FR2398043A1 - Procede pour l'obtention de benzoate de phenyle et/ou de phenol - Google Patents

Procede pour l'obtention de benzoate de phenyle et/ou de phenol

Info

Publication number
FR2398043A1
FR2398043A1 FR7821790A FR7821790A FR2398043A1 FR 2398043 A1 FR2398043 A1 FR 2398043A1 FR 7821790 A FR7821790 A FR 7821790A FR 7821790 A FR7821790 A FR 7821790A FR 2398043 A1 FR2398043 A1 FR 2398043A1
Authority
FR
France
Prior art keywords
phenol
phenyl benzoate
benzoic acid
water
dibenzoate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7821790A
Other languages
English (en)
Other versions
FR2398043B1 (fr
Inventor
Placido M Spaziante
Giancarlo Sioli
Luigi Giuffre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PANCLOR CHEMICALS Ltd
Original Assignee
PANCLOR CHEMICALS Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PANCLOR CHEMICALS Ltd filed Critical PANCLOR CHEMICALS Ltd
Publication of FR2398043A1 publication Critical patent/FR2398043A1/fr
Application granted granted Critical
Publication of FR2398043B1 publication Critical patent/FR2398043B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/01—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis
    • C07C37/055—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis the substituted group being bound to oxygen, e.g. ether group
    • C07C37/0555—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by replacing functional groups bound to a six-membered aromatic ring by hydroxy groups, e.g. by hydrolysis the substituted group being bound to oxygen, e.g. ether group being esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procédé amélioré pour l'obtention de phénol, à des rendements élevés. On opère par oxydation de l'acide benzoïque avec au moins un oxyde, hydroxyde ou carbonate de cuivre ou un oxyde de molybdène en présence d'un excès d'acide benzoïque et essentiellement en absence d'eau pour former le dibenzoate métallique correspondant, par chauffage du dibenzoate en absence d'oxygène et d'eau pour effectuer sa décarboxylation et pour former du benzoate de phényle, puis hydrolyse du benzoate de phényle avec l'eau pour former un mélange d'acide benzoïque et de phénol, le phénol étant récupéré dudit mélange Application à la synthèse de benzoate de phényle sans formation de goudron.
FR7821790A 1977-07-22 1978-07-21 Procede pour l'obtention de benzoate de phenyle et/ou de phenol Granted FR2398043A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH915877A CH632478A5 (it) 1977-07-22 1977-07-22 Procedimento per la preparazione del fenolo da acido benzoico.

Publications (2)

Publication Number Publication Date
FR2398043A1 true FR2398043A1 (fr) 1979-02-16
FR2398043B1 FR2398043B1 (fr) 1984-07-13

Family

ID=4348971

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7821790A Granted FR2398043A1 (fr) 1977-07-22 1978-07-21 Procede pour l'obtention de benzoate de phenyle et/ou de phenol

Country Status (13)

Country Link
JP (1) JPS5439039A (fr)
AU (1) AU528850B2 (fr)
BE (1) BE868779A (fr)
CA (1) CA1120949A (fr)
CH (1) CH632478A5 (fr)
DE (1) DE2832192A1 (fr)
ES (1) ES471940A1 (fr)
FR (1) FR2398043A1 (fr)
GB (1) GB2001317B (fr)
IT (1) IT1097832B (fr)
NL (1) NL7807199A (fr)
SE (1) SE7807919L (fr)
ZA (1) ZA784156B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6187646A (ja) * 1984-10-08 1986-05-06 Sagami Chem Res Center フッ素置換安息香酸フェニルの製造方法
NL8903098A (nl) * 1989-12-19 1991-07-16 Stamicarbon Werkwijze voor de bereiding van een fenol.

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2766294A (en) * 1952-05-19 1956-10-09 California Research Corp Process for preparing monohydroxy aromatic compounds from aromatic carboxylic acids

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2766294A (en) * 1952-05-19 1956-10-09 California Research Corp Process for preparing monohydroxy aromatic compounds from aromatic carboxylic acids

Also Published As

Publication number Publication date
DE2832192A1 (de) 1979-02-08
GB2001317B (en) 1982-05-26
IT7825865A0 (it) 1978-07-19
CA1120949A (fr) 1982-03-30
GB2001317A (en) 1979-01-31
AU3749678A (en) 1980-01-03
ZA784156B (en) 1979-07-25
SE7807919L (sv) 1979-01-23
AU528850B2 (en) 1983-05-19
ES471940A1 (es) 1979-10-01
IT1097832B (it) 1985-08-31
JPS5439039A (en) 1979-03-24
CH632478A5 (it) 1982-10-15
BE868779A (fr) 1978-11-03
FR2398043B1 (fr) 1984-07-13
NL7807199A (nl) 1979-01-24

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse