FR2378743A1 - Procede pour preparer des polyamines a partir de polynitriles avec un catalyseur d'hydrogenation en pellets - Google Patents
Procede pour preparer des polyamines a partir de polynitriles avec un catalyseur d'hydrogenation en pelletsInfo
- Publication number
- FR2378743A1 FR2378743A1 FR7734552A FR7734552A FR2378743A1 FR 2378743 A1 FR2378743 A1 FR 2378743A1 FR 7734552 A FR7734552 A FR 7734552A FR 7734552 A FR7734552 A FR 7734552A FR 2378743 A1 FR2378743 A1 FR 2378743A1
- Authority
- FR
- France
- Prior art keywords
- hydrogenation catalyst
- polynitrils
- pellet
- preparing polyamines
- polynitriles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 3
- 229920000768 polyamine Polymers 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229920005554 polynitrile Polymers 0.000 abstract 2
- RHRVANRKEISTIR-UHFFFAOYSA-N 3-[2-(2-cyanoethylamino)ethylamino]propanenitrile Chemical compound N#CCCNCCNCCC#N RHRVANRKEISTIR-UHFFFAOYSA-N 0.000 abstract 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000008188 pellet Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyamides (AREA)
Abstract
L'invention concerne un procédé pour préparer des polyamines à partir de polynitriles avec un catalyseur d'hydrogénation en pastilles. On hydrogène des polynitriles en présence d'un catalyseur en pastilles, en présence d'une polyamine ou d'une hydroxylamine ne comportant pas plus de quatre atomes de carbone entre les radicaux amino ou entre les radicaux amino et hydroxy. L'invention s'applique en particulier à l'hydrogénation de la N,N'-bis(cyanoéthyl) éthylènediamine ou d'oxypolynitriles en présence de catalyseurs au cobalt en pastilles dont la désintégration est évitée.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76339477A | 1977-01-28 | 1977-01-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
FR2378743A1 true FR2378743A1 (fr) | 1978-08-25 |
Family
ID=25067735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7734552A Pending FR2378743A1 (fr) | 1977-01-28 | 1977-11-17 | Procede pour preparer des polyamines a partir de polynitriles avec un catalyseur d'hydrogenation en pellets |
Country Status (12)
Country | Link |
---|---|
US (1) | US4146560A (fr) |
JP (1) | JPS5395906A (fr) |
BE (1) | BE863398A (fr) |
BR (1) | BR7707891A (fr) |
CA (1) | CA1105947A (fr) |
DE (1) | DE2755687A1 (fr) |
ES (1) | ES463934A1 (fr) |
FR (1) | FR2378743A1 (fr) |
GB (1) | GB1579599A (fr) |
IT (1) | IT1202381B (fr) |
NL (1) | NL7800165A (fr) |
SE (1) | SE7713967L (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0135725B1 (fr) * | 1983-08-02 | 1989-03-08 | Tosoh Corporation | Procédé de préparation de polyamines |
US4721811A (en) * | 1985-08-26 | 1988-01-26 | W. R. Grace & Co. | Synthesis of aliphatic polyamines |
US4906392A (en) * | 1986-04-18 | 1990-03-06 | The Lubrizol Corporation | Coupled polyamine lubricant additives derived from hydrocarbyl polynitriles and polyamines |
US5039436A (en) * | 1986-04-18 | 1991-08-13 | The Lubrizol Corporation | Coupled polyamine lubricant additives derived from hydrocarbyl polynitriles and polyamines |
EP0372544B1 (fr) * | 1988-12-07 | 1994-07-27 | Kao Corporation | Production d'amines aliphatiques secondaires |
US5362914A (en) * | 1993-08-25 | 1994-11-08 | Texaco Chemical Inc. | Decolorization of polyethylene polyamines using cobalt/copper/chromium |
US7399886B2 (en) * | 2003-09-04 | 2008-07-15 | Garnini Ananda Vedage | Aminopropylation of alcohols in the presence of amide or ether solvents |
JP5377335B2 (ja) * | 2007-03-01 | 2013-12-25 | ビーエーエスエフ ソシエタス・ヨーロピア | テトラエチレンペンタアミンの製造方法 |
US7880036B2 (en) * | 2007-03-01 | 2011-02-01 | Basf Se | Production method for ethyleneamine mixtures |
EP2129651B1 (fr) * | 2007-03-01 | 2013-04-10 | Basf Se | Nouveau procédé de fabrication de teta au moyen de eddn |
ES2390626T3 (es) * | 2007-03-01 | 2012-11-14 | Basf Se | Método de preparación de trietilentetraamina |
CN106631822B (zh) * | 2015-11-04 | 2018-06-12 | 万华化学集团股份有限公司 | 一种n1-(2-氨乙基)-1,2-乙二胺的制备方法 |
TWI565686B (zh) * | 2015-11-26 | 2017-01-11 | 南亞塑膠工業股份有限公司 | 一種n,n’-雙(3-胺基丙基)-1,2-乙二胺的製備方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3384666A (en) * | 1964-12-04 | 1968-05-21 | Jefferson Chem Co Inc | Catalyst pellet stabilization in the continuous preparation of iminobispropyl amines |
FR2248265A1 (en) * | 1973-10-19 | 1975-05-16 | Rhone Poulenc Sa | Biprim. diamines prepd. by hydrogenation of dinitriles - with Raney cobalt and amine, pref. heterocyclic |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3235600A (en) * | 1962-11-28 | 1966-02-15 | Monsanto Co | Reduction of diaminocyclohexane concentration in crude hexamethylenedi-amine |
US3673251A (en) * | 1969-04-30 | 1972-06-27 | Nat Distillers Chem Corp | Process for the catalytic reductive amination of nitriles |
GB1377192A (en) * | 1971-06-04 | 1974-12-11 | Ici Ltd | Hydrogenation process for the preparation of aliphatic diamines |
DE2312591C3 (de) * | 1973-03-14 | 1982-05-06 | Basf Ag, 6700 Ludwigshafen | Herstellung von Hexamethylendiamin |
-
1977
- 1977-10-07 GB GB41739/77A patent/GB1579599A/en not_active Expired
- 1977-11-07 ES ES463934A patent/ES463934A1/es not_active Expired
- 1977-11-17 FR FR7734552A patent/FR2378743A1/fr active Pending
- 1977-11-22 IT IT29922/77A patent/IT1202381B/it active
- 1977-11-28 US US05/855,516 patent/US4146560A/en not_active Expired - Lifetime
- 1977-11-28 BR BR7707891A patent/BR7707891A/pt unknown
- 1977-12-08 SE SE7713967A patent/SE7713967L/ not_active Application Discontinuation
- 1977-12-14 DE DE19772755687 patent/DE2755687A1/de not_active Ceased
-
1978
- 1978-01-06 NL NL7800165A patent/NL7800165A/xx not_active Application Discontinuation
- 1978-01-26 JP JP678878A patent/JPS5395906A/ja active Granted
- 1978-01-27 BE BE184692A patent/BE863398A/fr unknown
- 1978-01-30 CA CA295,865A patent/CA1105947A/fr not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3384666A (en) * | 1964-12-04 | 1968-05-21 | Jefferson Chem Co Inc | Catalyst pellet stabilization in the continuous preparation of iminobispropyl amines |
FR2248265A1 (en) * | 1973-10-19 | 1975-05-16 | Rhone Poulenc Sa | Biprim. diamines prepd. by hydrogenation of dinitriles - with Raney cobalt and amine, pref. heterocyclic |
Also Published As
Publication number | Publication date |
---|---|
BE863398A (fr) | 1978-07-27 |
ES463934A1 (es) | 1978-07-01 |
DE2755687A1 (de) | 1978-08-03 |
NL7800165A (nl) | 1978-08-01 |
CA1105947A (fr) | 1981-07-28 |
IT1202381B (it) | 1989-02-09 |
SE7713967L (sv) | 1978-07-29 |
US4146560A (en) | 1979-03-27 |
BR7707891A (pt) | 1978-08-29 |
JPS5395906A (en) | 1978-08-22 |
JPS5735899B2 (fr) | 1982-07-31 |
GB1579599A (en) | 1980-11-19 |
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