FR2361411A1 - Procede de preparation d'alkylphosphines - Google Patents
Procede de preparation d'alkylphosphinesInfo
- Publication number
- FR2361411A1 FR2361411A1 FR7724961A FR7724961A FR2361411A1 FR 2361411 A1 FR2361411 A1 FR 2361411A1 FR 7724961 A FR7724961 A FR 7724961A FR 7724961 A FR7724961 A FR 7724961A FR 2361411 A1 FR2361411 A1 FR 2361411A1
- Authority
- FR
- France
- Prior art keywords
- alkylphosphines
- following general
- preparation
- general formula
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- 150000003973 alkyl amines Chemical class 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- 150000003003 phosphines Chemical group 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5004—Acyclic saturated phosphines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
L'invention concerne un procédé de préparation d'alkylphosphines de formule générale suivante : Rn PH3-n (1) Selon l'invention, on fait réagir de l'hydrogène phosphoré, des phosphines primaires ou secondaires avec des alkylamines de formule générale suivante : Rn NH3- n (II) dans des rapports molaires de 0,1 à 10 moles d'alkylamine de formule II par mole d'hydrogène phosphoré ou de phosphine, à 150-400 degrés C sous une pression allant de la pression normale à 1 atmosphère relative. On effectue la réaction en présence de catalyseurs et on fait passer les matières de départ dans une zone de réaction à une vitesse assurant une durée de contact de 0,1 à 400 s entre ces dernières et le catalyseur.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2636558A DE2636558C3 (de) | 1976-08-13 | 1976-08-13 | Verfahren zur Herstellung von Alkylphosphinen |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2361411A1 true FR2361411A1 (fr) | 1978-03-10 |
FR2361411B1 FR2361411B1 (fr) | 1984-05-25 |
Family
ID=5985410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7724961A Granted FR2361411A1 (fr) | 1976-08-13 | 1977-08-12 | Procede de preparation d'alkylphosphines |
Country Status (9)
Country | Link |
---|---|
US (1) | US4156697A (fr) |
BE (1) | BE857738A (fr) |
CA (1) | CA1073926A (fr) |
CH (1) | CH632276A5 (fr) |
DE (1) | DE2636558C3 (fr) |
FR (1) | FR2361411A1 (fr) |
GB (1) | GB1544759A (fr) |
IT (1) | IT1079913B (fr) |
NL (1) | NL7707058A (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3822777A1 (de) * | 1988-07-06 | 1990-01-11 | Hoechst Ag | Verfahren zur entfernung von phosphorwasserstoff aus abluft |
JP2000109491A (ja) * | 1998-10-02 | 2000-04-18 | Kankyo Kagaku Center:Kk | 第二級ホスフィンの製造法 |
CN111995641B (zh) * | 2020-08-28 | 2022-11-01 | 苏州求索生物科技有限公司 | 一种烷基膦的生产方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855311A (en) * | 1972-11-11 | 1974-12-17 | Hoechst Ag | Production of dialkylphosphines |
DE2407461A1 (de) * | 1974-02-16 | 1975-08-28 | Hoechst Ag | Verfahren zur herstellung von organophosphinen |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2437797A (en) * | 1944-07-13 | 1948-03-16 | Du Pont | New metal salts of organic phosphines and processes of making the same |
US3153670A (en) * | 1962-03-16 | 1964-10-20 | Monsanto Co | Vinyl amines |
US3253036A (en) * | 1962-03-21 | 1966-05-24 | Allied Chem | Alkylation of amines with alkyl phosphites |
US3340333A (en) * | 1963-07-01 | 1967-09-05 | Hooker Chemical Corp | Preparation of phosphorus compounds containing a phosphoryl group |
US3366687A (en) * | 1964-06-11 | 1968-01-30 | Gulf Research Development Co | Process for preparing primary and secondary amines |
DE2116439B2 (de) * | 1971-04-03 | 1979-05-31 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Trialkylphosphinen |
-
1976
- 1976-08-13 DE DE2636558A patent/DE2636558C3/de not_active Expired
-
1977
- 1977-06-24 NL NL7707058A patent/NL7707058A/xx not_active Application Discontinuation
- 1977-08-04 IT IT50561/77A patent/IT1079913B/it active
- 1977-08-09 US US05/823,140 patent/US4156697A/en not_active Expired - Lifetime
- 1977-08-09 CH CH977077A patent/CH632276A5/de not_active IP Right Cessation
- 1977-08-09 CA CA284,345A patent/CA1073926A/fr not_active Expired
- 1977-08-12 FR FR7724961A patent/FR2361411A1/fr active Granted
- 1977-08-12 GB GB33937/77A patent/GB1544759A/en not_active Expired
- 1977-08-12 BE BE180123A patent/BE857738A/fr not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855311A (en) * | 1972-11-11 | 1974-12-17 | Hoechst Ag | Production of dialkylphosphines |
DE2407461A1 (de) * | 1974-02-16 | 1975-08-28 | Hoechst Ag | Verfahren zur herstellung von organophosphinen |
Also Published As
Publication number | Publication date |
---|---|
NL7707058A (nl) | 1978-02-15 |
DE2636558A1 (de) | 1978-02-16 |
BE857738A (fr) | 1978-02-13 |
DE2636558C3 (de) | 1979-05-17 |
GB1544759A (en) | 1979-04-25 |
CH632276A5 (de) | 1982-09-30 |
DE2636558B2 (de) | 1978-09-14 |
US4156697A (en) | 1979-05-29 |
FR2361411B1 (fr) | 1984-05-25 |
CA1073926A (fr) | 1980-03-18 |
IT1079913B (it) | 1985-05-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |