FR2320981A1 - Lubricant stable in ultraviolet contains a sulphur complex of nickel - esp. phenol sulphide, alkylthio-amine , dithiosphosphate or dithiocarbamate - Google Patents

Lubricant stable in ultraviolet contains a sulphur complex of nickel - esp. phenol sulphide, alkylthio-amine , dithiosphosphate or dithiocarbamate

Info

Publication number
FR2320981A1
FR2320981A1 FR7624821A FR7624821A FR2320981A1 FR 2320981 A1 FR2320981 A1 FR 2320981A1 FR 7624821 A FR7624821 A FR 7624821A FR 7624821 A FR7624821 A FR 7624821A FR 2320981 A1 FR2320981 A1 FR 2320981A1
Authority
FR
France
Prior art keywords
dithiocarbamate
esp
dithiosphosphate
alkylthio
amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7624821A
Other languages
French (fr)
Other versions
FR2320981B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of FR2320981A1 publication Critical patent/FR2320981A1/en
Application granted granted Critical
Publication of FR2320981B1 publication Critical patent/FR2320981B1/fr
Granted legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/18—Complexes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C10M2215/102—Ureas; Semicarbazides; Allophanates
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
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    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
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    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
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    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
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    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
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    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
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    • C10M2223/042—Metal salts thereof
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    • C10M2223/045—Metal containing thio derivatives
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    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/16—Groups 8, 9, or 10
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Abstract

The lubricant may be mineral or synthetic, and may be a viscosity oil, a hydrocracked oil, a hydraulic oil, a gearbox oil, a transmission fluid, a wax or a grease. The Ni complex is esp. (I) a phenol sulphide of Ni, (II) a Ni alkylthioamine, (III) a Ni dithiophosphate, or (IV) a Ni dithiocarbamate. (I) are of formula (where R is H or 1-30C alkyl, e.g. -C8H17. (II) is e.g. Ni (2,2'-thio-bis-(4-tert. octylphenolato))-n-butylamine. (III) is e.g. Ni bis-(4-methyl-2-pentyl) dithiophosphate. (IV) is e.g. Ni N,N-dibutyl dithiocarbamate. The lubricant contains 0.01-5(0.1-2) wt % of the Ni complex.
FR7624821A 1975-08-15 1976-08-13 Lubricant stable in ultraviolet contains a sulphur complex of nickel - esp. phenol sulphide, alkylthio-amine , dithiosphosphate or dithiocarbamate Granted FR2320981A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60497775A 1975-08-15 1975-08-15

Publications (2)

Publication Number Publication Date
FR2320981A1 true FR2320981A1 (en) 1977-03-11
FR2320981B1 FR2320981B1 (en) 1981-08-07

Family

ID=24421782

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7624821A Granted FR2320981A1 (en) 1975-08-15 1976-08-13 Lubricant stable in ultraviolet contains a sulphur complex of nickel - esp. phenol sulphide, alkylthio-amine , dithiosphosphate or dithiocarbamate

Country Status (21)

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JP (1) JPS6014793B2 (en)
AT (1) AT362487B (en)
AU (1) AU501498B2 (en)
BE (1) BE845054A (en)
BR (1) BR7605333A (en)
CA (1) CA1088506A (en)
CH (1) CH602909A5 (en)
DE (1) DE2636583A1 (en)
DK (1) DK367076A (en)
FI (1) FI60885C (en)
FR (1) FR2320981A1 (en)
GR (1) GR61121B (en)
IT (1) IT1066053B (en)
MX (1) MX145462A (en)
NL (1) NL7608842A (en)
NO (1) NO143707C (en)
NZ (1) NZ181648A (en)
PT (1) PT65462B (en)
SE (1) SE421429B (en)
TR (1) TR19122A (en)
ZA (1) ZA764881B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6285191U (en) * 1985-11-13 1987-05-30
WO1997015644A1 (en) * 1995-10-23 1997-05-01 Nsk Ltd. Lubricant composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE572057A (en) *
GB551852A (en) * 1939-12-27 1943-03-12 Standard Oil Dev Co Improved oxidation resisting hydrocarbon and rubber compositions
US3398170A (en) * 1964-05-21 1968-08-20 Universal Oil Prod Co Mixed chelates of a schiff base, an amine, and a transition series metal

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB800964A (en) * 1955-12-20 1958-09-03 Exxon Research Engineering Co Improvements in or relating to lubricating oil additive compositions and to lubricating oil compositions containing them
US2971941A (en) * 1959-05-15 1961-02-14 Ferro Corp Nickel bis-(p-octylphenol) monosulphide stabilized polyethylene
US2971940A (en) * 1959-03-20 1961-02-14 Ferro Corp Nickel phenolate stabilized polypropylene
US3215717A (en) * 1961-12-11 1965-11-02 American Cyanamid Co Phenol sulfide nickel amine derivatives
US3450636A (en) * 1967-08-22 1969-06-17 Sinclair Research Inc Automatic transmission fluid of reduced susceptibility oxidative degradation
GB1204798A (en) * 1967-12-06 1970-09-09 Snam Progetti Metal derivatives of dithiophosphoric acids and lubricating compositions containing them
FR2077906A1 (en) * 1970-02-23 1971-11-05 Inst Francais Du Petrole

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE572057A (en) *
GB551852A (en) * 1939-12-27 1943-03-12 Standard Oil Dev Co Improved oxidation resisting hydrocarbon and rubber compositions
US3398170A (en) * 1964-05-21 1968-08-20 Universal Oil Prod Co Mixed chelates of a schiff base, an amine, and a transition series metal

Also Published As

Publication number Publication date
BR7605333A (en) 1977-08-09
FI762327A (en) 1977-02-16
NO143707C (en) 1981-04-01
PT65462B (en) 1978-02-10
AU1678676A (en) 1978-02-16
DE2636583A1 (en) 1977-02-24
SE7608973L (en) 1977-02-16
FR2320981B1 (en) 1981-08-07
BE845054A (en) 1977-02-10
PT65462A (en) 1976-09-01
CH602909A5 (en) 1978-08-15
DK367076A (en) 1977-02-16
SE421429B (en) 1981-12-21
GR61121B (en) 1978-09-14
NO762814L (en) 1977-02-16
FI60885C (en) 1982-04-13
ATA608976A (en) 1980-10-15
MX145462A (en) 1982-02-19
CA1088506A (en) 1980-10-28
ZA764881B (en) 1978-03-29
JPS6014793B2 (en) 1985-04-16
NL7608842A (en) 1977-02-17
NO143707B (en) 1980-12-22
AT362487B (en) 1981-05-25
IT1066053B (en) 1985-03-04
TR19122A (en) 1978-07-01
FI60885B (en) 1981-12-31
AU501498B2 (en) 1979-06-21
JPS5224203A (en) 1977-02-23
NZ181648A (en) 1978-07-28

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