FR2433545A1 - Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees - Google Patents

Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees

Info

Publication number
FR2433545A1
FR2433545A1 FR7920495A FR7920495A FR2433545A1 FR 2433545 A1 FR2433545 A1 FR 2433545A1 FR 7920495 A FR7920495 A FR 7920495A FR 7920495 A FR7920495 A FR 7920495A FR 2433545 A1 FR2433545 A1 FR 2433545A1
Authority
FR
France
Prior art keywords
isoprene
butadiene
copolymer rubber
improved treatment
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7920495A
Other languages
English (en)
Other versions
FR2433545B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Publication of FR2433545A1 publication Critical patent/FR2433545A1/fr
Application granted granted Critical
Publication of FR2433545B1 publication Critical patent/FR2433545B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention concerne un nouveau caoutchouc copolymère d'isoprène-butadiène. Ce caoutchouc copolymère comprend une microstructure de la partie butadiène ayant de 70 à 90 % de liaison trans-1,4 et de 2 à 8 % de liaison vinyle, une teneur en isoprène comprise entre 3 et 25 % en poids et une teneur en styrène comprise entre 0 et 30 % en poids, ledit caoutchouc copolymère ayant une viscosité Mooney comprise entre 30 et 150, une distribution de poids moléculaire Mw/Mn comprise entre 1,2 et 3,5, ledit caoutchouc, à l'état non allongé, ne présentant pas de point de fusion mesuré par la méthode d'analyse calorimétrique différentielle par balayage. Ce caoutchouc copolymère présente des meilleures propriétés de traitement que les produits correspondants antérieurs.
FR7920495A 1978-08-18 1979-08-10 Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees Granted FR2433545A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10000678A JPS5527337A (en) 1978-08-18 1978-08-18 Isoprene-butadiene copolymer rubber having improved processability

Publications (2)

Publication Number Publication Date
FR2433545A1 true FR2433545A1 (fr) 1980-03-14
FR2433545B1 FR2433545B1 (fr) 1982-09-17

Family

ID=14262473

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7920495A Granted FR2433545A1 (fr) 1978-08-18 1979-08-10 Caoutchouc copolymere d'isoprene-butadiene ayant des proprietes de traitement ameliorees
FR8113905A Granted FR2483428A1 (fr) 1978-08-18 1981-07-16 Nouvel initiateur complexe formant catalyseur pour la preparation de polymeres ou de copolymeres notamment de butadiene

Family Applications After (1)

Application Number Title Priority Date Filing Date
FR8113905A Granted FR2483428A1 (fr) 1978-08-18 1981-07-16 Nouvel initiateur complexe formant catalyseur pour la preparation de polymeres ou de copolymeres notamment de butadiene

Country Status (6)

Country Link
US (1) US4413098A (fr)
JP (1) JPS5527337A (fr)
DE (1) DE2932871C2 (fr)
FR (2) FR2433545A1 (fr)
GB (1) GB2029426B (fr)
IT (1) IT1123533B (fr)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4355156A (en) 1980-02-25 1982-10-19 The General Tire & Rubber Company Solution polymerization
US4302568A (en) 1980-02-25 1981-11-24 The General Tire & Rubber Co. Solution polymerization
US4297240A (en) 1980-02-25 1981-10-27 The General Tire & Rubber Company Solution polymerization
US4307218A (en) 1980-02-25 1981-12-22 The General Tire & Rubber Company Solution polymerization
JPS57123237A (en) * 1981-01-26 1982-07-31 Sumitomo Rubber Ind Ltd Butadiene-isoprene copolymer composition
JPS57100146A (en) * 1980-12-16 1982-06-22 Asahi Chem Ind Co Ltd Novel rubber composition
JPS57145134A (en) * 1981-03-04 1982-09-08 Nippon Zeon Co Ltd Rubber composition
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
JPH0662727B2 (ja) * 1984-08-27 1994-08-17 日本合成ゴム株式会社 ゴム組成物
US4616065A (en) * 1985-04-15 1986-10-07 Gencorp Inc. High trans butadiene based elastomeric block copolymers and blends
DE3710002A1 (de) * 1986-08-14 1988-02-18 Huels Chemische Werke Ag Abc-blockcopolymerisate auf basis von butadien und isopren, verfahren zu ihrer herstellung und ihre verwendung
DE3724871A1 (de) * 1987-07-28 1989-02-09 Huels Chemische Werke Ag Ab-blockcopolymerisate auf basis von butadien, isopren und styrol, verfahren zu ihrer herstellung und ihre verwendung
KR910008275B1 (ko) * 1987-08-19 1991-10-12 아사히가세이고오교 가부시끼가이샤 공역 디엔 화화물 예비중합체 용액 제조를 위한 예비중합방법
US5191021A (en) * 1988-06-29 1993-03-02 The Goodyear Tire & Rubber Company Tire with tread containing styrene, isoprene, butadiene terpolymer rubber
US5047483A (en) * 1988-06-29 1991-09-10 The Goodyear Tire & Rubber Company Pneumatic tire with tread of styrene, isoprene, butadiene rubber
US5254653A (en) * 1989-12-28 1993-10-19 The Goodyear Tire & Rubber Company Terpolymer rubber of styrene, isoprene and butadiene
US5159020A (en) * 1989-12-28 1992-10-27 The Goodyear Tire & Rubber Company Tire with tread comprising styrene, isoprene, butadiene terpolymer rubber
US5210359A (en) * 1990-01-16 1993-05-11 Mobil Oil Corporation Vulcanizable liquid compositions
US5187236A (en) * 1990-01-16 1993-02-16 Mobil Oil Corporation Solid block and random elastomeric copolymers
US5268427A (en) * 1990-01-16 1993-12-07 Mobil Oil Corporation Solid block and random elastomeric copolymers
US5663239A (en) * 1990-01-16 1997-09-02 Mobil Oil Corporation Star-branched block elastomeric copolymers
US5149895A (en) * 1990-01-16 1992-09-22 Mobil Oil Corporation Vulcanizable liquid compositions
US5147951A (en) * 1990-09-21 1992-09-15 Bridgestone/Firestone, Inc. Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds
US5272203A (en) * 1990-09-21 1993-12-21 Bridgestone/Firestone, Inc. High performance tire treads and tires
US5260370A (en) * 1990-09-21 1993-11-09 Bridgestone Corporation Oil extended ultra high molecular weight elastomers
US5231152A (en) * 1990-12-18 1993-07-27 Bridgestone Corporation Continuous process for preparing copolymers of conjugated dienes and aromatic vinyl compounds
US5510548A (en) * 1995-02-03 1996-04-23 Mobil Oil Corporation Vulcanizable liquid compositions
EP0818478B1 (fr) * 1995-03-30 2004-08-11 Zeon Corporation Caoutchouc au copolymere styrene-isoprene-butadiene et son procede de production
US5844044A (en) * 1997-07-18 1998-12-01 The Goodyear Tire & Rubber Company Trans 1,4-butadiene/isoprene copolymers and tire with tread thereof
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
US6204320B1 (en) * 1999-02-12 2001-03-20 The Goodyear Tire & Rubber Company Liquid isoprene-butadiene rubber
US20050061418A1 (en) * 2003-08-25 2005-03-24 Bates Kenneth Allen Pneumatic tire having a component containing high trans isoprene-butadiene rubber
JP5331756B2 (ja) * 2010-06-29 2013-10-30 ダンロップスポーツ株式会社 ゴルフボール
CA2826711C (fr) 2011-02-14 2020-07-14 Kuraray America Inc. Formulations elastomeres utiles dans des films et des feuilles
CN105601814B (zh) 2016-03-24 2020-11-27 青岛科技大学 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置
CN110139882A (zh) 2016-11-09 2019-08-16 株式会社普利司通 聚丁二烯和聚异戊二烯的高顺式-1,4嵌段共聚物
CN112210127B (zh) * 2019-07-09 2023-08-01 中国石油化工股份有限公司 一种高性能子午线轮胎胎面基部用胶及其制备方法
CN112210128B (zh) * 2019-07-09 2023-09-01 中国石油化工股份有限公司 一种基于梯度嵌段锂系bir的轮胎胎侧胶料及制备方法
CN112210040B (zh) * 2019-07-09 2024-01-30 中国石油化工股份有限公司 一种宽分布聚丁二烯-异戊二烯橡胶及其制备方法
CN113563685B (zh) * 2020-04-29 2023-10-13 中国石油化工股份有限公司 一种全钢载重子午线轮胎配方胶料及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1271265A (en) * 1968-06-08 1972-04-19 Bridgestone Tire Co Ltd Method of preparing conjugated diene polymers using catalysts based on organolithium compounds
US3846385A (en) * 1973-07-16 1974-11-05 Gen Tire & Rubber Co Preparation of solution polymers using a barium di-tert alkoxide and a di-butyl magnesium catalyst complex
US4092268A (en) * 1974-06-05 1978-05-30 Compagnie Generale Des Etablissements Michelin, Raison Sociale Michelin & Cie Catalytic composition
FR2340958A2 (fr) 1974-06-05 1977-09-09 Michelin & Cie Procede de polymerisation ou de copolymerisation de dienes conjugues et polymeres ainsi obtenus
US4048427A (en) * 1975-07-07 1977-09-13 The General Tire & Rubber Company Preparation of solution polymers
US3992561A (en) * 1975-07-07 1976-11-16 The General Tire & Rubber Company Preparation of solution polymers

Also Published As

Publication number Publication date
FR2483428A1 (fr) 1981-12-04
DE2932871C2 (de) 1986-11-20
DE2932871A1 (de) 1980-02-21
FR2483428B1 (fr) 1984-04-27
FR2433545B1 (fr) 1982-09-17
IT1123533B (it) 1986-04-30
GB2029426B (en) 1982-12-22
JPH0231084B2 (fr) 1990-07-11
US4413098A (en) 1983-11-01
IT7925174A0 (it) 1979-08-20
GB2029426A (en) 1980-03-19
JPS5527337A (en) 1980-02-27

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