FR2392942A1 - METHOD AND APPARATUS FOR TREATMENT OF WASTE WATER CONTAINING HEAVY METALS - Google Patents

METHOD AND APPARATUS FOR TREATMENT OF WASTE WATER CONTAINING HEAVY METALS

Info

Publication number
FR2392942A1
FR2392942A1 FR7815563A FR7815563A FR2392942A1 FR 2392942 A1 FR2392942 A1 FR 2392942A1 FR 7815563 A FR7815563 A FR 7815563A FR 7815563 A FR7815563 A FR 7815563A FR 2392942 A1 FR2392942 A1 FR 2392942A1
Authority
FR
France
Prior art keywords
metal ions
heavy metal
waste water
heavy metals
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7815563A
Other languages
French (fr)
Other versions
FR2392942B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Filter Co Ltd
Original Assignee
Nihon Filter Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Filter Co Ltd filed Critical Nihon Filter Co Ltd
Publication of FR2392942A1 publication Critical patent/FR2392942A1/en
Application granted granted Critical
Publication of FR2392942B1 publication Critical patent/FR2392942B1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/24—Dialysis ; Membrane extraction
    • B01D61/243—Dialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/422—Electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
    • C02F1/4678—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction of metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
    • C25C1/10—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of chromium or manganese
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/46115—Electrolytic cell with membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4612—Controlling or monitoring
    • C02F2201/4615—Time
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4616—Power supply
    • C02F2201/4617—DC only
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

Abstract

In the known electrolytic treatment of waste waters which contain heavy metal ions such as nickel, copper or zinc to recover the heavy metals with reuse of the electrolyte which accumulates during the electrolysis, the waste water which contains the heavy metal ions and other ions is passed through a concentration and purification unit, e.g. an ion exchange system. The costs for the apparatus and for operation are high in this case. These disadvantages are diminished or eliminated by regenerating the concentration and purification unit with the electrolyte which accumulates in the electrolysis cell, and introducing the eluate which contains the heavy metal ions into the electrolysis cell. This makes it possible to use a simple system which has a clearly arranged construction and which can be operated reliably and with considerably reduced costs for maintenance, chemicals and with a good current efficiency.
FR787815563A 1977-06-01 1978-05-25 PROCESS AND APPARATUS FOR TREATING WASTE WATER CONTAINING HEAVY METALS Expired FR2392942B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2724724A DE2724724C3 (en) 1977-06-01 1977-06-01 Process and system for treating wastewater containing heavy metals while recovering heavy metals

Publications (2)

Publication Number Publication Date
FR2392942A1 true FR2392942A1 (en) 1978-12-29
FR2392942B1 FR2392942B1 (en) 1985-07-26

Family

ID=6010410

Family Applications (1)

Application Number Title Priority Date Filing Date
FR787815563A Expired FR2392942B1 (en) 1977-06-01 1978-05-25 PROCESS AND APPARATUS FOR TREATING WASTE WATER CONTAINING HEAVY METALS

Country Status (5)

Country Link
AT (1) AT381920B (en)
CH (1) CH642033A5 (en)
DE (1) DE2724724C3 (en)
FR (1) FR2392942B1 (en)
IT (1) IT1096410B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2533233A1 (en) * 1982-09-17 1984-03-23 Perrier Materiel Process for the recovery of metals from dilute solutions of their salts and device for its use.
EP0159349A1 (en) * 1983-10-18 1985-10-30 Gnb Batteries Inc. Processes for treating waste streams
EP0280029A2 (en) * 1987-02-25 1988-08-31 Dornier Gmbh Simultaneous removal of heavy metals and oxidizable noxious compounds from waste water
FR2703676A1 (en) * 1993-04-05 1994-10-14 Electricite De France Method and device for decontaminating liquid effluents containing metals in ionic form.

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3345346A1 (en) * 1983-12-15 1985-06-27 Fa. Stadler, 7963 Altshausen METHOD FOR RECOVERING USED PHOTOGRAPHIC FILMS AND LIQUIDS
DE3921180A1 (en) * 1989-06-28 1991-01-03 Gsb Ges Zur Beseitigung Von So METHOD AND SYSTEM FOR THE PURIFICATION OF POLLUTANT-BASED EXHAUST GASES WITH AVOIDANCE OF SALT RESIDUES
DE19850235A1 (en) * 1998-10-31 2000-05-04 Eilenburger Elektrolyse & Umwelttechnik Gmbh Base metals are recovered from acidic process solutions, especially electroplating, pickling or waste solutions, by dosing into a circulating catholyte of a divided electrolysis cell
CN102267774A (en) * 2011-07-27 2011-12-07 宝钢工程技术集团有限公司 Strong brine processing system
CN106698759B (en) * 2015-11-18 2019-08-13 建德蓝忻环境科技有限公司 A kind for the treatment of method of chemical nickel-plating wastewater
CN109250847A (en) * 2018-11-19 2019-01-22 李红燕 It is concisely and efficiently nickel-containing waste water pretreatment unit and technique

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2793183A (en) * 1954-07-15 1957-05-21 Clayton Manufacturing Co Electrolytic and ion exchange treatment of water
GB922148A (en) * 1962-01-23 1963-03-27 Joseph Curry Raine Improvements in or relating to manufacturing processes leading to the purification of effluents
US3547800A (en) * 1967-05-29 1970-12-15 Fairbanks Morse Inc Apparatus and method for purifying waste waters
FR2168605A1 (en) * 1972-01-19 1973-08-31 Dart Ind Inc
US3756932A (en) * 1971-04-08 1973-09-04 Industrial Filter Pump Mfg Co Electrolytic cyanide destruction
FR2233288A1 (en) * 1973-06-15 1975-01-10 Tecneco Spa
DE2623277A1 (en) * 1975-05-24 1976-12-02 Nihon Filter Co Ltd Recovery of heavy metals and water from effluent - by use of ion exchange for sepn. of heavy metal ions and subsequent extraction for recovery by electrolysis

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1054803B (en) * 1957-09-06 1959-04-09 Wilhelm Theodor Schulte Process for the regeneration of metal pickles
DE1621602A1 (en) * 1967-08-17 1970-07-30 Ibm Deutschland Process for the recovery of ammonium persulfate solution
DE2130595A1 (en) * 1971-06-21 1973-02-15 Heinz Janus Pickling of copper - removal of dissolved and solid copper residues,and recovery of copper there from
JP2884860B2 (en) * 1991-10-21 1999-04-19 日本精機株式会社 Display device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2793183A (en) * 1954-07-15 1957-05-21 Clayton Manufacturing Co Electrolytic and ion exchange treatment of water
GB922148A (en) * 1962-01-23 1963-03-27 Joseph Curry Raine Improvements in or relating to manufacturing processes leading to the purification of effluents
US3547800A (en) * 1967-05-29 1970-12-15 Fairbanks Morse Inc Apparatus and method for purifying waste waters
US3756932A (en) * 1971-04-08 1973-09-04 Industrial Filter Pump Mfg Co Electrolytic cyanide destruction
FR2168605A1 (en) * 1972-01-19 1973-08-31 Dart Ind Inc
FR2233288A1 (en) * 1973-06-15 1975-01-10 Tecneco Spa
DE2623277A1 (en) * 1975-05-24 1976-12-02 Nihon Filter Co Ltd Recovery of heavy metals and water from effluent - by use of ion exchange for sepn. of heavy metal ions and subsequent extraction for recovery by electrolysis

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2533233A1 (en) * 1982-09-17 1984-03-23 Perrier Materiel Process for the recovery of metals from dilute solutions of their salts and device for its use.
EP0159349A1 (en) * 1983-10-18 1985-10-30 Gnb Batteries Inc. Processes for treating waste streams
EP0159349A4 (en) * 1983-10-18 1986-11-06 Gnb Batteries Inc Processes for treating waste streams.
EP0280029A2 (en) * 1987-02-25 1988-08-31 Dornier Gmbh Simultaneous removal of heavy metals and oxidizable noxious compounds from waste water
EP0280029A3 (en) * 1987-02-25 1989-03-15 Dornier System Gmbh Simultaneous removal of heavy metals and oxidizable noxious compounds from waste water
FR2703676A1 (en) * 1993-04-05 1994-10-14 Electricite De France Method and device for decontaminating liquid effluents containing metals in ionic form.
EP0623561A1 (en) * 1993-04-05 1994-11-09 Electricite De France Process and device for decontaminating a liquid effluent containing ionic metals

Also Published As

Publication number Publication date
DE2724724C3 (en) 1982-12-16
DE2724724B2 (en) 1979-09-06
CH642033A5 (en) 1984-03-30
IT1096410B (en) 1985-08-26
FR2392942B1 (en) 1985-07-26
DE2724724A1 (en) 1978-12-07
IT7824108A0 (en) 1978-06-01
AT381920B (en) 1986-12-10
ATA383178A (en) 1986-05-15

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Legal Events

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ST Notification of lapse