FR2407745A1 - CATALYST AND CRACKING AND ITS PREPARATION PROCESS - Google Patents

CATALYST AND CRACKING AND ITS PREPARATION PROCESS

Info

Publication number
FR2407745A1
FR2407745A1 FR7830900A FR7830900A FR2407745A1 FR 2407745 A1 FR2407745 A1 FR 2407745A1 FR 7830900 A FR7830900 A FR 7830900A FR 7830900 A FR7830900 A FR 7830900A FR 2407745 A1 FR2407745 A1 FR 2407745A1
Authority
FR
France
Prior art keywords
approximately
catalyst
weight
cracking
clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7830900A
Other languages
French (fr)
Other versions
FR2407745B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GCP Products UK Ltd
WR Grace and Co Conn
Original Assignee
WR Grace Ltd
WR Grace and Co Conn
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace Ltd, WR Grace and Co Conn filed Critical WR Grace Ltd
Publication of FR2407745A1 publication Critical patent/FR2407745A1/en
Application granted granted Critical
Publication of FR2407745B1 publication Critical patent/FR2407745B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12Noble metals
    • B01J29/126Y-type faujasite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'INVENTION CONCERNE UN CATALYSEUR DE CRAQUAGE RESISTANT AUX OXYDES DE SOUFRE ET AUX METAUX LOURDS. LE CATALYSEUR SELON L'INVENTION CONTIENT: A.ENVIRON 12 A 60 EN POIDS D'UNE ZEOLITE TRAITEE PAR UN SEL D'UN METAL DES GROUPES II ET VIII DE LA CLASSIFICATION PERIODIQUE DES ELEMENTS; B.FACULTATIVEMENT JUSQU'A 75 EN POIDS D'ARGILE; C.D'ENVIRON, 20 A 50 EN POIDS DE TRIHYDRATE D'ALUMINE A; D.UN LIANT INORGANIQUE DU TYPE OXYDE, LADITE ZEOLITE A, LADITE ARGILE B, LADITE ALUMINE C ET LEDIT LIANT D ETANT MELANGES SOUS FORME DE PARTICULES DE CATALYSEURS; ET E.ENVIRON 0,1 A 20 PPM DE PLATINE, PALLADIUM OU LEURS MELANGES. APPLICATION : CRAQUAGE CATALYTIQUE DES CHARGES D'HYDROCARBURES CONTENANT DU SOUFRE ETOU DES METAUX LOURDS POUR DONNER DES RENDEMENTS ELEVES D'ESSENCE AVEC DE FAIBLES EMISSIONS DE CO ET D'OXYDES DE SOUFRE.THE INVENTION RELATES TO A CRACKING CATALYST RESISTANT TO SULFUR OXIDES AND HEAVY METALS. THE CATALYST ACCORDING TO THE INVENTION CONTAINS: A. APPROXIMATELY 12 TO 60 BY WEIGHT OF A ZEOLITE TREATED WITH A SALT OF A METAL FROM GROUPS II AND VIII OF THE PERIODIC CLASSIFICATION OF THE ELEMENTS; B. OPTIONALLY UP TO 75 BY WEIGHT OF CLAY; C. APPROXIMATELY 20 TO 50 BY WEIGHT OF ALUMINA A TRIHYDRATE; D. AN INORGANIC BINDER OF THE OXIDE TYPE, SAID ZEOLITE A, SAID CLAY B, SAID ALUMINA C AND SAID BINDER D WHICH ARE MIXED IN THE FORM OF CATALYST PARTICLES; AND E APPROXIMATELY 0.1 TO 20 PPM OF PLATINUM, PALLADIUM OR THEIR MIXTURES. APPLICATION: CATALYTIC CRACKING OF HYDROCARBON LOADS CONTAINING SULFUR AND OR HEAVY METALS TO GIVE HIGH GASOLINE YIELDS WITH LOW CO AND SULFUR OXIDES EMISSIONS.

FR7830900A 1977-11-02 1978-10-31 CATALYST AND CRACKING AND ITS PREPARATION PROCESS Granted FR2407745A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US84780077A 1977-11-02 1977-11-02

Publications (2)

Publication Number Publication Date
FR2407745A1 true FR2407745A1 (en) 1979-06-01
FR2407745B1 FR2407745B1 (en) 1984-11-09

Family

ID=25301544

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7830900A Granted FR2407745A1 (en) 1977-11-02 1978-10-31 CATALYST AND CRACKING AND ITS PREPARATION PROCESS

Country Status (7)

Country Link
JP (1) JPS5472790A (en)
AU (1) AU522835B2 (en)
CA (1) CA1117511A (en)
DE (1) DE2847005A1 (en)
FR (1) FR2407745A1 (en)
GB (1) GB2007107B (en)
NL (1) NL7810826A (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU539269B2 (en) * 1979-10-15 1984-09-20 Mobil Oil Corp. Preparing a zeolite containing group 8 metal catalyst
SE420353B (en) * 1980-04-23 1981-09-28 Pharos Ab DEVICE FOR CHECKING MATERIAL
EP0073874B1 (en) * 1981-03-19 1987-08-26 Ashland Oil, Inc. Immobilisation of vanadia deposited on catalytic materials during the conversion of oil that contains coke precursors and heavy metals
US4429053A (en) * 1981-12-04 1984-01-31 Union Oil Company Of California Rare earth-containing Y zeolite compositions
US4565621A (en) * 1981-12-04 1986-01-21 Union Oil Company Of California Hydrocracking with rare earth-containing Y zeolite compositions
US4604187A (en) * 1981-12-04 1986-08-05 Union Oil Company Of California Hydrocracking with rare earth-containing Y zeolite compositions
US4584287A (en) * 1981-12-04 1986-04-22 Union Oil Company Of California Rare earth-containing Y zeolite compositions
EP0109064A3 (en) * 1982-11-16 1985-06-19 W.R. Grace & Co. Hydrocarbon conversion catalysts
EP0124122B1 (en) * 1983-05-02 1986-12-30 Union Carbide Corporation Catalytic cracking catalyst and process
ATE27827T1 (en) * 1983-05-02 1987-07-15 Union Carbide Corp CATALYST AND PROCESS FOR HYDROCRACKING.
EP0135317B1 (en) * 1983-08-12 1988-09-07 Engelhard Corporation A fluid catalytic cracking catalyst for cracking sulfur containing petroleum feedstocks and a process for using it
JPH01132443A (en) * 1987-11-18 1989-05-24 Mazda Motor Corp Structure for knee protector of vehicle
JPH0454044Y2 (en) * 1988-07-29 1992-12-18
US5168086A (en) * 1989-03-02 1992-12-01 W. R. Grace & Co.-Conn. Catalytic cracking catalysis
US5147836A (en) * 1991-10-18 1992-09-15 W. R. Grace & Co.-Conn. Catalytic cracking catalysts
US5304526A (en) 1991-10-18 1994-04-19 W. R. Grace & Co.-Conn. Silica bayerite/eta alumina
EP0568170B1 (en) * 1992-04-27 1995-11-08 W.R. Grace & Co.-Conn. Catalytic cracking catalysts and additives
US5376608A (en) * 1993-01-27 1994-12-27 W. R. Grace & Co.-Conn. Sulfur reduction in FCC gasoline
US6974787B2 (en) 1998-08-31 2005-12-13 Exxonmobil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US6852214B1 (en) 1998-08-31 2005-02-08 Mobil Oil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US20020153283A1 (en) 1998-12-28 2002-10-24 Arthur W Chester Gasoline sulfur reduction in fluid catalytic cracking
US6846403B2 (en) 1998-12-28 2005-01-25 Mobil Oil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US7803267B2 (en) 1998-12-28 2010-09-28 W. R. Grace & Co.-Conn. Gasoline sulfur reduction in fluid catalytic cracking
US7507686B2 (en) 2002-12-03 2009-03-24 W. R. Grace & Co. - Conn. Gasoline sulfur reduction in fluid catalytic cracking
JP4818131B2 (en) * 2007-01-16 2011-11-16 一般財団法人石油エネルギー技術センター Hydrocarbon oil catalytic cracking catalyst and method for catalytic cracking of hydrocarbon oil using the catalyst
JP4916320B2 (en) * 2007-01-19 2012-04-11 一般財団法人石油エネルギー技術センター Hydrocarbon oil catalytic cracking catalyst and method for catalytic cracking of hydrocarbon oil using the catalyst
JP4818135B2 (en) * 2007-01-19 2011-11-16 一般財団法人石油エネルギー技術センター Hydrocarbon oil catalytic cracking catalyst and method for catalytic cracking of hydrocarbon oil using the catalyst
JP4818156B2 (en) * 2007-02-19 2011-11-16 一般財団法人石油エネルギー技術センター Hydrocarbon oil catalytic cracking catalyst and method for catalytic cracking of hydrocarbon oil using the catalyst

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3267022A (en) * 1964-01-24 1966-08-16 Union Oil Co Hydrocracking process and catalysts
FR1529190A (en) * 1967-06-26 1968-06-14 Exxon Research Engineering Co Improved catalysts and their use in hydrocarbon conversion processes
GB1117210A (en) * 1965-10-05 1968-06-19 Grace W R & Co Catalytic cracking of hydrocarbons and catalyst therefor
US3554899A (en) * 1968-11-26 1971-01-12 Union Oil Co Hydrocracking process
US3607043A (en) * 1969-11-19 1971-09-21 Grace W R & Co Cation and thermal stabilization of a faujasite-type zeolite
US3867308A (en) * 1973-12-10 1975-02-18 Grace W R & Co Process for preparing a petroleum cracking catalyst
US3957689A (en) * 1974-08-02 1976-05-18 W. R. Grace & Co. Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst
DE2716121A1 (en) * 1976-04-12 1977-10-20 Exxon Research Engineering Co CATALYST FOR THE CONVERSION OF HYDROCARBONS, THE PROCESS FOR ITS MANUFACTURING AND ITS USE

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3267022A (en) * 1964-01-24 1966-08-16 Union Oil Co Hydrocracking process and catalysts
GB1117210A (en) * 1965-10-05 1968-06-19 Grace W R & Co Catalytic cracking of hydrocarbons and catalyst therefor
FR1529190A (en) * 1967-06-26 1968-06-14 Exxon Research Engineering Co Improved catalysts and their use in hydrocarbon conversion processes
US3554899A (en) * 1968-11-26 1971-01-12 Union Oil Co Hydrocracking process
US3607043A (en) * 1969-11-19 1971-09-21 Grace W R & Co Cation and thermal stabilization of a faujasite-type zeolite
US3867308A (en) * 1973-12-10 1975-02-18 Grace W R & Co Process for preparing a petroleum cracking catalyst
US3957689A (en) * 1974-08-02 1976-05-18 W. R. Grace & Co. Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst
DE2716121A1 (en) * 1976-04-12 1977-10-20 Exxon Research Engineering Co CATALYST FOR THE CONVERSION OF HYDROCARBONS, THE PROCESS FOR ITS MANUFACTURING AND ITS USE
FR2348265A1 (en) * 1976-04-12 1977-11-10 Exxon Research Engineering Co Hydrocarbon conversion catalyst - contg. carbon monoxide oxidn. promoter on oxide carrier and aluminosilicate zeolite in porous oxide matrix

Also Published As

Publication number Publication date
DE2847005A1 (en) 1979-05-03
GB2007107B (en) 1982-05-19
AU4109578A (en) 1980-05-01
GB2007107A (en) 1979-05-16
NL7810826A (en) 1979-05-04
FR2407745B1 (en) 1984-11-09
JPS6240060B2 (en) 1987-08-26
JPS5472790A (en) 1979-06-11
CA1117511A (en) 1982-02-02
AU522835B2 (en) 1982-07-01

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