FR2264047A2 - Polyesteramine fibres/mouldings affinitative to anionic dyes - polyterephthalates modified with amine-bearing side chains - Google Patents
Polyesteramine fibres/mouldings affinitative to anionic dyes - polyterephthalates modified with amine-bearing side chainsInfo
- Publication number
- FR2264047A2 FR2264047A2 FR7408425A FR7408425A FR2264047A2 FR 2264047 A2 FR2264047 A2 FR 2264047A2 FR 7408425 A FR7408425 A FR 7408425A FR 7408425 A FR7408425 A FR 7408425A FR 2264047 A2 FR2264047 A2 FR 2264047A2
- Authority
- FR
- France
- Prior art keywords
- gps
- anionic dyes
- pref
- polyesteramine
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/521—Polyesters using acid dyes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
- C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
Polyesteramines with good affinity towards anionic dyes are prepd. by exchange reaction of a diol contg. is not 3 C atoms perf. 1,4-butane-diol, with the methyl ester of aromatic dicarboxylic acid, pref. terephthalic acid, opt. contg. is not >10 mol.% of methyl ester of aliphatic dicarboxylic acid, until is not 90 wt.% of the theoretical methanol content is displaced, adding a cpd. NR3 (I), and continuing reaction under vacuum until polycondensation is complete. In (I) R = alkyl, cyclane, cycloalkyl or arylaliphatic gps. which contain ester-forming gps. to an inclusive total is not >3; 2 R gps. may be cyclised together; is not >2 R gps. are cycloaliphatic or arylaliphatic with only 1 C atom between N and the ring cpd.; is not 3 C atoms are between N and the ester-forming gps. (I) is pref. a N,N-omega-dihydroxyalkylamine, e.g., N,N-di-(omega-hydroxyhexyl)-benzylamine and is used in proportion to give >0.03 wt.% (e.g., 0.05-0.5, pref. 0.05-0.13wt.% N2) on the polyesteramine. For melt-extrudable, spinnable polyester filaments and fibres and mouldable articles dyeable with anionic dyes. High tenacity, crease-resistance and flexibility are combined with good dyeability.
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7408425A FR2264047A2 (en) | 1974-03-11 | 1974-03-11 | Polyesteramine fibres/mouldings affinitative to anionic dyes - polyterephthalates modified with amine-bearing side chains |
NLAANVRAGE7413351,A NL175303C (en) | 1973-10-15 | 1974-10-10 | METHOD FOR PREPARING LINEAR POLYESTERAMINES WITH GOOD AFFINITY FOR ANIONIC DYES, FIBERS, WHOLE OR PARTLY CONTAINING SUCH POLYESTERAMINES |
BR8502/74A BR7408502D0 (en) | 1973-10-15 | 1974-10-11 | POLYESTERAMINES OF GOOD DYE AFFINITY PROCESS FOR THEIR PREPARATION AND CONFORMED ITEMS OBTAINED FROM THESE POLYESTERAMINS |
CA211,328A CA1049694A (en) | 1973-10-15 | 1974-10-11 | Process for the preparation of polyesteramines having improved tinctorial affinities |
IE2115/74A IE40462B1 (en) | 1973-10-15 | 1974-10-14 | Spinnable polyesteramines and their production |
DK536974A DK536974A (en) | 1973-10-15 | 1974-10-14 | |
CH1377774A CH619475A5 (en) | 1973-10-15 | 1974-10-14 | |
JP49117231A JPS5838448B2 (en) | 1973-10-15 | 1974-10-14 | Polyester Amino Seizouhou Oyobi Sono Seikeibutsu |
LU71094A LU71094A1 (en) | 1973-10-15 | 1974-10-14 | |
US05/514,784 US3980620A (en) | 1973-10-15 | 1974-10-15 | Polyesteramines with improved dye affinity and process for their production |
DE2449099A DE2449099C2 (en) | 1973-10-15 | 1974-10-15 | Spinnable polyesteramines with good affinity for anionic dyes and their use |
GB44659/74A GB1484498A (en) | 1973-10-15 | 1974-10-15 | Spinnable polyesteramines and their production |
IT28444/74A IT1022890B (en) | 1973-10-15 | 1974-10-15 | IMPROVED PIALE-DYED AFFINITY POLYESTERAMINE AND PROCEDURE TO GET PLAIN |
ES431035A ES431035A1 (en) | 1973-10-15 | 1974-10-15 | Polyesteramines with improved dye affinity and process for their production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7408425A FR2264047A2 (en) | 1974-03-11 | 1974-03-11 | Polyesteramine fibres/mouldings affinitative to anionic dyes - polyterephthalates modified with amine-bearing side chains |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2264047A2 true FR2264047A2 (en) | 1975-10-10 |
FR2264047B2 FR2264047B2 (en) | 1980-01-04 |
Family
ID=9136211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7408425A Granted FR2264047A2 (en) | 1973-10-15 | 1974-03-11 | Polyesteramine fibres/mouldings affinitative to anionic dyes - polyterephthalates modified with amine-bearing side chains |
Country Status (1)
Country | Link |
---|---|
FR (1) | FR2264047A2 (en) |
-
1974
- 1974-03-11 FR FR7408425A patent/FR2264047A2/en active Granted
Also Published As
Publication number | Publication date |
---|---|
FR2264047B2 (en) | 1980-01-04 |
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