FR2361411A1 - Procede de preparation d'alkylphosphines - Google Patents

Procede de preparation d'alkylphosphines

Info

Publication number
FR2361411A1
FR2361411A1 FR7724961A FR7724961A FR2361411A1 FR 2361411 A1 FR2361411 A1 FR 2361411A1 FR 7724961 A FR7724961 A FR 7724961A FR 7724961 A FR7724961 A FR 7724961A FR 2361411 A1 FR2361411 A1 FR 2361411A1
Authority
FR
France
Prior art keywords
alkylphosphines
following general
preparation
general formula
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7724961A
Other languages
English (en)
Other versions
FR2361411B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of FR2361411A1 publication Critical patent/FR2361411A1/fr
Application granted granted Critical
Publication of FR2361411B1 publication Critical patent/FR2361411B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/5004Acyclic saturated phosphines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé de préparation d'alkylphosphines de formule générale suivante : Rn PH3-n (1) Selon l'invention, on fait réagir de l'hydrogène phosphoré, des phosphines primaires ou secondaires avec des alkylamines de formule générale suivante : Rn NH3- n (II) dans des rapports molaires de 0,1 à 10 moles d'alkylamine de formule II par mole d'hydrogène phosphoré ou de phosphine, à 150-400 degrés C sous une pression allant de la pression normale à 1 atmosphère relative. On effectue la réaction en présence de catalyseurs et on fait passer les matières de départ dans une zone de réaction à une vitesse assurant une durée de contact de 0,1 à 400 s entre ces dernières et le catalyseur.
FR7724961A 1976-08-13 1977-08-12 Procede de preparation d'alkylphosphines Granted FR2361411A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2636558A DE2636558C3 (de) 1976-08-13 1976-08-13 Verfahren zur Herstellung von Alkylphosphinen

Publications (2)

Publication Number Publication Date
FR2361411A1 true FR2361411A1 (fr) 1978-03-10
FR2361411B1 FR2361411B1 (fr) 1984-05-25

Family

ID=5985410

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7724961A Granted FR2361411A1 (fr) 1976-08-13 1977-08-12 Procede de preparation d'alkylphosphines

Country Status (9)

Country Link
US (1) US4156697A (fr)
BE (1) BE857738A (fr)
CA (1) CA1073926A (fr)
CH (1) CH632276A5 (fr)
DE (1) DE2636558C3 (fr)
FR (1) FR2361411A1 (fr)
GB (1) GB1544759A (fr)
IT (1) IT1079913B (fr)
NL (1) NL7707058A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3822777A1 (de) * 1988-07-06 1990-01-11 Hoechst Ag Verfahren zur entfernung von phosphorwasserstoff aus abluft
JP2000109491A (ja) * 1998-10-02 2000-04-18 Kankyo Kagaku Center:Kk 第二級ホスフィンの製造法
CN111995641B (zh) * 2020-08-28 2022-11-01 苏州求索生物科技有限公司 一种烷基膦的生产方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855311A (en) * 1972-11-11 1974-12-17 Hoechst Ag Production of dialkylphosphines
DE2407461A1 (de) * 1974-02-16 1975-08-28 Hoechst Ag Verfahren zur herstellung von organophosphinen

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2437797A (en) * 1944-07-13 1948-03-16 Du Pont New metal salts of organic phosphines and processes of making the same
US3153670A (en) * 1962-03-16 1964-10-20 Monsanto Co Vinyl amines
US3253036A (en) * 1962-03-21 1966-05-24 Allied Chem Alkylation of amines with alkyl phosphites
US3340333A (en) * 1963-07-01 1967-09-05 Hooker Chemical Corp Preparation of phosphorus compounds containing a phosphoryl group
US3366687A (en) * 1964-06-11 1968-01-30 Gulf Research Development Co Process for preparing primary and secondary amines
DE2116439B2 (de) * 1971-04-03 1979-05-31 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Trialkylphosphinen

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855311A (en) * 1972-11-11 1974-12-17 Hoechst Ag Production of dialkylphosphines
DE2407461A1 (de) * 1974-02-16 1975-08-28 Hoechst Ag Verfahren zur herstellung von organophosphinen

Also Published As

Publication number Publication date
NL7707058A (nl) 1978-02-15
DE2636558A1 (de) 1978-02-16
BE857738A (fr) 1978-02-13
DE2636558C3 (de) 1979-05-17
GB1544759A (en) 1979-04-25
CH632276A5 (de) 1982-09-30
DE2636558B2 (de) 1978-09-14
US4156697A (en) 1979-05-29
FR2361411B1 (fr) 1984-05-25
CA1073926A (fr) 1980-03-18
IT1079913B (it) 1985-05-13

Similar Documents

Publication Publication Date Title
RO83836B (ro) Procedeu pentru obtinerea unor compusi cu grupe izocianurice
FR2353578A1 (fr) Procede de preparation de mousses de polyurethannes avec utilisation, comme catalyseurs, de polyamines ramifiees contenant au moins 4 atomes d'azote tertiaires
BE881765A (fr) Procede d'isolement de methyltertiobutylether a partir des produits de la reaction du methanol avec une coupe d'hydrocarbures c4 renfermant de l'isobutene
FR2375187A1 (fr) Cyclopentane-1-amines, procede pour leur preparation et produits contenant ces composes
RO91880A (fr) Procede de preparation des aldehydes
FR2400021A1 (fr) Preparation d'acide (1r,cis);caronaldehydique
FR2361411A1 (fr) Procede de preparation d'alkylphosphines
FR2376836A1 (fr) Procede de preparation du 2,5-dichlorophenol
CA2008014A1 (fr) Methode et catalyseur pour la preparation de derives de 2,2,'-bipyridyles
ES8107203A1 (es) Procedimiento para la preparacion de (2,2')-disulfuros de ditiazolilo
FR2361480A1 (fr) Procede de preparation de carotenoides symetriques
FR2358415A1 (fr) Derives peptidiques, leur preparation et leur application en tant que medicaments
FR2381733A1 (fr) Procede de preparation de m-bromo-a,a,a-trifluorotoluenes
MX9603655A (es) Procedimiento para la preparacion de pentenaleno.
FR2359154A1 (fr) Derives peptidiques utiles comme medicaments et procede pour leur preparation
MX166037B (es) Procedimiento de sintesis de alquilarsinas o alquilarsinas sustituidas
EP0299720A3 (en) Process for the condensation of alcohols
FR2397387A1 (fr) 4,4'-bis-formyl-polyhalo-diphenoxyalcanes, procede de preparation et application a la synthese de 4,4'-dicyano-polyhalo-diphenoxyalcanes
CA2099791A1 (fr) Methode pour la preparation de composes de type 1-aza-2-silacyclopentane
AU2335895A (en) Improved processes and catalysts for the preparation of 2,2'-bipyridyls
IE44659L (en) Method of preparing 2, 6-ditert. butylphenol
FR2363557A1 (fr) Procede de preparation de 2,3-cycloalcenopyridines
FR2382934A1 (fr) Catalyseurs pour la polymerisation d'olefines
FR2443447A1 (fr) Procede de preparation d'hydrocarbures
FR2354988A1 (fr) Procede de preparation de bisphenols ou de polyphenols a empechements steriques

Legal Events

Date Code Title Description
ST Notification of lapse