA-N 0.000 abstract 1
- -1 METHYLMERCAPTO Chemical class 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/34—One oxygen atom
- C07D239/36—One oxygen atom as doubly bound oxygen atom or as unsubstituted hydroxy radical
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/6512—Six-membered rings having the nitrogen atoms in positions 1 and 3
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
L'INVENTION CONCERNE DES PYRIMIDIN-4-YL-PHOSPHOROTHIONATES DE FORMULE:II : (CF DESSIN DANS BOPI) DANS LAQUELLE R EST UN GROUPEMENT ALKYLE EN C-C, R EST UN GROUPEMENT ALCOXY EN C-C OU ALKYLAMINO EN C-C, R ET R SONT INDEPENDAMMENT UN ATOME D'HALOGENE OU UN GROUPEMENT ALCOXY EN C-C OU METHYLMERCAPTO, ET X EST L'OXYGENE OU LE SOUFRE. CES COMPOSES SONT OBTENUS PAR CONDENSATION DE 4-HYDROXYPYRIMIDINE DE FORMULE II: (CF DESSIN DANS BOPI) ET DE COMPOSES DE FORMULE III: (CF DESSIN DANS BOPI) (Y DESIGNANT UN ATOME D'HALOGENE). LES 4-HYDROXYPYRIMIDINES DE FORMULE II SONT DES COMPOSES NOUVEAUX ET LEUR PROCEDE DE PREPARATION EST EGALEMENT DECRIT. LES COMPOSES DE FORMULE I SONT UTILISABLES COMME INGREDIENTS ACTIFS DANS DES COMPOSITIONS INSECTICIDES, ACARICIDES ETOU NEMATOCIDES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1249779A JPS55104295A (en) | 1979-02-05 | 1979-02-05 | Pyrimidin-4-yl(thio)phosphoric acid ester, its preparation, and insecticide, miticide, and nematocide containing the compound as effective component |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2447915A1 true FR2447915A1 (fr) | 1980-08-29 |
FR2447915B1 FR2447915B1 (fr) | 1984-01-27 |
Family
ID=11807001
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8002389A Granted FR2447915A1 (fr) | 1979-02-05 | 1980-02-04 | Pyrimidin-4-yl-phosphorothionates, leur preparation et leur utilisation comme insecticides, acaricides et/ou nematocides |
Country Status (9)
Country | Link |
---|---|
US (1) | US4308258A (fr) |
JP (1) | JPS55104295A (fr) |
CH (1) | CH644385A5 (fr) |
DE (1) | DE3003337A1 (fr) |
FR (1) | FR2447915A1 (fr) |
GB (1) | GB2043643B (fr) |
IT (1) | IT1143914B (fr) |
NL (1) | NL8000688A (fr) |
PH (1) | PH17500A (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382087A (en) * | 1981-05-04 | 1983-05-03 | Olin Corporation | Selected O-(2-trichloromethyl-4-pyrimidinyl)-O,O-dialkyl phosphorothionates and O-(2-trichloromethyl-4-pyrimidinyl)-O,O-dialkyl phosphoronates and their use as insecticides |
US4634690A (en) * | 1981-12-10 | 1987-01-06 | Uniroyal Chemical Company, Inc. | Substituted pyrimidinyl organophosphorus insecticides |
US4472389A (en) * | 1981-12-10 | 1984-09-18 | Uniroyal, Inc. | Substituted pyrimidinyl organophosphorus insecticides |
US4395551A (en) * | 1981-12-10 | 1983-07-26 | Uniroyal, Inc. | Pyridopyrimidinone compounds |
US4496728A (en) * | 1982-09-20 | 1985-01-29 | Ciba-Geigy Corporation | Method for the production of 2-isopropyl-4-methyl-6-hydroxypyrimidine |
US4489068A (en) * | 1983-04-28 | 1984-12-18 | The Dow Chemical Company | Method and composition for enhancing the insecticidal activity of certain organophosphorus compounds |
DE3420166A1 (de) * | 1984-05-30 | 1985-12-05 | Basf Ag, 6700 Ludwigshafen | Pyrimidylphosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen |
US5034529A (en) * | 1988-04-28 | 1991-07-23 | Ciba-Geigy Corporation | Process for the production of thiophosphoric acid esters of hydroxypyrimidines |
US5466458A (en) * | 1992-03-09 | 1995-11-14 | Roussel Uclaf | Emulsified spray formulations |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1369062A (fr) * | 1962-08-24 | 1964-08-07 | Bayer Ag | Nouvelles compositions insecticides et acaricides et leur procédé de fabrication |
FR2378791A1 (fr) * | 1977-01-27 | 1978-08-25 | Bayer Ag | Nouveaux esters ou amides d'esters de pyrimidinyle substitues d'acide (thio) phosphorique (phosphonique), leur procede de preparation et leur application comme insecticides, acaricides et nematicides |
DE2804889A1 (de) * | 1978-02-04 | 1979-08-16 | Hoechst Ag | (thio)phosphor- und -phosphonsaeureester von substituierten pyrimidinen, ihre herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE641253A (fr) * | ||||
NL86689C (fr) * | 1951-04-20 | 1900-01-01 | ||
US3159630A (en) * | 1961-06-14 | 1964-12-01 | Dow Chemical Co | Pyrimidinyl omicron-alkyl phosphoramidates and phosphoramidothioates |
NL296930A (fr) * | 1962-08-24 | 1900-01-01 | ||
GB1436754A (en) | 1973-05-16 | 1976-05-26 | Sandoz Ltd | Phosphoric and thionophosphoric acid esters and esteramides |
JPS547109B2 (fr) * | 1973-06-25 | 1979-04-04 | ||
DE2747357A1 (de) | 1977-10-21 | 1979-04-26 | Bayer Ag | Substituierte pyrimidinyl(thiono) (thiol)phosphor (phosphon)-saeureester bzw. -esteramide, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide |
-
1979
- 1979-02-05 JP JP1249779A patent/JPS55104295A/ja active Pending
-
1980
- 1980-01-24 US US06/114,737 patent/US4308258A/en not_active Expired - Lifetime
- 1980-01-30 GB GB8003113A patent/GB2043643B/en not_active Expired
- 1980-01-30 DE DE19803003337 patent/DE3003337A1/de not_active Withdrawn
- 1980-02-01 IT IT8047779A patent/IT1143914B/it active
- 1980-02-04 PH PH23585A patent/PH17500A/en unknown
- 1980-02-04 NL NL8000688A patent/NL8000688A/nl not_active Application Discontinuation
- 1980-02-04 FR FR8002389A patent/FR2447915A1/fr active Granted
- 1980-02-04 CH CH87880A patent/CH644385A5/de not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1369062A (fr) * | 1962-08-24 | 1964-08-07 | Bayer Ag | Nouvelles compositions insecticides et acaricides et leur procédé de fabrication |
FR2378791A1 (fr) * | 1977-01-27 | 1978-08-25 | Bayer Ag | Nouveaux esters ou amides d'esters de pyrimidinyle substitues d'acide (thio) phosphorique (phosphonique), leur procede de preparation et leur application comme insecticides, acaricides et nematicides |
DE2804889A1 (de) * | 1978-02-04 | 1979-08-16 | Hoechst Ag | (thio)phosphor- und -phosphonsaeureester von substituierten pyrimidinen, ihre herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
Also Published As
Publication number | Publication date |
---|---|
GB2043643A (en) | 1980-10-08 |
PH17500A (en) | 1984-09-07 |
US4308258A (en) | 1981-12-29 |
GB2043643B (en) | 1983-05-11 |
JPS55104295A (en) | 1980-08-09 |
DE3003337A1 (de) | 1980-08-14 |
NL8000688A (nl) | 1980-08-07 |
FR2447915B1 (fr) | 1984-01-27 |
IT1143914B (it) | 1986-10-29 |
CH644385A5 (de) | 1984-07-31 |
IT8047779A0 (it) | 1980-02-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |