FR2372132A1 - Catalyseur destine a la reduction de l'oxyde de carbone co a l'aide d'hydrogene - Google Patents

Catalyseur destine a la reduction de l'oxyde de carbone co a l'aide d'hydrogene

Info

Publication number
FR2372132A1
FR2372132A1 FR7735590A FR7735590A FR2372132A1 FR 2372132 A1 FR2372132 A1 FR 2372132A1 FR 7735590 A FR7735590 A FR 7735590A FR 7735590 A FR7735590 A FR 7735590A FR 2372132 A1 FR2372132 A1 FR 2372132A1
Authority
FR
France
Prior art keywords
catalyst
reduction
hydrogen
carbon oxide
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7735590A
Other languages
English (en)
Other versions
FR2372132B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of FR2372132A1 publication Critical patent/FR2372132A1/fr
Application granted granted Critical
Publication of FR2372132B1 publication Critical patent/FR2372132B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/24—Nitrogen compounds
    • C07C2527/26—Cyanides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un catalyseur destiné à la réduction de l'oxyde de carbone CO avec formation de mélanges d'hydrocarbures essentiellement en C1 -C4 . Le catalyseur est caractérisé en ce qu'il est préparé par précipitation de sels d'acides cyanohydriques de formule genérale MeI MeII (CN) x , séparation et séchage des sels précipités et ensuite activation. Bonne sélectivité de ce catalyseur.
FR7735590A 1976-11-27 1977-11-25 Catalyseur destine a la reduction de l'oxyde de carbone co a l'aide d'hydrogene Granted FR2372132A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762653985 DE2653985A1 (de) 1976-11-27 1976-11-27 Katalysator zur reduktion von kohlenmonoxid mit wasserstoff

Publications (2)

Publication Number Publication Date
FR2372132A1 true FR2372132A1 (fr) 1978-06-23
FR2372132B1 FR2372132B1 (fr) 1983-06-03

Family

ID=5994150

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7735590A Granted FR2372132A1 (fr) 1976-11-27 1977-11-25 Catalyseur destine a la reduction de l'oxyde de carbone co a l'aide d'hydrogene

Country Status (13)

Country Link
US (1) US4186112A (fr)
JP (1) JPS5367688A (fr)
BE (1) BE861198A (fr)
CA (1) CA1096847A (fr)
CS (1) CS213333B2 (fr)
DE (1) DE2653985A1 (fr)
FR (1) FR2372132A1 (fr)
GB (1) GB1554082A (fr)
IT (1) IT1090587B (fr)
NL (1) NL7712509A (fr)
PL (1) PL109758B1 (fr)
SU (1) SU884555A3 (fr)
ZA (1) ZA777012B (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4394298A (en) * 1980-01-10 1983-07-19 Phillips Petroleum Company Hydrogenation catalyst
US4604375A (en) * 1983-12-20 1986-08-05 Exxon Research And Engineering Co. Manganese-spinel catalysts in CO/H2 olefin synthesis
US4618597A (en) * 1983-12-20 1986-10-21 Exxon Research And Engineering Company High surface area dual promoted iron/managanese spinel compositions
US4670476A (en) * 1983-12-20 1987-06-02 Exxon Research And Engineering Company Manganese-spinel catalysts in CO/H2 olefin synthesis
US4588705A (en) * 1984-08-10 1986-05-13 Exxon Research And Engineering Co. Method for preparing dual colloid compositions
CA1250565A (fr) * 1984-08-10 1989-02-28 Michael A. Richard Methode de preparation de compositions catalytiques colloidales doubles
US4639431A (en) * 1985-07-11 1987-01-27 Exxon Research And Engineering Company Catalysts in Fischer-Tropsch process for producing olefins
US4657885A (en) * 1985-07-11 1987-04-14 Exxon Research And Engineering Company Cerium promoted Fischer-Tropsch catalysts
US4613722A (en) * 1985-07-25 1986-09-23 Phillips Petroleum Company Dehydrogenation of C3 and C4 hydrocarbons over an iron-based catalyst
US5504118A (en) * 1986-05-08 1996-04-02 Rentech, Inc. Process for the production of hydrocarbons
US4876402A (en) * 1986-11-03 1989-10-24 Union Carbide Chemicals And Plastics Company Inc. Improved aldehyde hydrogenation process
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
US5032570A (en) * 1987-08-04 1991-07-16 Hitachi Metals, Ltd. Method for producing ceramic superconducting material using intermediate products
US5198592A (en) * 1987-12-11 1993-03-30 Engelhard De Meern B.V. Hydrogenolysis reaction and catalyst suitable therefor
GB9005964D0 (en) * 1990-03-16 1990-05-09 Shell Int Research Catalyst preparation process
GB9015193D0 (en) * 1990-07-10 1990-08-29 Shell Int Research Catalysts and catalysts precursors suitable for hydrocarbon synthesis
US20020019309A1 (en) * 1999-10-15 2002-02-14 Lapidus Albert L?Apos;Vovich Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions
JP4773116B2 (ja) * 2005-03-24 2011-09-14 新日本製鐵株式会社 合成ガスから炭化水素を製造する触媒の製造方法、並びに当該触媒を用いた合成ガスから炭化水素を製造する方法
JP6948057B2 (ja) * 2017-08-30 2021-10-13 公立大学法人大阪 有機リン化合物分解触媒
WO2020176210A1 (fr) * 2019-02-28 2020-09-03 Exxonmobil Chemical Patents Inc. Compositions et précurseurs de catalyseur, leurs procédés de fabrication et procédés de conversion de gaz de synthèse

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1011662A (fr) * 1949-02-26 1952-06-25 Ruhrchemie Ag Procédé pour l'obtention de produits d'hydrogénation de l'oxyde de carbone avec une teneur élevée en combinaisons oxygénées
FR2251371A1 (fr) * 1973-11-20 1975-06-13 Basf Ag
FR2327818A1 (fr) * 1975-10-17 1977-05-13 Hoechst Ag Catalyseur et procede de reduction de l'oxyde de carbone

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE729290C (de) * 1936-02-26 1942-12-15 Ig Farbenindustrie Ag Verfahren zur Umsetzung von Kohlenoxyd und Wasserstoff
US2234246A (en) * 1937-12-09 1941-03-11 Celanese Corp Metallic composition
US2767202A (en) * 1952-01-30 1956-10-16 Ruhrchemie Ag Catalytic hydrogenation of carbon monoxides
US2753367A (en) * 1952-07-09 1956-07-03 Ruhrchemie Ag Catalytic hydrogenation of carbon monoxide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1011662A (fr) * 1949-02-26 1952-06-25 Ruhrchemie Ag Procédé pour l'obtention de produits d'hydrogénation de l'oxyde de carbone avec une teneur élevée en combinaisons oxygénées
FR2251371A1 (fr) * 1973-11-20 1975-06-13 Basf Ag
FR2327818A1 (fr) * 1975-10-17 1977-05-13 Hoechst Ag Catalyseur et procede de reduction de l'oxyde de carbone

Also Published As

Publication number Publication date
NL7712509A (nl) 1978-05-30
US4186112A (en) 1980-01-29
DE2653985A1 (de) 1978-06-01
CS213333B2 (en) 1982-04-09
PL109758B1 (en) 1980-06-30
ZA777012B (en) 1978-10-25
FR2372132B1 (fr) 1983-06-03
SU884555A3 (ru) 1981-11-23
IT1090587B (it) 1985-06-26
PL202450A1 (pl) 1978-07-17
CA1096847A (fr) 1981-03-03
BE861198A (fr) 1978-05-25
JPS5367688A (en) 1978-06-16
GB1554082A (en) 1979-10-17

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