FR2175689A1 - Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers - Google Patents

Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers

Info

Publication number
FR2175689A1
FR2175689A1 FR7209590A FR7209590A FR2175689A1 FR 2175689 A1 FR2175689 A1 FR 2175689A1 FR 7209590 A FR7209590 A FR 7209590A FR 7209590 A FR7209590 A FR 7209590A FR 2175689 A1 FR2175689 A1 FR 2175689A1
Authority
FR
France
Prior art keywords
oxidn
derivs
hydrazines
coreducers
organic hydroxyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7209590A
Other languages
French (fr)
Other versions
FR2175689B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7209590A priority Critical patent/FR2175689A1/en
Publication of FR2175689A1 publication Critical patent/FR2175689A1/en
Application granted granted Critical
Publication of FR2175689B1 publication Critical patent/FR2175689B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Hydroxyl derivs. are prepd. by molecular oxidn. of aliphatic, alicyclic or aromatic hydrocarbons using a transition metal catalyst with hydrazines (I) as co-reducers (at 5-60 degrees C). (I) are R1-NH-NH-R2 where R1, R2 are 1-20C (substd) alkyl, aryl, aralkyl, alkylaryl or sec. cyclic hydrazine where 0.001-1 mole/litre of a 1-10C carboxylic acid is added. Oxidised (I) is regenerated by catalytic reduction. Use of co-reducers gives excellent selectivity at low temp.
FR7209590A 1972-03-17 1972-03-17 Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers Granted FR2175689A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7209590A FR2175689A1 (en) 1972-03-17 1972-03-17 Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7209590A FR2175689A1 (en) 1972-03-17 1972-03-17 Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers

Publications (2)

Publication Number Publication Date
FR2175689A1 true FR2175689A1 (en) 1973-10-26
FR2175689B1 FR2175689B1 (en) 1974-08-30

Family

ID=9095454

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7209590A Granted FR2175689A1 (en) 1972-03-17 1972-03-17 Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers

Country Status (1)

Country Link
FR (1) FR2175689A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0301723A1 (en) * 1987-07-20 1989-02-01 Sun Refining and Marketing Company Oxidation of alkanes

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4045498A (en) 1975-10-15 1977-08-30 Fats And Proteins Research Foundation, Inc. Method of hydroxylation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0301723A1 (en) * 1987-07-20 1989-02-01 Sun Refining and Marketing Company Oxidation of alkanes

Also Published As

Publication number Publication date
FR2175689B1 (en) 1974-08-30

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Legal Events

Date Code Title Description
ST Notification of lapse