FR2416910A1 - Procede de preparation de copolymeres greffes modifies cellulose-monomeres monovinyliques - Google Patents

Procede de preparation de copolymeres greffes modifies cellulose-monomeres monovinyliques

Info

Publication number
FR2416910A1
FR2416910A1 FR7830086A FR7830086A FR2416910A1 FR 2416910 A1 FR2416910 A1 FR 2416910A1 FR 7830086 A FR7830086 A FR 7830086A FR 7830086 A FR7830086 A FR 7830086A FR 2416910 A1 FR2416910 A1 FR 2416910A1
Authority
FR
France
Prior art keywords
monovinyl
copolymers
modification
graft
cellulose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7830086A
Other languages
English (en)
Other versions
FR2416910B1 (fr
Inventor
M O Lishevskaya
B P Morin
G I Stanchenko
T A Vanjushkina
Z A Rogovin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Moskovsky Textilny Institut
Original Assignee
Moskovsky Textilny Institut
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Moskovsky Textilny Institut filed Critical Moskovsky Textilny Institut
Publication of FR2416910A1 publication Critical patent/FR2416910A1/fr
Application granted granted Critical
Publication of FR2416910B1 publication Critical patent/FR2416910B1/fr
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16Organic material
    • B01J39/18Macromolecular compounds
    • B01J39/22Cellulose or wood; Derivatives thereof
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D9/00Composition of chemical substances for use in breathing apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00Ion-exchange processes in general; Apparatus therefor
    • B01J47/12Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes
    • B01J47/127Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes in the form of filaments or fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F251/00Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
    • C08F251/02Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Pulmonology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention concerne l'obtention de copolymères. Le procédé conforme à l'invention, de préparation de copolymères greffés modifiés cellulo-monomères monovinyliques contenant des groupements ionogènes ou des groupements non ionogènes capables de se transformer en groupements ionogène du type comprenant une copolymérisation en greffe par radicaux libres sur la cellulose desdits monomères monovinyliques en présence d'un amorceur du type à radicaux libres, et une modification, est caractérisé en ce qu'on effectue les processus de polymérisation en greffe par radicaux libres et de modification en un stade unique en présence d'un agent modificateur tel que le divinyl-benzène à raison de 1 à 5 % en moles par rapport au monomère monovinylique, en soumettant à la modification les copolymères greffés cellulose-monomères monovinyliques qui se forment au cours de la polymérisation en greffe par radicaux libres. Les copolymères en question sont utilisés dans les processus d'échange d'ions, notamment pour le piégeage d'ions de métaux précieux et d'autres métaux, pour la purification des eaux résiduaires, des sirops de sucre, etc.
FR7830086A 1978-02-14 1978-10-23 Procede de preparation de copolymeres greffes modifies cellulose-monomeres monovinyliques Granted FR2416910A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU782581701A SU806692A1 (ru) 1978-02-14 1978-02-14 Способ получени целлюлозных волок-НиСТыХ иОНиТОВ

Publications (2)

Publication Number Publication Date
FR2416910A1 true FR2416910A1 (fr) 1979-09-07
FR2416910B1 FR2416910B1 (fr) 1980-10-31

Family

ID=20749766

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7830086A Granted FR2416910A1 (fr) 1978-02-14 1978-10-23 Procede de preparation de copolymeres greffes modifies cellulose-monomeres monovinyliques

Country Status (7)

Country Link
US (1) US4198326A (fr)
AT (1) AT366075B (fr)
DE (1) DE2845259A1 (fr)
FR (1) FR2416910A1 (fr)
IT (1) IT7851666A0 (fr)
NL (1) NL174555C (fr)
SU (1) SU806692A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0042075A1 (fr) * 1980-06-18 1981-12-23 Texcontor-Anstalt Copolymères à activité bactéricide, procédé pour leur préparation et compositions pharmaceutiques obtenues à partir de ceux-ci

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0045823A1 (fr) * 1980-08-08 1982-02-17 Tokyo Organic Chemical Industries, Ltd. Matières fibreuses d'échange d'ions, leur préparation et application
US4517351A (en) * 1982-08-11 1985-05-14 National Starch And Chemical Corporation Process for reacting quaternary ammonium monomer in the presence of anionic polymers
AU580548B2 (en) * 1983-02-14 1989-01-19 Cuno Incorporated Polymer modified polysaccharide
US4663163A (en) * 1983-02-14 1987-05-05 Hou Kenneth C Modified polysaccharide supports
SE437146B (sv) * 1983-04-06 1985-02-11 Srs Water Research Corp Ab Sett och jonbytarblandning for att rena vatten vid fiskodling
US5082497A (en) * 1990-09-24 1992-01-21 Westvaco Corporation Solution rosin resinate for publication gravure inks
SE0302509D0 (sv) 2003-09-19 2003-09-19 Amersham Biosciences Ab Matrix for separation of polyethers and method of separation
CN100434448C (zh) * 2005-11-04 2008-11-19 中国科学院化学研究所 基于羧甲基纤维素钠改性的电极表面修饰材料及其制备方法
CN101200523B (zh) * 2007-11-26 2010-06-16 天津科技大学 一种从制浆废液制备聚合物溶液的方法
CN110975832A (zh) * 2019-12-11 2020-04-10 安徽大学 一种高效除去重金属离子的秸秆基水凝胶吸附剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3184421A (en) * 1961-05-24 1965-05-18 Eastman Kodak Co Polymeric composition prepared from cellulose sulfate and alkyl acrylate and textilematerial coated therewith
FR2066423A5 (fr) * 1969-10-24 1971-08-06 Eastman Kodak Co
FR2305452A1 (fr) * 1975-03-27 1976-10-22 Sanyo Chemical Ind Ltd Nouvelles resines hydro-absorbantes et leurs applications
GB1490128A (en) * 1976-05-14 1977-10-26 Revertex Ltd Hydrophilic polymeric materials and method of making them

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3889678A (en) * 1973-12-07 1975-06-17 Personal Products Co Cellulose graft copolymer containing non-ionic and ionic polymer moieties as absorbent media in absorbent dressings

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3184421A (en) * 1961-05-24 1965-05-18 Eastman Kodak Co Polymeric composition prepared from cellulose sulfate and alkyl acrylate and textilematerial coated therewith
FR2066423A5 (fr) * 1969-10-24 1971-08-06 Eastman Kodak Co
FR2305452A1 (fr) * 1975-03-27 1976-10-22 Sanyo Chemical Ind Ltd Nouvelles resines hydro-absorbantes et leurs applications
GB1490128A (en) * 1976-05-14 1977-10-26 Revertex Ltd Hydrophilic polymeric materials and method of making them

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0042075A1 (fr) * 1980-06-18 1981-12-23 Texcontor-Anstalt Copolymères à activité bactéricide, procédé pour leur préparation et compositions pharmaceutiques obtenues à partir de ceux-ci

Also Published As

Publication number Publication date
AT366075B (de) 1982-03-10
SU806692A1 (ru) 1981-02-23
DE2845259A1 (de) 1979-10-04
IT7851666A0 (it) 1978-10-26
NL7810636A (nl) 1979-08-16
FR2416910B1 (fr) 1980-10-31
ATA747178A (de) 1981-07-15
US4198326A (en) 1980-04-15
NL174555C (nl) 1984-07-02

Similar Documents

Publication Publication Date Title
FR2416910A1 (fr) Procede de preparation de copolymeres greffes modifies cellulose-monomeres monovinyliques
AU1542788A (en) Branched acrylate copolymerisate with polymerizable double bonds and process for manufacture thereof
EP0270515A3 (en) Process for the production of transparent block copolymers
JPS56155212A (en) Manufacture of polymer dispersion
EP0231395A4 (fr) Procede de production de polymere de methacrylate.
DE3460294D1 (en) Process for the manufacture of 2-cyanoacrylates from 2,4-dicyanoglutarates
IT1196375B (it) Metodo per la preparazione di copolimeri aggraffati per polimerizzazione in emulsione
DE69020299D1 (de) Verfahren zur Herstellung von Kesselstein verhindernden Mitteln.
FR2372189A1 (fr) Nouveaux melanges reactionnels, leur procede de preparation et leur utilisation comme initiateurs de polymerisation
DE3165078D1 (en) Process for the preparation of a graft copolymer
FR2430428A1 (fr) Nouveaux amorceurs de polymerisation anionique a base d'amidures alcalins et procede de polymerisation anionique les utilisant
FR2388002A1 (fr) Procede de traitement de suspensions de copolymeres de chlorure de vinyle et d'acetate de vinyle
FR2416909A1 (fr) Procede de preparation de copolymeres greffes cellulose-vinylpyridines
EP0180262A3 (fr) Procédé de préparation de polymeres de vinylsaccharide solubles dans l'eau
FR2356681A1 (fr) Procede de greffage de caoutchoucs avec des monomeres mono-alkenylaromatiques par polymerisation en masse et nouveaux produits ainsi obtenus
ATE58743T1 (de) Vinylchloridcopolymere und herstellungsverfahren.
FR2705958B1 (fr) Procédé pour le traitement des effluents générés par les procédés de traitement des métaux, en particulier les procédés de nickelage .
GB1569503A (en) High molecular weight polymers
FR2406645A1 (fr) Procede de preparation de copolymeres greffes a partir de monomeres insatures et de peroxy-diester-polyols, produits obtenus et leur application a la production de polyurethannes
ES8203107A1 (es) Procedimiento y aparato para eliminar metales de soluciones de sales metalicas
SU1368780A1 (ru) Способ определени количества привитого полимера,содержащего четвертичную аммониевую группу,в целлюлозном волокне
ES441220A1 (es) Procedimiento para la obtencion de azucar invertido purifi- cado.
AU536206B2 (en) Ethylene polymerisation apparatus
UA41905C2 (uk) Спосіб виготовлення глинозему за методом бауера
FR2664601B1 (fr) Procede de preparation de monomeres de saccharides comportant au moins un groupement carbonyloxyvinylique polymerisable.

Legal Events

Date Code Title Description
ST Notification of lapse