FR2376109A1 - Purifying crude di:phenol monomers by recrystallisation - from water contg. hydroxylic co-solvent, e.g. ethylene glycol (NL 4.7.78) - Google Patents

Purifying crude di:phenol monomers by recrystallisation - from water contg. hydroxylic co-solvent, e.g. ethylene glycol (NL 4.7.78)

Info

Publication number
FR2376109A1
FR2376109A1 FR7739515A FR7739515A FR2376109A1 FR 2376109 A1 FR2376109 A1 FR 2376109A1 FR 7739515 A FR7739515 A FR 7739515A FR 7739515 A FR7739515 A FR 7739515A FR 2376109 A1 FR2376109 A1 FR 2376109A1
Authority
FR
France
Prior art keywords
water
alcohols
ethylene glycol
solvent
hydroxylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7739515A
Other languages
French (fr)
Inventor
Victor Mark
Charles Vernon Hedge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of FR2376109A1 publication Critical patent/FR2376109A1/en
Priority to US06/041,642 priority Critical patent/US4242527A/en
Priority to US06/156,953 priority patent/US4320234A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/26—Separation; Purification; Stabilisation; Use of additives
    • C07C319/28—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/06—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
    • C07C37/84—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Crude diphenols (I) are purified by warming a slurry with a mixt. of water and >=1 water-soluble, alcoholic or phenolic cosolvent (II), until (I) has completely dissolved (or nearly so), to the b. pt. (or near the b. pt.) of water or the solvent system. The soln. is then cooled to cause sepn. of purified (I) which is recovered. (II) are pref. mono-, di- or tri-valent alcohols, ether alcohols, amino-alcohols, keto-alcohols or phenols, specifically (m)ethanol, 1,2-propylene glycol or ethylene glycol. (I) is esp. bisphenol A (Ia). (I) are monomers. This method avoids the use of expensive solvents such as benzene or CH2Cl2, or separate solvent recovery stages.
FR7739515A 1976-12-30 1977-12-28 Purifying crude di:phenol monomers by recrystallisation - from water contg. hydroxylic co-solvent, e.g. ethylene glycol (NL 4.7.78) Withdrawn FR2376109A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US06/041,642 US4242527A (en) 1977-12-28 1979-05-23 Process for purifying crude diphenols
US06/156,953 US4320234A (en) 1977-12-28 1980-06-06 Process for purifying crude diphenols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US75598276A 1976-12-30 1976-12-30

Publications (1)

Publication Number Publication Date
FR2376109A1 true FR2376109A1 (en) 1978-07-28

Family

ID=25041513

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7739515A Withdrawn FR2376109A1 (en) 1976-12-30 1977-12-28 Purifying crude di:phenol monomers by recrystallisation - from water contg. hydroxylic co-solvent, e.g. ethylene glycol (NL 4.7.78)

Country Status (4)

Country Link
JP (1) JPS53101347A (en)
DE (1) DE2758565A1 (en)
FR (1) FR2376109A1 (en)
NL (1) NL7714564A (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300000A (en) 1977-12-28 1981-11-10 General Electric Company Process for the recovery of 2,2-bis(4-hydroxyphenyl)propane
JPS5639030A (en) * 1979-09-07 1981-04-14 Sumitomo Chem Co Ltd Purification of p,p'-biphenols
US4414422A (en) * 1982-05-10 1983-11-08 The Dow Chemical Company Purification of 4,4-dihydroxybiphenyl
JPS62138443A (en) * 1985-12-11 1987-06-22 Mitsui Toatsu Chem Inc Production of biscresol
US4950806A (en) * 1988-02-22 1990-08-21 Mitsui Toatsu Chemicals, Inc. Process for crystallizing adduct of bisphenol A with phenol
DE3900680C1 (en) * 1989-01-12 1989-11-09 Bayer Ag, 5090 Leverkusen, De
US4992598A (en) * 1990-02-09 1991-02-12 Hoechst Celanese Corporation Purification of 1, 1, 1-tris(4'-hydroxyphenyl)ethane

Also Published As

Publication number Publication date
JPS53101347A (en) 1978-09-04
NL7714564A (en) 1978-07-04
DE2758565A1 (en) 1978-07-06

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Legal Events

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