FR2377426A1 - AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING - Google Patents

AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING

Info

Publication number
FR2377426A1
FR2377426A1 FR7701015A FR7701015A FR2377426A1 FR 2377426 A1 FR2377426 A1 FR 2377426A1 FR 7701015 A FR7701015 A FR 7701015A FR 7701015 A FR7701015 A FR 7701015A FR 2377426 A1 FR2377426 A1 FR 2377426A1
Authority
FR
France
Prior art keywords
weight
dispersions
acid
esters
monomers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7701015A
Other languages
French (fr)
Other versions
FR2377426B1 (en
Inventor
Rene Decamp
Jean-Claude Leveque
Jacques Paillier
Jean Perronin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Priority to FR7701015A priority Critical patent/FR2377426A1/en
Priority to DK587677A priority patent/DK587677A/en
Priority to DE19782801099 priority patent/DE2801099A1/en
Priority to GB1151/78A priority patent/GB1560870A/en
Priority to NL7800357A priority patent/NL7800357A/en
Priority to IT67051/78A priority patent/IT1106967B/en
Priority to BE184257A priority patent/BE862842A/en
Priority to ES465979A priority patent/ES465979A1/en
Publication of FR2377426A1 publication Critical patent/FR2377426A1/en
Application granted granted Critical
Publication of FR2377426B1 publication Critical patent/FR2377426B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols

Abstract

L'invention a pour objet de nouvelles dispersions aqueuses de copolymères solubilisables. Ces dispersions de pH compris entre 2 et 7 contiennent un copolymère dont la température de transition vitreuse est comprise entre - 60 et + 140 degrés C et la valeur K entre 20 et 130, ledit copolymère contenant sous forme interpolymérisée: a. 0,75 a 5,75 % en poids d'un ou plusieurs monomères choisis parmi l'acide acrylique, l'acide méthacrylique, l'acide crotonique, l'acide itaconique, l'anhydride maléïque et les hémi-esters de l'acide maléïque; b. 50 à 99,25 % en poids d'un ou plusieurs monomères choisis parmi les esters de l'acide acrylique ou méthacrylique. avec un alcool contenant 1 à 18 atomes de carbone et les esters vinyliques d'acides carboxyliques comportant 1 à 18 atomes de carbone ou d'acides minéraux ; c. 0 à 49,25 % en poids d'un ou plusieurs monomères monoéthyléniques autres que les esters précités, formant des homopolymères insolubles dans l'eau; et d. 0 à 5 % en poids d'un ou plusieurs monomères monoéthyléniques portant au moins un groupe polaire, les dispersions ayant un taux de matières sèches compris entre 20 et 50 %. Ces dispersions solubilisables par addition d'un agent alcalin peuvent être utilisées pour l'impression ou l'enduction de divers substrats.The subject of the invention is novel aqueous dispersions of soluble copolymers. These dispersions with a pH of between 2 and 7 contain a copolymer whose glass transition temperature is between - 60 and + 140 degrees C and the K value between 20 and 130, said copolymer containing in interpolymerized form: a. 0.75 to 5.75% by weight of one or more monomers selected from acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic anhydride and half-esters of maleic acid; b. 50 to 99.25% by weight of one or more monomers chosen from esters of acrylic or methacrylic acid. with an alcohol containing 1 to 18 carbon atoms and vinyl esters of carboxylic acids having 1 to 18 carbon atoms or of mineral acids; vs. 0 to 49.25% by weight of one or more monoethylenic monomers other than the above esters, forming homopolymers insoluble in water; and D. 0 to 5% by weight of one or more monoethylenic monomers bearing at least one polar group, the dispersions having a solids content of between 20 and 50%. These dispersions which can be solubilized by the addition of an alkaline agent can be used for printing or coating various substrates.

FR7701015A 1977-01-14 1977-01-14 AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING Granted FR2377426A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR7701015A FR2377426A1 (en) 1977-01-14 1977-01-14 AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING
DK587677A DK587677A (en) 1977-01-14 1977-12-30 WATER DISPERSIONS OF COPOLYMERS THAT CAN BE DISSOLVED FOR PRINTING AND COATING
DE19782801099 DE2801099A1 (en) 1977-01-14 1978-01-11 Aqueous DISPERSIONS OF SOLUBLE COPOLYMERIZED FOR PRINTING AND COATING PURPOSES
NL7800357A NL7800357A (en) 1977-01-14 1978-01-12 PROCEDURE FOR PREPARING A WATERY DISPERSION OF A COPOLYMER.
GB1151/78A GB1560870A (en) 1977-01-14 1978-01-12 Aqueous dispersions of copolymers
IT67051/78A IT1106967B (en) 1977-01-14 1978-01-12 WATER DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR MOLDING AND INDUCTION
BE184257A BE862842A (en) 1977-01-14 1978-01-12 AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING
ES465979A ES465979A1 (en) 1977-01-14 1978-01-13 Aqueous dispersions of copolymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7701015A FR2377426A1 (en) 1977-01-14 1977-01-14 AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING

Publications (2)

Publication Number Publication Date
FR2377426A1 true FR2377426A1 (en) 1978-08-11
FR2377426B1 FR2377426B1 (en) 1980-04-18

Family

ID=9185496

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7701015A Granted FR2377426A1 (en) 1977-01-14 1977-01-14 AQUEOUS DISPERSIONS OF SOLUBILIZABLE COPOLYMERS FOR PRINTING AND COATING

Country Status (8)

Country Link
BE (1) BE862842A (en)
DE (1) DE2801099A1 (en)
DK (1) DK587677A (en)
ES (1) ES465979A1 (en)
FR (1) FR2377426A1 (en)
GB (1) GB1560870A (en)
IT (1) IT1106967B (en)
NL (1) NL7800357A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0216210A1 (en) * 1985-09-04 1987-04-01 Wacker-Chemie GmbH Thermally resistant contact adhesive
EP0302521A2 (en) * 1987-08-06 1989-02-08 Air Products And Chemicals, Inc. Nonwoven binder emulsions of vinyl acetate/ethylene copolymers having improved solvent resistance
WO1993003103A1 (en) * 1991-08-09 1993-02-18 Minnesota Mining And Manufacturing Company Water-based chemical compositions
EP0630919A1 (en) * 1993-05-21 1994-12-28 BASF Aktiengesellschaft Aqueous polymer dispersions
EP0630920A1 (en) * 1993-05-21 1994-12-28 BASF Aktiengesellschaft Powdery polymer

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3101892A1 (en) * 1981-01-22 1982-08-26 Röhm GmbH, 6100 Darmstadt METHOD FOR PRODUCING AQUEOUS PLASTIC DISPERSIONS WITH A HIGH PIGMENT BINDING CAPACITY
DE3147007C2 (en) * 1981-11-27 1983-10-06 Roehm Gmbh, 6100 Darmstadt Self-crosslinking aqueous plastic dispersion
DE4122990C2 (en) * 1991-07-11 1994-04-28 Huber Fa Michael Muenchen Water-thinnable bronze or effect printing ink, its use and method for producing a bronze or effect printing
DE4227974C2 (en) * 1992-08-26 1996-04-18 Stockhausen Chem Fab Gmbh Copolymers containing alkoxy groups, processes for their preparation and their use for retanning leather
CA2186831A1 (en) * 1995-10-06 1997-04-07 Carl Michael Hesler Ink composition and method for preparing
US6160059A (en) 1996-07-26 2000-12-12 Cook Composites And Polymers Co. Bulk polymerization process for preparing solid acrylic resin
CA2307665A1 (en) 1997-10-31 1999-05-14 Cognis Corporation Continuous bulk polymerization process
JP4690006B2 (en) * 2004-10-06 2011-06-01 理想科学工業株式会社 Water-based ink for stencil printing and stencil printing method
CN114316117B (en) * 2020-09-30 2023-09-26 四川赛华睿科技有限责任公司 Fluorine-free treating agent and oil-proof paper product

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0216210A1 (en) * 1985-09-04 1987-04-01 Wacker-Chemie GmbH Thermally resistant contact adhesive
EP0302521A2 (en) * 1987-08-06 1989-02-08 Air Products And Chemicals, Inc. Nonwoven binder emulsions of vinyl acetate/ethylene copolymers having improved solvent resistance
EP0302521A3 (en) * 1987-08-06 1989-09-20 Air Products And Chemicals, Inc. Nonwoven binder emulsions of vinyl acetate/ethylene copolymers having improved solvent resistance
WO1993003103A1 (en) * 1991-08-09 1993-02-18 Minnesota Mining And Manufacturing Company Water-based chemical compositions
US5462768A (en) * 1991-08-09 1995-10-31 Minnesota Mining And Manufacturing Company Screen printing process using water-based chemical composition
EP0630919A1 (en) * 1993-05-21 1994-12-28 BASF Aktiengesellschaft Aqueous polymer dispersions
EP0630920A1 (en) * 1993-05-21 1994-12-28 BASF Aktiengesellschaft Powdery polymer
US5512629A (en) * 1993-05-21 1996-04-30 Basf Aktiengesellschaft Aqueous polymer dispersions

Also Published As

Publication number Publication date
IT1106967B (en) 1985-11-18
DE2801099A1 (en) 1978-07-20
IT7867051A0 (en) 1978-01-12
ES465979A1 (en) 1979-05-16
FR2377426B1 (en) 1980-04-18
NL7800357A (en) 1978-07-18
DK587677A (en) 1978-07-15
GB1560870A (en) 1980-02-13
BE862842A (en) 1978-07-12

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