FR2415628A1 - Procede de preparation d'urethannes aromatiques - Google Patents
Procede de preparation d'urethannes aromatiquesInfo
- Publication number
- FR2415628A1 FR2415628A1 FR7802127A FR7802127A FR2415628A1 FR 2415628 A1 FR2415628 A1 FR 2415628A1 FR 7802127 A FR7802127 A FR 7802127A FR 7802127 A FR7802127 A FR 7802127A FR 2415628 A1 FR2415628 A1 FR 2415628A1
- Authority
- FR
- France
- Prior art keywords
- cpd
- prepn
- hydroxy
- metal
- relatively low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Suivant l'invention, on prépare un uréthanne aromatique de haute qualité et très stable à la chaleur avec un rendement élevé par interaction d'un composé nitro aromatique, d'un composé organique contenant un groupe hydroxyle et d'oxyde de carbone en présence d'un système catalytique se composant de palladium, ruthénium, rhodium ou d'un composé de ces derniers, d'un acide de Lewis, et d'ammoniac. L'utilisation d'un tel système catalytique supprime les réactions secondaires indésirables dans une mesure convenable et assure que la réaction se déroule sans provoquer de corrosion du réacteur en acier inoxydable. Si nécessaire, on peut ajouter de l'eau au système réactionnel pour accélérer la vitesse de réaction de manière à pouvoir réduire le prix unitaire du catalyseur.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7802127A FR2415628A1 (fr) | 1978-01-26 | 1978-01-26 | Procede de preparation d'urethannes aromatiques |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7802127A FR2415628A1 (fr) | 1978-01-26 | 1978-01-26 | Procede de preparation d'urethannes aromatiques |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2415628A1 true FR2415628A1 (fr) | 1979-08-24 |
FR2415628B1 FR2415628B1 (fr) | 1981-11-20 |
Family
ID=9203830
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7802127A Granted FR2415628A1 (fr) | 1978-01-26 | 1978-01-26 | Procede de preparation d'urethannes aromatiques |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2415628A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0014845A1 (fr) * | 1979-02-02 | 1980-09-03 | Bayer Ag | Procédé de préparation d'uréthanes |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3454620A (en) * | 1965-11-08 | 1969-07-08 | Ici Ltd | Process for manufacture of urethanes from hydroxyl group containing compound,nitrogenous compound and carbon monoxide in presence of transition metal compound |
US3467694A (en) * | 1965-10-15 | 1969-09-16 | American Cyanamid Co | Process for producing urethanes |
US3531512A (en) * | 1965-10-15 | 1970-09-29 | American Cyanamid Co | Process of producing urethanes |
FR2295020A1 (fr) * | 1974-12-19 | 1976-07-16 | Mitsui Toatsu Chemicals | Procede de preparation d'un ester alcoylique d'un acide carbamique aromatique |
FR2299317A1 (fr) * | 1975-01-30 | 1976-08-27 | Mitsui Toatsu Chemicals | Procede de preparation d'un urethanne aromatique |
US3993685A (en) * | 1974-10-21 | 1976-11-23 | Atlantic Richfield Company | Process for the production of urethanes |
US4052437A (en) * | 1975-09-22 | 1977-10-04 | Ethyl Corporation | Process for producing urethane from nitro compounds, hydroxyl compounds and carbon monoxide using rhodium oxide catalysts |
-
1978
- 1978-01-26 FR FR7802127A patent/FR2415628A1/fr active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3467694A (en) * | 1965-10-15 | 1969-09-16 | American Cyanamid Co | Process for producing urethanes |
US3531512A (en) * | 1965-10-15 | 1970-09-29 | American Cyanamid Co | Process of producing urethanes |
US3454620A (en) * | 1965-11-08 | 1969-07-08 | Ici Ltd | Process for manufacture of urethanes from hydroxyl group containing compound,nitrogenous compound and carbon monoxide in presence of transition metal compound |
US3993685A (en) * | 1974-10-21 | 1976-11-23 | Atlantic Richfield Company | Process for the production of urethanes |
FR2295020A1 (fr) * | 1974-12-19 | 1976-07-16 | Mitsui Toatsu Chemicals | Procede de preparation d'un ester alcoylique d'un acide carbamique aromatique |
FR2299317A1 (fr) * | 1975-01-30 | 1976-08-27 | Mitsui Toatsu Chemicals | Procede de preparation d'un urethanne aromatique |
US4052437A (en) * | 1975-09-22 | 1977-10-04 | Ethyl Corporation | Process for producing urethane from nitro compounds, hydroxyl compounds and carbon monoxide using rhodium oxide catalysts |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0014845A1 (fr) * | 1979-02-02 | 1980-09-03 | Bayer Ag | Procédé de préparation d'uréthanes |
Also Published As
Publication number | Publication date |
---|---|
FR2415628B1 (fr) | 1981-11-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |