FR2233314A1 - Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light - Google Patents

Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light

Info

Publication number
FR2233314A1
FR2233314A1 FR7420480A FR7420480A FR2233314A1 FR 2233314 A1 FR2233314 A1 FR 2233314A1 FR 7420480 A FR7420480 A FR 7420480A FR 7420480 A FR7420480 A FR 7420480A FR 2233314 A1 FR2233314 A1 FR 2233314A1
Authority
FR
France
Prior art keywords
alkyl
hydroxy
protecting
violet light
polyethylenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7420480A
Other languages
French (fr)
Other versions
FR2233314B3 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH880073A external-priority patent/CH567451A5/en
Priority claimed from CH1504673A external-priority patent/CH582122A5/en
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of FR2233314A1 publication Critical patent/FR2233314A1/en
Application granted granted Critical
Publication of FR2233314B3 publication Critical patent/FR2233314B3/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/134Phenols containing ester groups
    • C08K5/1345Carboxylic esters of phenolcarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/22Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0091Complexes with metal-heteroatom-bonds

Abstract

p-Hydroxybenzoic acid esters of formula:- where R1 is C4-14 t-alkyl. R2 is H, alkyl, alkoxy, cycloalkyl, cycloalkylalkyl, aralkyl opt. substd in the aryl by 1-2 alkyl or halogen gps. or aryl opt. substd. by 1-2 alkyl gps. R3,R4 are H, alkyl, R5 is alkyl, cycloalkyl, cycloalkylalkyo, aralkyl, heterocyclic aromatic, or phenyl opt. substd. by 1-2 alkyl, or an alkoxy or a residue in the p-position of formula as above in the p-position to -COR5. Me is H or a divalent cation. Y is 0 or 1. Specifically (a) with y = 1, R1 t-butyl R t-butyl (o to hydroxy) R3 R4 t-butyl-(o-to hydroxy) Me is H or N1 and R5 either phenyl, p-chlorophenyl, p-t-butyphenyl, p-phenylphenyl and methyl, (b) with y = O, R1 R2 and Me as in (a) and R5 methyl. The cpds. are prepd, by esterification methods and are used for protecting org. cpds. against ultra-violet light, partic. polypropylene and polyethylene.
FR7420480A 1973-06-18 1974-06-13 Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light Granted FR2233314A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH880073A CH567451A5 (en) 1973-06-18 1973-06-18 Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light
CH1504673A CH582122A5 (en) 1973-10-25 1973-10-25 Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light

Publications (2)

Publication Number Publication Date
FR2233314A1 true FR2233314A1 (en) 1975-01-10
FR2233314B3 FR2233314B3 (en) 1977-04-08

Family

ID=25703785

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7420480A Granted FR2233314A1 (en) 1973-06-18 1974-06-13 Para-hydroxy-benzoic esters - contg. tert-alkyl groups for protecting polyethylenes against ultra violet light

Country Status (6)

Country Link
JP (1) JPS5036437A (en)
BR (1) BR7404922D0 (en)
DE (1) DE2428693A1 (en)
FR (1) FR2233314A1 (en)
IT (1) IT1013500B (en)
NL (1) NL7407965A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016017053A (en) * 2014-07-09 2016-02-01 Dic株式会社 Antioxidant, liquid crystal composition, and display element

Also Published As

Publication number Publication date
DE2428693A1 (en) 1975-01-16
NL7407965A (en) 1974-12-20
FR2233314B3 (en) 1977-04-08
JPS5036437A (en) 1975-04-05
IT1013500B (en) 1977-03-30
BR7404922D0 (en) 1975-01-21

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Legal Events

Date Code Title Description
ST Notification of lapse