FR2419281A1 - Procede de production de methylmercaptan - Google Patents
Procede de production de methylmercaptanInfo
- Publication number
- FR2419281A1 FR2419281A1 FR7905762A FR7905762A FR2419281A1 FR 2419281 A1 FR2419281 A1 FR 2419281A1 FR 7905762 A FR7905762 A FR 7905762A FR 7905762 A FR7905762 A FR 7905762A FR 2419281 A1 FR2419281 A1 FR 2419281A1
- Authority
- FR
- France
- Prior art keywords
- sulfide
- hydroxide
- salt
- oxide
- methylmercaptan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229930182817 methionine Natural products 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
L'invention concerne un procédé perfectionné de production de méthylmercaptan par réaction d'oxyde de carbone, d'hydrogène et d'hydrogène sulfuré en présence d'un catalyseur à haute température et à haute pression. Le perfectionnement consiste à utiliser un catalyseur solide à une seule phase, fixé sur un support, par mélange d'un oxyde, d'un sulfure, d'un hydroxyde ou d'un sel d'un métal choisi entre le fer, le nickel, le chrome, le cobalt et le molybdène avec une amine organique ou une base minérale de métal alcalin qui est un oxyde, un hydroxyde, un sulfure ou un sel, puis à sulfurer le mélange. Le méthylmercaptan est utilisé comme composé intermédiaire pour la fabrication de divers produits chimiques destinés à l'agriculture et comme matière première dans la production de la méthionine.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US88343878A | 1978-03-06 | 1978-03-06 | |
US1197779A | 1979-02-14 | 1979-02-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2419281A1 true FR2419281A1 (fr) | 1979-10-05 |
FR2419281B1 FR2419281B1 (fr) | 1984-06-22 |
Family
ID=26683002
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7905762A Granted FR2419281A1 (fr) | 1978-03-06 | 1979-03-06 | Procede de production de methylmercaptan |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPS54135715A (fr) |
AR (1) | AR222991A1 (fr) |
BR (1) | BR7901361A (fr) |
CA (1) | CA1120499A (fr) |
DE (1) | DE2908668A1 (fr) |
ES (1) | ES478320A1 (fr) |
FR (1) | FR2419281A1 (fr) |
GB (1) | GB2016468B (fr) |
IT (1) | IT1114467B (fr) |
MX (1) | MX151167A (fr) |
NL (1) | NL190447C (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010046607A1 (fr) * | 2008-10-24 | 2010-04-29 | Arkema France | Catalyseur d'hydrogénation, notamment de sulfure de carbone |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4536492A (en) * | 1982-09-29 | 1985-08-20 | Pennwalt Corporation | Catalyst for the preparation of methyl mercaptan from carbon oxides |
US4449006A (en) * | 1982-09-29 | 1984-05-15 | Pennwalt Corporation | Preparation of methyl mercaptan from carbon oxides |
US4491639A (en) * | 1982-09-30 | 1985-01-01 | Gas Research Institute | Methods of making high activity transition metal catalysts |
RU2394023C2 (ru) * | 2003-10-10 | 2010-07-10 | Эвоник Дегусса Гмбх | Способ получения метилмеркаптана |
CN101143329A (zh) * | 2006-09-11 | 2008-03-19 | 德古萨股份公司 | Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用 |
EP1982764A1 (fr) * | 2007-04-17 | 2008-10-22 | Evonik Degussa GmbH | Catalyseur pour la préparation de mercaptan de méthyle |
DE102007024576A1 (de) * | 2007-05-25 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoff- und wasserstoffhaltigen Verbindungen |
DE102009027837A1 (de) * | 2009-07-20 | 2011-01-27 | Evonik Degussa Gmbh | Verfahren zur kontinuierlichen Herstellung von Methylmercaptan aus kohlenstoffhaltigen Verbindungen, Schwefel und Wasserstoff |
CA3020740A1 (fr) | 2016-05-31 | 2017-12-07 | Novus International Inc. | Procede de production de methyle mercaptan a partir de sulfure de dimethyle |
CN114849693A (zh) * | 2022-06-17 | 2022-08-05 | 黄河三角洲京博化工研究院有限公司 | 一种用于合成甲硫醇的催化剂、制备方法及应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3070632A (en) * | 1959-12-21 | 1962-12-25 | Pennsalt Chemicals Corp | Process for preparation of methyl mercaptan |
-
1979
- 1979-03-01 GB GB7907182A patent/GB2016468B/en not_active Expired
- 1979-03-05 IT IT48218/79A patent/IT1114467B/it active
- 1979-03-05 NL NLAANVRAGE7901730,A patent/NL190447C/xx not_active IP Right Cessation
- 1979-03-05 CA CA000322731A patent/CA1120499A/fr not_active Expired
- 1979-03-05 MX MX176799A patent/MX151167A/es unknown
- 1979-03-06 ES ES478320A patent/ES478320A1/es not_active Expired
- 1979-03-06 FR FR7905762A patent/FR2419281A1/fr active Granted
- 1979-03-06 JP JP2519279A patent/JPS54135715A/ja active Granted
- 1979-03-06 BR BR7901361A patent/BR7901361A/pt unknown
- 1979-03-06 DE DE2908668A patent/DE2908668A1/de active Granted
- 1979-03-06 AR AR275717A patent/AR222991A1/es active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3070632A (en) * | 1959-12-21 | 1962-12-25 | Pennsalt Chemicals Corp | Process for preparation of methyl mercaptan |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010046607A1 (fr) * | 2008-10-24 | 2010-04-29 | Arkema France | Catalyseur d'hydrogénation, notamment de sulfure de carbone |
FR2937566A1 (fr) * | 2008-10-24 | 2010-04-30 | Arkema France | Catalyseur d'hydrogenation, notamment de sulfure de carbone |
US8426648B2 (en) | 2008-10-24 | 2013-04-23 | Arkema France | Hydrogenation catalyst, particularly for carbon disulphide |
Also Published As
Publication number | Publication date |
---|---|
ES478320A1 (es) | 1980-01-16 |
DE2908668C2 (fr) | 1992-10-29 |
AR222991A1 (es) | 1981-07-15 |
BR7901361A (pt) | 1979-10-02 |
NL190447B (nl) | 1993-10-01 |
IT7948218A0 (it) | 1979-03-05 |
FR2419281B1 (fr) | 1984-06-22 |
CA1120499A (fr) | 1982-03-23 |
DE2908668A1 (de) | 1979-09-20 |
IT1114467B (it) | 1986-01-27 |
JPS54135715A (en) | 1979-10-22 |
GB2016468B (en) | 1982-09-15 |
NL190447C (nl) | 1994-03-01 |
GB2016468A (en) | 1979-09-26 |
MX151167A (es) | 1984-10-08 |
JPS6312866B2 (fr) | 1988-03-23 |
NL7901730A (nl) | 1979-09-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
CD | Change of name or company name | ||
ST | Notification of lapse |