FR2338236A1 - Continuous alkylation of isobutane with olefin - using part of prod. as coolant in place of water - Google Patents

Continuous alkylation of isobutane with olefin - using part of prod. as coolant in place of water

Info

Publication number
FR2338236A1
FR2338236A1 FR7701295A FR7701295A FR2338236A1 FR 2338236 A1 FR2338236 A1 FR 2338236A1 FR 7701295 A FR7701295 A FR 7701295A FR 7701295 A FR7701295 A FR 7701295A FR 2338236 A1 FR2338236 A1 FR 2338236A1
Authority
FR
France
Prior art keywords
isobutane
olefin
effluent
prod
coolant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7701295A
Other languages
French (fr)
Other versions
FR2338236B1 (en
Inventor
Richard Howard Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/742,949 external-priority patent/US4130593A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of FR2338236A1 publication Critical patent/FR2338236A1/en
Application granted granted Critical
Publication of FR2338236B1 publication Critical patent/FR2338236B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56Addition to acyclic hydrocarbons
    • C07C2/58Catalytic processes
    • C07C2/62Catalytic processes with acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054Sulfuric acid or other acids with the formula H2Sn03n+1
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/08Halides
    • C07C2527/12Fluorides
    • C07C2527/1206Hydrogen fluoride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

In the continuous alkylation of isobutane by an olefin, (a) the olefin is reacted with a molar excess of isobutane in presence of an acid, to give a liq. effluent; (b) the effluent is removed from the alkylation zone, and (c) (part of) the effluent is vapourised, to give vapours which are condensed by cooling in indirect heat-exchange with the effluent. The amt. of isobutane which has to be treated and recovered in the distn. column is greatly reduced. Cooling water is not needed for the head condenser of the distn. column. The columns operate at lower temp. than in prior art.
FR7701295A 1976-01-19 1977-01-18 Continuous alkylation of isobutane with olefin - using part of prod. as coolant in place of water Granted FR2338236A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US65034176A 1976-01-19 1976-01-19
US05/742,949 US4130593A (en) 1976-01-19 1976-11-18 Alkylation process utilizing the hydrocarbon phase from a reactor for condensing a vaporous distillation effluent

Publications (2)

Publication Number Publication Date
FR2338236A1 true FR2338236A1 (en) 1977-08-12
FR2338236B1 FR2338236B1 (en) 1981-11-20

Family

ID=27095834

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7701295A Granted FR2338236A1 (en) 1976-01-19 1977-01-18 Continuous alkylation of isobutane with olefin - using part of prod. as coolant in place of water

Country Status (19)

Country Link
JP (1) JPS52102207A (en)
AR (1) AR224094A1 (en)
AT (1) AT362040B (en)
AU (1) AU505525B2 (en)
BR (1) BR7700336A (en)
CA (1) CA1094581A (en)
CS (1) CS199659B2 (en)
DD (1) DD128763A5 (en)
DE (1) DE2701170A1 (en)
DK (1) DK18277A (en)
FR (1) FR2338236A1 (en)
IN (1) IN145697B (en)
IT (1) IT1091806B (en)
MX (1) MX143073A (en)
NL (1) NL7700528A (en)
NO (1) NO770144L (en)
PT (1) PT66084B (en)
RO (1) RO79194A (en)
SE (1) SE424441B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002313A1 (en) * 1977-10-26 1979-06-13 The Standard Oil Company Process for catalytic alkylation; process for the separation of the alkylation reactor effluent
EP0003579A1 (en) * 1978-02-02 1979-08-22 Phillips Petroleum Company HF Alkylation process with maximum heat utilization of isoparaffin recycle

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5538284U (en) * 1978-09-05 1980-03-12
US4214114A (en) * 1979-01-26 1980-07-22 Uop Inc. Isoparaffin-olefin alkylation utilizing evaporative cooling in a reactor-depropanizer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3544652A (en) * 1966-07-15 1970-12-01 Pullman Inc Alkylation with sulfuric acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3544652A (en) * 1966-07-15 1970-12-01 Pullman Inc Alkylation with sulfuric acid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0002313A1 (en) * 1977-10-26 1979-06-13 The Standard Oil Company Process for catalytic alkylation; process for the separation of the alkylation reactor effluent
EP0003579A1 (en) * 1978-02-02 1979-08-22 Phillips Petroleum Company HF Alkylation process with maximum heat utilization of isoparaffin recycle

Also Published As

Publication number Publication date
AT362040B (en) 1981-04-27
PT66084B (en) 1978-06-26
AU2145677A (en) 1978-07-27
ATA25677A (en) 1980-09-15
CS199659B2 (en) 1980-07-31
FR2338236B1 (en) 1981-11-20
NL7700528A (en) 1977-07-21
CA1094581A (en) 1981-01-27
SE424441B (en) 1982-07-19
SE7700557L (en) 1977-07-20
BR7700336A (en) 1977-09-20
AU505525B2 (en) 1979-11-22
IN145697B (en) 1985-01-05
DK18277A (en) 1977-07-20
JPS6121927B2 (en) 1986-05-29
IT1091806B (en) 1985-07-06
PT66084A (en) 1977-02-01
NO770144L (en) 1977-07-20
DE2701170A1 (en) 1977-07-28
JPS52102207A (en) 1977-08-27
MX143073A (en) 1981-03-10
DD128763A5 (en) 1977-12-07
AR224094A1 (en) 1981-10-30
RO79194A (en) 1982-10-26

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Legal Events

Date Code Title Description
ST Notification of lapse