FR2445842A1 - Procede d'obtention de polyisoprene-1,4 cis - Google Patents
Procede d'obtention de polyisoprene-1,4 cisInfo
- Publication number
- FR2445842A1 FR2445842A1 FR7900332A FR7900332A FR2445842A1 FR 2445842 A1 FR2445842 A1 FR 2445842A1 FR 7900332 A FR7900332 A FR 7900332A FR 7900332 A FR7900332 A FR 7900332A FR 2445842 A1 FR2445842 A1 FR 2445842A1
- Authority
- FR
- France
- Prior art keywords
- cpd
- prodn
- organo
- cis
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 title 1
- 229920001971 elastomer Polymers 0.000 title 1
- 125000002370 organoaluminium group Chemical group 0.000 title 1
- 229920001195 polyisoprene Polymers 0.000 title 1
- 239000010936 titanium Substances 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 title 1
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229920003211 cis-1,4-polyisoprene Polymers 0.000 abstract 1
- 238000004880 explosion Methods 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229920003049 isoprene rubber Polymers 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
L'invention concerne la production des caoutchoucs synthétiques. Le procédé faisant l'objet de l'invention, du type dans lequel on procède à une polymérisation de l'isoprène au sein d'un solvant organique inerte à une température de -10 à + 100 degrés C en présence d'un système catalytique contenant un constituant A tel que le tétrachlorure de titane, un constituant B tel qu'un composé organoaluminique, un constituant C tel que des éthers répondant à la formule ROR', où R et R' sont des alcoyles, des cycloalcoyles et des alcényles ou des amines identiques ou différents, est caractérisé en ce que le système catalytique contient, à titre de constituant B, un composé organoaluminique ayant un motif élémentaire répondant à la formule générale :
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7900332A FR2445842A1 (fr) | 1979-01-08 | 1979-01-08 | Procede d'obtention de polyisoprene-1,4 cis |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7900332A FR2445842A1 (fr) | 1979-01-08 | 1979-01-08 | Procede d'obtention de polyisoprene-1,4 cis |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2445842A1 true FR2445842A1 (fr) | 1980-08-01 |
FR2445842B1 FR2445842B1 (fr) | 1982-06-18 |
Family
ID=9220529
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7900332A Granted FR2445842A1 (fr) | 1979-01-08 | 1979-01-08 | Procede d'obtention de polyisoprene-1,4 cis |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2445842A1 (fr) |
-
1979
- 1979-01-08 FR FR7900332A patent/FR2445842A1/fr active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2445842B1 (fr) | 1982-06-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |