FR2281972A1 - Catalysts for hydro-desulphurising of oils - contg. cobalt, nickel or molybdenum oxides on alumina carriers contg. chromic oxide - Google Patents

Catalysts for hydro-desulphurising of oils - contg. cobalt, nickel or molybdenum oxides on alumina carriers contg. chromic oxide

Info

Publication number
FR2281972A1
FR2281972A1 FR7524821A FR7524821A FR2281972A1 FR 2281972 A1 FR2281972 A1 FR 2281972A1 FR 7524821 A FR7524821 A FR 7524821A FR 7524821 A FR7524821 A FR 7524821A FR 2281972 A1 FR2281972 A1 FR 2281972A1
Authority
FR
France
Prior art keywords
contg
carrier
catalysts
desulphurising
hydro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7524821A
Other languages
French (fr)
Other versions
FR2281972B3 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of FR2281972A1 publication Critical patent/FR2281972A1/en
Application granted granted Critical
Publication of FR2281972B3 publication Critical patent/FR2281972B3/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Refining catalysts of cobalt and/or nickel and molybdenum oxides on alumina as carrier, in which the carrier contains 3-15 wt.% chromium oxide. The catalyst is used in the hydro-desulphurising of petroleum fractions contg. asphaltenes and organo-metallic cpds., esp. vacuum gas oils and distillation residues. Activity and useful life of the catalysts are improved, and refining can be carried out under milder conditions. The carrier is ppted. from an aq. soln. of Al sulphate and Cr sulphate at 60-95 degrees C and pH 6.5-8.5, opt. dried and calcined. Metal oxides of sub-group 8 (pref. 2.5-5 wt.%) and subgroup 6 (pref. 5-13 wt.%) are then incorporated as usual e.g. by impregnating the dried carrier with ammoniacal solns. of Ni or Co molybdate, or mixing these with the moist carrier paste.
FR7524821A 1974-08-14 1975-08-08 Catalysts for hydro-desulphurising of oils - contg. cobalt, nickel or molybdenum oxides on alumina carriers contg. chromic oxide Granted FR2281972A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742439007 DE2439007B2 (en) 1974-08-14 1974-08-14 PROCESS FOR MANUFACTURING REFINING CATALYSTS AND THEIR USE FOR HYDRATING DESULFURIZATION OF VACUUM GAS OILS AND DISTILLATION RESIDUES

Publications (2)

Publication Number Publication Date
FR2281972A1 true FR2281972A1 (en) 1976-03-12
FR2281972B3 FR2281972B3 (en) 1979-06-15

Family

ID=5923184

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7524821A Granted FR2281972A1 (en) 1974-08-14 1975-08-08 Catalysts for hydro-desulphurising of oils - contg. cobalt, nickel or molybdenum oxides on alumina carriers contg. chromic oxide

Country Status (5)

Country Link
JP (1) JPS5142095A (en)
BE (1) BE832396A (en)
DE (1) DE2439007B2 (en)
FR (1) FR2281972A1 (en)
NL (1) NL7509547A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4188284A (en) * 1977-12-21 1980-02-12 Standard Oil Company (Indiana) Process for the hydrotreating of heavy hydrocarbon streams
US4191635A (en) * 1977-12-21 1980-03-04 Standard Oil Company (Indiana) Process for the cracking of heavy hydrocarbon streams
US4278566A (en) * 1979-03-19 1981-07-14 Standard Oil Company (Indiana) Hydrotreating process

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4181602A (en) 1977-12-21 1980-01-01 Standard Oil Company (Indiana) Process for the hydrotreating of heavy hydrocarbon streams
US4306965A (en) 1979-03-19 1981-12-22 Standard Oil Company (Indiana) Hydrotreating process
US4224144A (en) 1979-03-19 1980-09-23 Standard Oil Company (Indiana) Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur
JPS60202738A (en) * 1984-03-26 1985-10-14 Res Assoc Petroleum Alternat Dev<Rapad> Catalyst for denitrifying hydrocarbonic oil by hydrogenation
US6112771A (en) * 1995-04-28 2000-09-05 Yokohama Rubber Co., Ltd. Reinforced pressure hose

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4188284A (en) * 1977-12-21 1980-02-12 Standard Oil Company (Indiana) Process for the hydrotreating of heavy hydrocarbon streams
US4191635A (en) * 1977-12-21 1980-03-04 Standard Oil Company (Indiana) Process for the cracking of heavy hydrocarbon streams
US4278566A (en) * 1979-03-19 1981-07-14 Standard Oil Company (Indiana) Hydrotreating process

Also Published As

Publication number Publication date
NL7509547A (en) 1976-02-17
DE2439007B2 (en) 1977-03-10
BE832396A (en) 1976-02-13
JPS5142095A (en) 1976-04-09
DE2439007A1 (en) 1976-02-26
FR2281972B3 (en) 1979-06-15

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