FR2219966A2 - Resin coating compsns. from metals - contg. metal ions to control coating wt. - Google Patents

Resin coating compsns. from metals - contg. metal ions to control coating wt.

Info

Publication number
FR2219966A2
FR2219966A2 FR7407277A FR7407277A FR2219966A2 FR 2219966 A2 FR2219966 A2 FR 2219966A2 FR 7407277 A FR7407277 A FR 7407277A FR 7407277 A FR7407277 A FR 7407277A FR 2219966 A2 FR2219966 A2 FR 2219966A2
Authority
FR
France
Prior art keywords
metals
mins
ions
contg
metal ions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7407277A
Other languages
French (fr)
Other versions
FR2219966B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
Original Assignee
Amchem Products Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amchem Products Inc filed Critical Amchem Products Inc
Publication of FR2219966A2 publication Critical patent/FR2219966A2/en
Application granted granted Critical
Publication of FR2219966B2 publication Critical patent/FR2219966B2/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06—Copolymers with styrene
    • C09D109/08—Latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/142—Auto-deposited coatings, i.e. autophoretic coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/088—Autophoretic paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/10—Metal compounds
    • C08K3/11—Compounds containing metals of Groups 4 to 10 or of Groups 14 to 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The compsn. comprises a dispersion of 5-550 g/l resin, pref. latex, in an aqs. acids phase, pref. HF. of pH 1.6-5.0 and contains is not 0.025 (0.025-20) g/l Gp VI A to IV B metal as free ions or F-contlexed ions. For heavy coatings the compsn. may contain an oxidising agent, e.g. in amt. giving 0.01-0.2 oxidation equivs. per l. other additives include 5-30 g/l coalescing agent (e.g. ethylene glycol monobutyl ether), pigments and non-ion ic or anionic wetting agents. Substrates are contacted 15 sec. to 10 mins (0.5-5 mins) at 4-49(18-35) degrees C, opt. placed in oxidising atmos. for 15 sec. to 10 mins. rinsed, then dried or fired. Metals with ionization tendency between that of Al and Cu can be coated, compared with only ferrous substrates using the process of the parent patent in which Fe (III) ions were added.
FR7407277A 1971-03-10 1974-03-04 Resin coating compsns. from metals - contg. metal ions to control coating wt. Granted FR2219966A2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP46012462A JPS5235692B1 (en) 1971-03-10 1971-03-10

Publications (2)

Publication Number Publication Date
FR2219966A2 true FR2219966A2 (en) 1974-09-27
FR2219966B2 FR2219966B2 (en) 1976-06-25

Family

ID=11806007

Family Applications (2)

Application Number Title Priority Date Filing Date
FR7208545A Expired FR2141029A5 (en) 1971-03-10 1972-03-10
FR7407277A Granted FR2219966A2 (en) 1971-03-10 1974-03-04 Resin coating compsns. from metals - contg. metal ions to control coating wt.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
FR7208545A Expired FR2141029A5 (en) 1971-03-10 1972-03-10

Country Status (13)

Country Link
US (2) US4347172A (en)
JP (1) JPS5235692B1 (en)
AU (1) AU472666B2 (en)
BE (1) BE780486A (en)
BR (1) BR7201381D0 (en)
CA (1) CA1032678A (en)
DE (2) DE2211490C3 (en)
FR (2) FR2141029A5 (en)
GB (1) GB1356215A (en)
IT (1) IT958698B (en)
NL (1) NL156936B (en)
SE (1) SE388137B (en)
ZA (1) ZA721146B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0012134A1 (en) * 1978-11-29 1980-06-25 Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America Process for forming a polymeric coating on a metallic surface, acidic aqueous coating compositions and coating systems employing such compositions

Families Citing this family (46)

* Cited by examiner, † Cited by third party
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CA1089155A (en) * 1975-08-29 1980-11-11 Wilbur S. Hall Treating autodeposited coatings with cr composition
US4186219A (en) * 1975-08-29 1980-01-29 Union Carbide Corporation Maintaining the effectiveness of a coating composition
US4191676A (en) * 1976-03-08 1980-03-04 Union Carbide Corporation Autodeposition process and composition
US4108817A (en) 1976-12-30 1978-08-22 Amchem Products, Inc. Autodeposited coatings
US4229492A (en) * 1977-12-30 1980-10-21 Amchem Products, Inc. Control of autodeposition baths
AT352843B (en) * 1978-04-27 1979-10-10 Vianova Kunstharz Ag PROCESS FOR THE PREPARATION OF AQUATIC COATING EMULSIONS
US4366195A (en) 1979-03-27 1982-12-28 Amchem Products, Inc. Formation of polymeric coatings
US4414350A (en) * 1979-09-27 1983-11-08 Amchem Products, Inc. Ferrous complexing agent for autodeposition
ATE7926T1 (en) * 1980-02-01 1984-06-15 Imperial Chemical Industries Plc WATER-BASED PAINTS AND THEIR USE.
US4313861A (en) * 1980-02-28 1982-02-02 Union Carbide Corporation Latex autodeposition coatings
IT1208665B (en) * 1984-01-04 1989-07-10 Sperimentale Metallurg Spa E T HIGH RESISTANCE THERMAL RESISTANT COATING FOR METAL SHEETS
US4647480A (en) * 1983-07-25 1987-03-03 Amchem Products, Inc. Use of additive in aqueous cure of autodeposited coatings
US4562098A (en) * 1983-07-25 1985-12-31 Amchem Products Inc. Water or steam cure of autodeposited resin coatings on metallic substrates
US6312820B1 (en) 1983-07-25 2001-11-06 Henkel Corporation Vinylidene chloride resin in autodeposition
US5912297A (en) * 1983-07-25 1999-06-15 Henkel Corporation Internally stabilized vinylidene chloride resin in autodeposition
US4874673A (en) * 1984-12-20 1989-10-17 Henkel Corporation Use of fugitive plasticizer in autodepositing composition
US4578419A (en) * 1985-03-28 1986-03-25 Amchem Products, Inc. Iodine compound activation of autodeposition baths
US4657788A (en) * 1986-03-31 1987-04-14 The Standard Oil Company Process for multiple stage autodeposition of organic coatings onto metals
US4800106A (en) * 1987-06-19 1989-01-24 Amchem Products, Inc. Gloss enhancement of autodeposited coatings
DE3727382A1 (en) * 1987-08-17 1989-03-02 Henkel Kgaa ADDUCTS OF CARBONIC ACIDS AND ISOCYANATES ON EPOXIDES, AQUEOUS DISPERSIONS CONTAINING SUCH ADDUCTS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE IN THE AUTOPHORETIC COATING OF METALLIC SURFACES
IT1229206B (en) * 1988-03-30 1991-07-25 Nihon Parkerizing METHOD TO FORM A BLACK COLOR COATING ON THE MATERIAL SURFACE.
EP0374772B1 (en) * 1988-12-20 1994-03-30 HENKEL CORPORATION (a Delaware corp.) Two stage method for operating autodeposition bath
US5011715A (en) * 1988-12-20 1991-04-30 Henkel Corporation Two stage method for operating autodeposition bath
AU6625590A (en) * 1989-10-02 1991-04-28 Henkel Corporation Composition and process for and article with improved autodeposited surface coating based on epoxy resin
US5114751A (en) * 1989-10-24 1992-05-19 Henkel Corporation Application of an organic coating to small metal articles
US5232815A (en) * 1989-12-15 1993-08-03 W. R. Grace & Co.-Conn. Autodeposition emulsion and methods of using thereof to selectively protect metallic surfaces
CA2051400A1 (en) * 1989-12-15 1991-06-16 Alan R. Browne Autodeposition emulsion for selectively protecting metallic surfaces
US5508141A (en) * 1989-12-15 1996-04-16 W. R. Grace & Co.-Conn. Autodeposition emulsion and methods of using thereof to selectively protect metallic surfaces
US5061523A (en) * 1990-09-24 1991-10-29 Henkel Corporation Autodeposition process with low volatile organic chemical emissions
US5164234A (en) * 1991-01-24 1992-11-17 Henkel Corporation Treating an autodeposited coating with an alkaline solution containing organophosphonate ions
US5248525A (en) * 1991-01-24 1993-09-28 Henkel Corporation Treating an autodeposited coating with an alkaline solution containing anions of multifunctional organic acids
US5427863A (en) * 1992-09-23 1995-06-27 Henkel Corporation Polymer blends for autodeposited coating
US5385758A (en) * 1992-12-30 1995-01-31 Henkel Corporation Method for applying autodeposition coating
US5667845A (en) * 1993-08-05 1997-09-16 Henkel Corporation Treatment to improve corrosion resistance of autodeposited coatings on metallic surfaces
CA2130616A1 (en) * 1993-08-27 1995-02-28 Mark Charles Bricker Polymer emulsion, agent for cross-linking a polymer emulsion and method for making a polymer film
US5688560A (en) * 1993-11-09 1997-11-18 Henkel Corporation Process for coating metal surfaces
US5760112A (en) * 1994-02-23 1998-06-02 Henkel Corporation Water-borne autodepositing coating compositions
JPH1135880A (en) * 1997-07-11 1999-02-09 Nippon Parkerizing Co Ltd Water-based surface treating liquid for aluminum-based material and surface treatment using the same
US6645633B2 (en) 2001-09-25 2003-11-11 Henkel Corporation Autodeposition compositions
KR100411724B1 (en) * 2001-11-12 2003-12-18 김상수 Water soluble black coloring agent, the method of manufacturing the same, and volts and nuts coated with the same
AU2003249165A1 (en) * 2002-07-15 2004-02-02 Henkel Kommanditgesellschaft Auf Aktien Corrosion resistant films based on ethylenically unsaturated monomer modified epoxy emulsions
US7388044B2 (en) * 2002-07-15 2008-06-17 Henkel Kommanditgesellschaft Auf Aktien Coatings with enhanced water-barrier and anti-corrosive properties
DE102008023569A1 (en) * 2008-05-02 2009-11-05 Itn Nanovation Ag Protective coating resisting corrosive attack by aggressive flue gases in power stations and incinerators, contains oxidizing agent, catalyst and additives in polymeric matrix
EP2721101B1 (en) 2011-06-17 2020-10-14 Henkel AG & Co. KGaA Single bath autodeposition coating for combination metal substrates and methods therefor
DK2623163T3 (en) 2012-02-05 2016-09-19 Minimax Gmbh & Co Kg Extinguishing System
CN216603913U (en) 2019-02-08 2022-05-27 米尼麦克斯维京研发有限公司 Fire protection sprinkler with gradient material assembly

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GB1043577A (en) * 1964-04-17 1966-09-21 Gillette Industries Ltd Process for coating metals
FR2072293A5 (en) * 1969-11-28 1971-09-24 Celamese Coatings Cy

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GB1043577A (en) * 1964-04-17 1966-09-21 Gillette Industries Ltd Process for coating metals
FR2072293A5 (en) * 1969-11-28 1971-09-24 Celamese Coatings Cy

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0012134A1 (en) * 1978-11-29 1980-06-25 Amchem Products, Inc. a Corporation organised under the Laws of the State of Delaware United States of America Process for forming a polymeric coating on a metallic surface, acidic aqueous coating compositions and coating systems employing such compositions

Also Published As

Publication number Publication date
JPS5235692B1 (en) 1977-09-10
DE2211490A1 (en) 1972-09-21
FR2219966B2 (en) 1976-06-25
ZA721146B (en) 1972-10-25
DE2211490C3 (en) 1984-09-27
FR2141029A5 (en) 1973-01-19
NL156936B (en) 1978-06-15
DE2409897C3 (en) 1982-05-19
DE2409897A1 (en) 1974-09-26
US4347172A (en) 1982-08-31
DE2409897B2 (en) 1981-08-06
IT958698B (en) 1973-10-30
US4411937A (en) 1983-10-25
DE2211490B2 (en) 1979-03-22
CA1032678A (en) 1978-06-06
NL7203161A (en) 1972-09-12
GB1356215A (en) 1974-06-12
BE780486A (en) 1972-07-03
BR7201381D0 (en) 1973-06-14
AU472666B2 (en) 1973-09-13
AU3981072A (en) 1973-09-13
SE388137B (en) 1976-09-27

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