FR2381751A1 - Regeneration d'agents d'extraction organiques contenant des a-hydroxyoximes ou des cetoximes - Google Patents
Regeneration d'agents d'extraction organiques contenant des a-hydroxyoximes ou des cetoximesInfo
- Publication number
- FR2381751A1 FR2381751A1 FR7805237A FR7805237A FR2381751A1 FR 2381751 A1 FR2381751 A1 FR 2381751A1 FR 7805237 A FR7805237 A FR 7805237A FR 7805237 A FR7805237 A FR 7805237A FR 2381751 A1 FR2381751 A1 FR 2381751A1
- Authority
- FR
- France
- Prior art keywords
- extractant
- solutions
- cetoximes
- hydroxyoximes
- regeneration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/402—Mixtures of acyclic or carbocyclic compounds of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/409—Mixtures at least one compound being an organo-metallic compound
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/09—Reaction techniques
- Y10S423/14—Ion exchange; chelation or liquid/liquid ion extraction
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Pour séparer le nickel du cobalt ou pour récupérer à la fois le nickel et le cobalt à partir des solutions de lessivage des minerais, on traite ces solutions par un agent d'extraction organique liquide comprenant au moins une oxime, qui est une cétoxime ou une alpha -hydroxyoxime. L'agent d'extraction contient également des acides sulfoniques pour faciliter le traitement des solutions de lessivage plus acides, et en raison du caractère acide de ces diverses solutions, les oximes contenus dans l'agent d'extraction se dégradent. L'invention réside dans le traitement de l'agent d'extraction organique par un sel d'une hydroxylamine aux intervalles nécessaires pour maintenir l'activité de l'oxime dans l'agent d'extraction. On régénère ainsi le composant actif de l'agent d'extraction organique.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/772,559 US4104359A (en) | 1977-02-28 | 1977-02-28 | Regeneration of organic extractants containing α-hydroxyoximes |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2381751A1 true FR2381751A1 (fr) | 1978-09-22 |
FR2381751B1 FR2381751B1 (fr) | 1982-03-12 |
Family
ID=25095487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7805237A Granted FR2381751A1 (fr) | 1977-02-28 | 1978-02-23 | Regeneration d'agents d'extraction organiques contenant des a-hydroxyoximes ou des cetoximes |
Country Status (4)
Country | Link |
---|---|
US (1) | US4104359A (fr) |
JP (1) | JPS53113270A (fr) |
CA (1) | CA1111825A (fr) |
FR (1) | FR2381751A1 (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA79175B (en) * | 1978-01-17 | 1980-01-30 | Matthey Rustenburg Refines | Solvent extraction |
US4237069A (en) * | 1979-07-02 | 1980-12-02 | Allied Chemical Corporation | Production of alpha-hydroxy oximes |
US4254087A (en) * | 1979-07-25 | 1981-03-03 | The Dow Chemical Company | Extraction of copper, nickel and cobalt using alkylaromatic sulfonic acids and chelating amines |
US5360459A (en) * | 1991-05-13 | 1994-11-01 | The Lubrizol Corporation | Copper-containing organometallic complexes and concentrates and diesel fuels containing same |
IL100669A0 (en) * | 1991-05-13 | 1992-09-06 | Lubrizol Corp | Low-sulfur diesel fuel containing organometallic complexes |
US5344467A (en) * | 1991-05-13 | 1994-09-06 | The Lubrizol Corporation | Organometallic complex-antioxidant combinations, and concentrates and diesel fuels containing same |
TW230781B (fr) * | 1991-05-13 | 1994-09-21 | Lubysu Co | |
US5376154A (en) * | 1991-05-13 | 1994-12-27 | The Lubrizol Corporation | Low-sulfur diesel fuels containing organometallic complexes |
US5993757A (en) * | 1997-03-03 | 1999-11-30 | Henkel Corporation | Reoximation of metal extraction circuit organics |
CA2554438A1 (fr) * | 2004-01-28 | 2005-08-11 | Commonwealth Scientific And Industrial Research Organisation | Procede d'extraction au solvant servant a separer cobalt et/ou manganese d'impuretes contenues dans des solutions de lixiviation |
EP1716262A4 (fr) * | 2004-01-28 | 2008-08-13 | Commw Scient Ind Res Org | Procede d'extraction par solvants pour la separation de cobalt et/ou de nickel a partir d'impuretes dans des solutions de lessivage |
FI122939B (fi) * | 2009-06-11 | 2012-09-14 | Outotec Oyj | Menetelmä ja laitteisto uuttoliuoksen regeneroimiseksi metallien uuttoprosesseissa |
CN103572054A (zh) * | 2013-11-25 | 2014-02-12 | 重庆浩康医药化工集团有限公司 | 湿法冶金萃取系统中醛肟类萃取剂的再生工艺 |
FI20155195A (fi) | 2015-03-20 | 2016-09-21 | Outotec Finland Oy | Hajonneiden oksiimimetalliuuttojen käsittely orgaanisissa prosessiliuoksissa |
CN111349785A (zh) * | 2018-12-24 | 2020-06-30 | 格林美(江苏)钴业股份有限公司 | 一种再生铜萃取剂的制备方法及其生产装置 |
KR102247859B1 (ko) * | 2020-12-28 | 2021-05-04 | 한국광물자원공사 | 하이드록시 옥심의 제조 방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1131203B (de) * | 1954-07-27 | 1962-06-14 | Bayer Ag | Verfahren zur Gewinnung von reinem Acetoxim und von reinen Hydroxylaminsalzen |
FR1312074A (fr) * | 1961-11-15 | 1962-12-14 | Du Pont | Procédé de préparation de cyclohexanone-oxime très pure |
FR1496435A (fr) * | 1965-10-16 | 1967-09-29 | Stamicarbon | Procédé de préparation d'oximes |
FR2196996A1 (en) * | 1972-08-25 | 1974-03-22 | Ici Ltd | Ortho-hydroxy phenyl benzyl ketoximes prepn - used as chelating agents, esp for separating copper from other divalent metals |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2579851A (en) * | 1951-12-25 | Method of producing lactams or | ||
US2270204A (en) * | 1938-11-28 | 1942-01-13 | Du Pont | Process of producing oximes |
GB1441174A (en) * | 1972-08-25 | 1976-06-30 | Ici Ltd | Use of hydroxyphenyl ketoximes in extracting metal values from aqueous solutions |
US4018865A (en) * | 1976-03-29 | 1977-04-19 | King Industries, Inc. | Solvent-extraction process for recovery and separation of metal values |
-
1977
- 1977-02-28 US US05/772,559 patent/US4104359A/en not_active Expired - Lifetime
-
1978
- 1978-01-30 CA CA295,900A patent/CA1111825A/fr not_active Expired
- 1978-02-23 JP JP2035378A patent/JPS53113270A/ja active Pending
- 1978-02-23 FR FR7805237A patent/FR2381751A1/fr active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1131203B (de) * | 1954-07-27 | 1962-06-14 | Bayer Ag | Verfahren zur Gewinnung von reinem Acetoxim und von reinen Hydroxylaminsalzen |
FR1312074A (fr) * | 1961-11-15 | 1962-12-14 | Du Pont | Procédé de préparation de cyclohexanone-oxime très pure |
FR1496435A (fr) * | 1965-10-16 | 1967-09-29 | Stamicarbon | Procédé de préparation d'oximes |
FR2196996A1 (en) * | 1972-08-25 | 1974-03-22 | Ici Ltd | Ortho-hydroxy phenyl benzyl ketoximes prepn - used as chelating agents, esp for separating copper from other divalent metals |
Also Published As
Publication number | Publication date |
---|---|
CA1111825A (fr) | 1981-11-03 |
JPS53113270A (en) | 1978-10-03 |
US4104359A (en) | 1978-08-01 |
FR2381751B1 (fr) | 1982-03-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |