FR2433545A1 - Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees - Google Patents
Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement amelioreesInfo
- Publication number
- FR2433545A1 FR2433545A1 FR7920495A FR7920495A FR2433545A1 FR 2433545 A1 FR2433545 A1 FR 2433545A1 FR 7920495 A FR7920495 A FR 7920495A FR 7920495 A FR7920495 A FR 7920495A FR 2433545 A1 FR2433545 A1 FR 2433545A1
- Authority
- FR
- France
- Prior art keywords
- isoprene
- butadiene
- copolymer rubber
- improved treatment
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Abstract
L'invention concerne un nouveau caoutchouc copolymère d'isoprène-butadiène. Ce caoutchouc copolymère comprend une microstructure de la partie butadiène ayant de 70 à 90 % de liaison trans-1,4 et de 2 à 8 % de liaison vinyle, une teneur en isoprène comprise entre 3 et 25 % en poids et une teneur en styrène comprise entre 0 et 30 % en poids, ledit caoutchouc copolymère ayant une viscosité Mooney comprise entre 30 et 150, une distribution de poids moléculaire Mw/Mn comprise entre 1,2 et 3,5, ledit caoutchouc, à l'état non allongé, ne présentant pas de point de fusion mesuré par la méthode d'analyse calorimétrique différentielle par balayage. Ce caoutchouc copolymère présente des meilleures propriétés de traitement que les produits correspondants antérieurs.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10000678A JPS5527337A (en) | 1978-08-18 | 1978-08-18 | Isoprene-butadiene copolymer rubber having improved processability |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2433545A1 true FR2433545A1 (fr) | 1980-03-14 |
FR2433545B1 FR2433545B1 (fr) | 1982-09-17 |
Family
ID=14262473
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7920495A Granted FR2433545A1 (fr) | 1978-08-18 | 1979-08-10 | Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees |
FR8113905A Granted FR2483428A1 (fr) | 1978-08-18 | 1981-07-16 | Nouvel initiateur complexe formant catalyseur pour la preparation de polymeres ou de copolymeres notamment de butadiene |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR8113905A Granted FR2483428A1 (fr) | 1978-08-18 | 1981-07-16 | Nouvel initiateur complexe formant catalyseur pour la preparation de polymeres ou de copolymeres notamment de butadiene |
Country Status (6)
Country | Link |
---|---|
US (1) | US4413098A (fr) |
JP (1) | JPS5527337A (fr) |
DE (1) | DE2932871C2 (fr) |
FR (2) | FR2433545A1 (fr) |
GB (1) | GB2029426B (fr) |
IT (1) | IT1123533B (fr) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4355156A (en) | 1980-02-25 | 1982-10-19 | The General Tire & Rubber Company | Solution polymerization |
US4302568A (en) | 1980-02-25 | 1981-11-24 | The General Tire & Rubber Co. | Solution polymerization |
US4297240A (en) | 1980-02-25 | 1981-10-27 | The General Tire & Rubber Company | Solution polymerization |
US4307218A (en) | 1980-02-25 | 1981-12-22 | The General Tire & Rubber Company | Solution polymerization |
JPS57123237A (en) * | 1981-01-26 | 1982-07-31 | Sumitomo Rubber Ind Ltd | Butadiene-isoprene copolymer composition |
JPS57100146A (en) * | 1980-12-16 | 1982-06-22 | Asahi Chem Ind Co Ltd | Novel rubber composition |
JPS57145134A (en) * | 1981-03-04 | 1982-09-08 | Nippon Zeon Co Ltd | Rubber composition |
FR2567135B1 (fr) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | Polymere ou copolymere de butadiene et procede de preparation |
JPH0662727B2 (ja) * | 1984-08-27 | 1994-08-17 | 日本合成ゴム株式会社 | ゴム組成物 |
US4616065A (en) * | 1985-04-15 | 1986-10-07 | Gencorp Inc. | High trans butadiene based elastomeric block copolymers and blends |
DE3710002A1 (de) * | 1986-08-14 | 1988-02-18 | Huels Chemische Werke Ag | Abc-blockcopolymerisate auf basis von butadien und isopren, verfahren zu ihrer herstellung und ihre verwendung |
DE3724871A1 (de) * | 1987-07-28 | 1989-02-09 | Huels Chemische Werke Ag | Ab-blockcopolymerisate auf basis von butadien, isopren und styrol, verfahren zu ihrer herstellung und ihre verwendung |
KR910008275B1 (ko) * | 1987-08-19 | 1991-10-12 | 아사히가세이고오교 가부시끼가이샤 | 공역 디엔 화화물 예비중합체 용액 제조를 위한 예비중합방법 |
US5191021A (en) * | 1988-06-29 | 1993-03-02 | The Goodyear Tire & Rubber Company | Tire with tread containing styrene, isoprene, butadiene terpolymer rubber |
US5047483A (en) * | 1988-06-29 | 1991-09-10 | The Goodyear Tire & Rubber Company | Pneumatic tire with tread of styrene, isoprene, butadiene rubber |
US5254653A (en) * | 1989-12-28 | 1993-10-19 | The Goodyear Tire & Rubber Company | Terpolymer rubber of styrene, isoprene and butadiene |
US5159020A (en) * | 1989-12-28 | 1992-10-27 | The Goodyear Tire & Rubber Company | Tire with tread comprising styrene, isoprene, butadiene terpolymer rubber |
US5210359A (en) * | 1990-01-16 | 1993-05-11 | Mobil Oil Corporation | Vulcanizable liquid compositions |
US5187236A (en) * | 1990-01-16 | 1993-02-16 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
US5268427A (en) * | 1990-01-16 | 1993-12-07 | Mobil Oil Corporation | Solid block and random elastomeric copolymers |
US5663239A (en) * | 1990-01-16 | 1997-09-02 | Mobil Oil Corporation | Star-branched block elastomeric copolymers |
US5149895A (en) * | 1990-01-16 | 1992-09-22 | Mobil Oil Corporation | Vulcanizable liquid compositions |
US5147951A (en) * | 1990-09-21 | 1992-09-15 | Bridgestone/Firestone, Inc. | Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds |
US5272203A (en) * | 1990-09-21 | 1993-12-21 | Bridgestone/Firestone, Inc. | High performance tire treads and tires |
US5260370A (en) * | 1990-09-21 | 1993-11-09 | Bridgestone Corporation | Oil extended ultra high molecular weight elastomers |
US5231152A (en) * | 1990-12-18 | 1993-07-27 | Bridgestone Corporation | Continuous process for preparing copolymers of conjugated dienes and aromatic vinyl compounds |
US5510548A (en) * | 1995-02-03 | 1996-04-23 | Mobil Oil Corporation | Vulcanizable liquid compositions |
EP0818478B1 (fr) * | 1995-03-30 | 2004-08-11 | Zeon Corporation | Caoutchouc au copolymere styrene-isoprene-butadiene et son procede de production |
US5844044A (en) * | 1997-07-18 | 1998-12-01 | The Goodyear Tire & Rubber Company | Trans 1,4-butadiene/isoprene copolymers and tire with tread thereof |
US6018007A (en) * | 1997-09-22 | 2000-01-25 | Bridgestone Corporation | Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst |
US6204320B1 (en) * | 1999-02-12 | 2001-03-20 | The Goodyear Tire & Rubber Company | Liquid isoprene-butadiene rubber |
US20050061418A1 (en) * | 2003-08-25 | 2005-03-24 | Bates Kenneth Allen | Pneumatic tire having a component containing high trans isoprene-butadiene rubber |
JP5331756B2 (ja) * | 2010-06-29 | 2013-10-30 | ダンロップスポーツ株式会社 | ゴルフボール |
CA2826711C (fr) | 2011-02-14 | 2020-07-14 | Kuraray America Inc. | Formulations elastomeres utiles dans des films et des feuilles |
CN105601814B (zh) | 2016-03-24 | 2020-11-27 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
CN110139882A (zh) | 2016-11-09 | 2019-08-16 | 株式会社普利司通 | 聚丁二烯和聚异戊二烯的高顺式-1,4嵌段共聚物 |
CN112210127B (zh) * | 2019-07-09 | 2023-08-01 | 中国石油化工股份有限公司 | 一种高性能子午线轮胎胎面基部用胶及其制备方法 |
CN112210128B (zh) * | 2019-07-09 | 2023-09-01 | 中国石油化工股份有限公司 | 一种基于梯度嵌段锂系bir的轮胎胎侧胶料及制备方法 |
CN112210040B (zh) * | 2019-07-09 | 2024-01-30 | 中国石油化工股份有限公司 | 一种宽分布聚丁二烯-异戊二烯橡胶及其制备方法 |
CN113563685B (zh) * | 2020-04-29 | 2023-10-13 | 中国石油化工股份有限公司 | 一种全钢载重子午线轮胎配方胶料及其制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1271265A (en) * | 1968-06-08 | 1972-04-19 | Bridgestone Tire Co Ltd | Method of preparing conjugated diene polymers using catalysts based on organolithium compounds |
US3846385A (en) * | 1973-07-16 | 1974-11-05 | Gen Tire & Rubber Co | Preparation of solution polymers using a barium di-tert alkoxide and a di-butyl magnesium catalyst complex |
US4092268A (en) * | 1974-06-05 | 1978-05-30 | Compagnie Generale Des Etablissements Michelin, Raison Sociale Michelin & Cie | Catalytic composition |
FR2340958A2 (fr) | 1974-06-05 | 1977-09-09 | Michelin & Cie | Procede de polymerisation ou de copolymerisation de dienes conjugues et polymeres ainsi obtenus |
US4048427A (en) * | 1975-07-07 | 1977-09-13 | The General Tire & Rubber Company | Preparation of solution polymers |
US3992561A (en) * | 1975-07-07 | 1976-11-16 | The General Tire & Rubber Company | Preparation of solution polymers |
-
1978
- 1978-08-18 JP JP10000678A patent/JPS5527337A/ja active Granted
-
1979
- 1979-07-31 GB GB7926623A patent/GB2029426B/en not_active Expired
- 1979-08-10 FR FR7920495A patent/FR2433545A1/fr active Granted
- 1979-08-14 DE DE2932871A patent/DE2932871C2/de not_active Expired
- 1979-08-20 IT IT25174/79A patent/IT1123533B/it active
-
1981
- 1981-07-16 FR FR8113905A patent/FR2483428A1/fr active Granted
- 1981-09-16 US US06/302,787 patent/US4413098A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
FR2483428A1 (fr) | 1981-12-04 |
DE2932871C2 (de) | 1986-11-20 |
DE2932871A1 (de) | 1980-02-21 |
FR2483428B1 (fr) | 1984-04-27 |
FR2433545B1 (fr) | 1982-09-17 |
IT1123533B (it) | 1986-04-30 |
GB2029426B (en) | 1982-12-22 |
JPH0231084B2 (fr) | 1990-07-11 |
US4413098A (en) | 1983-11-01 |
IT7925174A0 (it) | 1979-08-20 |
GB2029426A (en) | 1980-03-19 |
JPS5527337A (en) | 1980-02-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |