FR2288743A1 - Procede de fabrication simultanee d'epsilon-caprolactones et d'acides carboxyliques - Google Patents

Procede de fabrication simultanee d'epsilon-caprolactones et d'acides carboxyliques

Info

Publication number
FR2288743A1
FR2288743A1 FR7531858A FR7531858A FR2288743A1 FR 2288743 A1 FR2288743 A1 FR 2288743A1 FR 7531858 A FR7531858 A FR 7531858A FR 7531858 A FR7531858 A FR 7531858A FR 2288743 A1 FR2288743 A1 FR 2288743A1
Authority
FR
France
Prior art keywords
caprolactons
epsilon
carboxylic acids
simultaneous manufacturing
simultaneous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7531858A
Other languages
English (en)
Other versions
FR2288743B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Publication of FR2288743A1 publication Critical patent/FR2288743A1/fr
Application granted granted Critical
Publication of FR2288743B1 publication Critical patent/FR2288743B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyrane Compounds (AREA)
  • Pyridine Compounds (AREA)
FR7531858A 1974-10-23 1975-10-17 Procede de fabrication simultanee d'epsilon-caprolactones et d'acides carboxyliques Granted FR2288743A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP49122200A JPS5163118A (en) 1974-10-23 1974-10-23 Ipushiron kapurorakutonruito karubonsanruitono seizohoho

Publications (2)

Publication Number Publication Date
FR2288743A1 true FR2288743A1 (fr) 1976-05-21
FR2288743B1 FR2288743B1 (fr) 1978-04-07

Family

ID=14830027

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7531858A Granted FR2288743A1 (fr) 1974-10-23 1975-10-17 Procede de fabrication simultanee d'epsilon-caprolactones et d'acides carboxyliques

Country Status (9)

Country Link
US (1) US4013691A (fr)
JP (1) JPS5163118A (fr)
CA (1) CA1070700A (fr)
CH (1) CH619702A5 (fr)
DE (1) DE2546139C2 (fr)
FR (1) FR2288743A1 (fr)
GB (1) GB1507337A (fr)
IT (1) IT1042820B (fr)
NL (1) NL7512437A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0527642A1 (fr) * 1991-08-13 1993-02-17 Mitsubishi Gas Chemical Company, Inc. Procédé de préparation simultanée d'un lactone et d'un acide aromatique carboxylique
EP0569098A2 (fr) * 1992-05-07 1993-11-10 Dsm N.V. Conversion d'un cycloalcanone en lactone

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4652647A (en) * 1984-12-26 1987-03-24 Exxon Research And Engineering Company Aromatic-metal chelate compositions
US4870192A (en) * 1985-08-12 1989-09-26 Mobil Oil Corporation Production of lactones and omega-hydroxycarboxylic acids
US6258981B1 (en) 1999-02-17 2001-07-10 University Of Florida Catalytic oxidation of hydrocarbons
DE10010771C1 (de) * 2000-03-04 2001-05-03 Celanese Chem Europe Gmbh Verfahren zur Herstellung aliphatischer Carbonsäuren aus Aldehyden
CN102989459B (zh) * 2011-09-16 2014-10-29 中国科学院大连化学物理研究所 一种在醛助氧化作用下将环己酮/氧气氧化制备ε-己内脂的催化剂
CN102391238B (zh) * 2011-09-28 2013-07-03 江苏飞翔化工股份有限公司 一种催化环己酮氧化制备ε-己内酯的方法
CN106397386B (zh) * 2016-09-13 2019-05-14 华南理工大学 一种制备ε-己内酯的方法
CN109836406B (zh) 2017-11-28 2020-06-09 浙江大学 一种制备内酯类化合物的方法
CN109879853B (zh) * 2019-01-27 2020-10-20 台州市源众药业有限公司 一种Fe2O3/CeO2催化环己酮氧化制备ε-己内酯的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3025306A (en) * 1960-05-31 1962-03-13 Union Carbide Corp Process for the production of epsiloncaprolactones and carboxylic acids
GB1009773A (en) * 1963-08-19 1965-11-10 Ici Ltd Production of carboxylic acids and esters, particularly lactones
FR1411617A (fr) * 1963-10-17 1965-09-17 Stamicarbon Procédé pour la préparation d'epsilon-caprolactones
FR1435844A (fr) * 1963-12-23 1966-04-22 Ici Ltd Procédé de fabrication de composés organiques oxygénés
GB1103885A (en) * 1964-04-17 1968-02-21 Asahi Chemical Ind Method for producing lactones and carboxylic acids
DE1468169A1 (de) * 1964-12-16 1969-01-23 Knapsack Ag Verfahren zur gleichzeitigen Herstellung von aliphatischen Lactonen und von aliphatischen oder aromatischen Carbonsaeuren
NL6703009A (fr) * 1967-02-25 1968-08-26

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0527642A1 (fr) * 1991-08-13 1993-02-17 Mitsubishi Gas Chemical Company, Inc. Procédé de préparation simultanée d'un lactone et d'un acide aromatique carboxylique
EP0569098A2 (fr) * 1992-05-07 1993-11-10 Dsm N.V. Conversion d'un cycloalcanone en lactone
EP0569098A3 (fr) * 1992-05-07 1994-02-09 Dsm N.V. Conversion d'un cycloalcanone en lactone

Also Published As

Publication number Publication date
JPS5163118A (en) 1976-06-01
US4013691A (en) 1977-03-22
DE2546139A1 (de) 1976-04-29
IT1042820B (it) 1980-01-30
CH619702A5 (fr) 1980-10-15
GB1507337A (en) 1978-04-12
NL7512437A (nl) 1976-04-27
JPS5747896B2 (fr) 1982-10-13
DE2546139C2 (de) 1984-11-08
CA1070700A (fr) 1980-01-29
FR2288743B1 (fr) 1978-04-07

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Legal Events

Date Code Title Description
ST Notification of lapse