FR2324681A2 - Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776) - Google Patents

Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)

Info

Publication number
FR2324681A2
FR2324681A2 FR7529466A FR7529466A FR2324681A2 FR 2324681 A2 FR2324681 A2 FR 2324681A2 FR 7529466 A FR7529466 A FR 7529466A FR 7529466 A FR7529466 A FR 7529466A FR 2324681 A2 FR2324681 A2 FR 2324681A2
Authority
FR
France
Prior art keywords
beta
opt
contg
gps
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7529466A
Other languages
French (fr)
Other versions
FR2324681B2 (en
Inventor
Michel Crochemore
Michel Gay
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Industries SA
Original Assignee
Rhone Poulenc Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Industries SA filed Critical Rhone Poulenc Industries SA
Priority to FR7529466A priority Critical patent/FR2324681A2/en
Priority to CS76100A priority patent/CS196295B2/en
Priority to GB531/76A priority patent/GB1511621A/en
Priority to ZA00760090A priority patent/ZA7690B/en
Priority to BR7600085A priority patent/BR7600085A/en
Priority to PT64682A priority patent/PT64682B/en
Priority to FI760040A priority patent/FI64617C/en
Priority to DE2600516A priority patent/DE2600516C3/en
Priority to DD190753A priority patent/DD122551A5/en
Priority to CA243,383A priority patent/CA1077189A/en
Priority to BE163409A priority patent/BE837438A/en
Priority to AU10178/76A priority patent/AU496754B2/en
Priority to AR261893A priority patent/AR218429A1/en
Priority to IT19130/76A priority patent/IT1060204B/en
Priority to CH23276A priority patent/CH597303A5/xx
Priority to DK8276A priority patent/DK146927C/en
Priority to ES444162A priority patent/ES444162A1/en
Priority to AT12076A priority patent/AT348768B/en
Priority to NO760069A priority patent/NO152094C/en
Priority to SE7600175A priority patent/SE409037B/en
Priority to NL7600213.A priority patent/NL164311C/en
Priority to LU74155A priority patent/LU74155A1/xx
Priority to JP199276A priority patent/JPS5515498B2/ja
Priority to US05/754,232 priority patent/US4102839A/en
Publication of FR2324681A2 publication Critical patent/FR2324681A2/en
Application granted granted Critical
Publication of FR2324681B2 publication Critical patent/FR2324681B2/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Thermal stabiliser for (co)PVC comprises a mixt. of the usual carboxylate salts (I) of divalent metals and -diketones or -ketoaldehyde (II) of formula: R1-CO-cHR2-CO-R3 (in which R1 and R2 indep. are linear or branched alk(en)yl gps. with max. 30C, aralkyl gps. with 7-36C, aryl or cycloaliphatic gps. with less than 14C, opt. contg. C=C double bonds, opt. substd. by halogen or, in the case of the aryl or cycloaliphatic gpd., by Me or Et and opt. modified with -O-, -CO-O- and/or -CO- gp(s). In the aliphatic chain: R1 and R3 together can also be 2-5C alkylene, opt. contg. O or N; R1 or R3 can also be H; there is no ethylenic or aromatic unsatd. bond or carbonyl linkage on the C atom of R1 and R3 bound to the carbonyl gp.; R2 is H, an alk(en)yl gp. with max. 30C, opt. modified by -O-, -CO-O- or -CO- in the chain, or a -CO-R4 gp.; R4 is 1-30C alkyl or aryl, if neither R1 nor R3 is aromatic, or a gp. of the formula: R5 is 1-6C alkylene). These are used in amt. of 0.1-5wt.% (I) and 0.05-5, pref. 0.1-1wt.% (II) w.r.t. the polymer. Used for the stabilisation of various types of (co)PVC during moulding and elevated temp. applications.
FR7529466A 1975-01-10 1975-09-22 Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776) Granted FR2324681A2 (en)

Priority Applications (24)

Application Number Priority Date Filing Date Title
FR7529466A FR2324681A2 (en) 1975-09-22 1975-09-22 Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)
CS76100A CS196295B2 (en) 1975-01-10 1976-01-07 Stabilized materials based on polymers or copolymers vinylchloride
GB531/76A GB1511621A (en) 1975-01-10 1976-01-07 Stabilised vinyl chloride polymer compositions
ZA00760090A ZA7690B (en) 1975-01-10 1976-01-07 Stabilised vinyl chloride polymer compositions
PT64682A PT64682B (en) 1975-01-10 1976-01-08 PROCESS FOR THE PREPARATION OF COMPOSITIONS BASED ON POLYMERS OR COPOLYMERS OF VINYL CHLORIDE
FI760040A FI64617C (en) 1975-01-10 1976-01-08 STABILIZER POLYVINYLKLORIDBLANDNINGAR INNEHAOLLANDE BETA-DIKETON- ELLER BETA-KETOALDEHYDFOERENINGAR
DE2600516A DE2600516C3 (en) 1975-01-10 1976-01-08 Heat stabilization of molding compounds based on vinyl chloride homo- or copolymers
BR7600085A BR7600085A (en) 1975-01-10 1976-01-08 VINYL CHLORIDE POLYMERS OR COPOLIMERS BASED COMPOSITES
LU74155A LU74155A1 (en) 1975-01-10 1976-01-09
BE163409A BE837438A (en) 1975-01-10 1976-01-09 STABILIZED COMPOSITIONS BASED ON POLYVINYL CHLORIDE
AU10178/76A AU496754B2 (en) 1975-01-10 1976-01-09 Stabilised vinyl chloride polymer composition
AR261893A AR218429A1 (en) 1975-01-10 1976-01-09 VINYL CHLORIDE POLYMER OR COPOLYMER BASED COMPOSITIONS
DD190753A DD122551A5 (en) 1975-01-10 1976-01-09 HEAT STABILIZER FOR HOMOPOLYMERISATES AND COPOLYMERISATES BASED ON VINYL CHLORIDE
CH23276A CH597303A5 (en) 1975-01-10 1976-01-09
DK8276A DK146927C (en) 1975-01-10 1976-01-09 BISMUTH- AND ANTIMON-FREE HEAT-STABILIZED SUBSTANCES BASED ON A VINYL CHLORIDE POLYMER
ES444162A ES444162A1 (en) 1975-01-10 1976-01-09 Stabilised vinyl chloride polymer compositions
AT12076A AT348768B (en) 1975-01-10 1976-01-09 COMPOSITION BASED ON POLYVINYL CHLORIDE
NO760069A NO152094C (en) 1975-01-10 1976-01-09 HEAT STABILIZED VINYL CHLORIDE PLASTIC
SE7600175A SE409037B (en) 1975-01-10 1976-01-09 HEAT RESISTANCE POLYVINYL CHLORIDE COMPOSITIONS
NL7600213.A NL164311C (en) 1975-01-10 1976-01-09 PROCESS FOR PREPARING A PREPARATION BASED ON A POLYMER OR COPOLYMER OF VINYL CHLORIDE.
CA243,383A CA1077189A (en) 1975-01-10 1976-01-09 Polyvinyl chloride based stabilized compounds
JP199276A JPS5515498B2 (en) 1975-01-10 1976-01-09
IT19130/76A IT1060204B (en) 1975-01-10 1976-01-09 POLYVINYL CHLORIDE-BASED COMPOSITIONS
US05/754,232 US4102839A (en) 1975-01-10 1976-12-29 Stabilization of vinyl chloride polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7529466A FR2324681A2 (en) 1975-09-22 1975-09-22 Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)

Publications (2)

Publication Number Publication Date
FR2324681A2 true FR2324681A2 (en) 1977-04-15
FR2324681B2 FR2324681B2 (en) 1979-08-03

Family

ID=9160457

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7529466A Granted FR2324681A2 (en) 1975-01-10 1975-09-22 Thermal stabiliser mixt. for (co) polyvinyl chloride - contg. divalent metal carboxylated and beta-di-ketone or beta-keto-aldehyde (BE090776)

Country Status (1)

Country Link
FR (1) FR2324681A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2600516A1 (en) * 1975-01-10 1976-07-15 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
DE2652408A1 (en) * 1976-05-10 1977-11-17 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
DE2652458A1 (en) * 1976-05-20 1977-12-01 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
FR2529562A1 (en) * 1982-07-01 1984-01-06 Rhone Poulenc Spec Chim PROCESS FOR STABILIZING POLYMERS BASED ON VINYL CHLORIDE

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2600516A1 (en) * 1975-01-10 1976-07-15 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
DE2652408A1 (en) * 1976-05-10 1977-11-17 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
DE2652458A1 (en) * 1976-05-20 1977-12-01 Rhone Poulenc Ind HEAT STABILIZER FOR HOMOPOLYMERISATE AND COPOLYMERISATE BASED ON VINYL CHLORIDE
FR2529562A1 (en) * 1982-07-01 1984-01-06 Rhone Poulenc Spec Chim PROCESS FOR STABILIZING POLYMERS BASED ON VINYL CHLORIDE
EP0100741A1 (en) * 1982-07-01 1984-02-15 Rhone-Poulenc Chimie Process for the stabilization of vinyl chloride polymers

Also Published As

Publication number Publication date
FR2324681B2 (en) 1979-08-03

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