FR2189463A1 - Polymeric catalyst precursor - comprising complex of a polysilsesquioxane and palladium or platinum - Google Patents

Polymeric catalyst precursor - comprising complex of a polysilsesquioxane and palladium or platinum

Info

Publication number
FR2189463A1
FR2189463A1 FR7321694A FR7321694A FR2189463A1 FR 2189463 A1 FR2189463 A1 FR 2189463A1 FR 7321694 A FR7321694 A FR 7321694A FR 7321694 A FR7321694 A FR 7321694A FR 2189463 A1 FR2189463 A1 FR 2189463A1
Authority
FR
France
Prior art keywords
esp
alkyl
substd
opt
substituent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7321694A
Other languages
French (fr)
Other versions
FR2189463B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of FR2189463A1 publication Critical patent/FR2189463A1/en
Application granted granted Critical
Publication of FR2189463B1 publication Critical patent/FR2189463B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/398—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B01J31/1675—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins the linkage being to an organometallic polymer covered by groups B01J31/123 - B01J31/127, e.g. polyhydrosiloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/30—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen phosphorus-containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Non-linear polymer for use as a catalyst precursor, eg in prodn of catalysts for polymsn of dienes, hydrogenation isomerisation of alkenes, oligomeriation, acetoxylation silylation and hydrocyanation of alkenes and the oxo process consists of repeating units of formula (I) (where R' is opt substd 1-10C alkylene, the substituent being halogen or phenyl, esp unsubstd 1-5C alkylene, or opt. substd divalent aryl gp with 1-3 benzene rings, the substituent being halogen or 1-5C alkyl, esp chlorinated or unchlorinated phenylene or diphenylene; and R2 is opt. substd 1-10C alkyl or cycloalkyl esp. 1-5C alkyl, or opt substd aryl with 1-3 benzene rings, the substituent being halogen or 1-5C alkyl, esp. chlorinated or unchlorinated phenyl or diphenyl). Gives catalysts producing higher conversions based on wt. of catalytic component. Easy recovery of catalyst for recycling. Avoids loss of expensive catalytic metals.
FR7321694A 1972-06-15 1973-06-14 Polymeric catalyst precursor - comprising complex of a polysilsesquioxane and palladium or platinum Granted FR2189463A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US26323172A 1972-06-15 1972-06-15

Publications (2)

Publication Number Publication Date
FR2189463A1 true FR2189463A1 (en) 1974-01-25
FR2189463B1 FR2189463B1 (en) 1976-04-30

Family

ID=23000914

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7321694A Granted FR2189463A1 (en) 1972-06-15 1973-06-14 Polymeric catalyst precursor - comprising complex of a polysilsesquioxane and palladium or platinum

Country Status (7)

Country Link
JP (1) JPS4952194A (en)
BE (1) BE800896A (en)
CA (1) CA1014967A (en)
DE (1) DE2330308A1 (en)
FR (1) FR2189463A1 (en)
IT (1) IT985430B (en)
NL (1) NL7308282A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002055587A1 (en) * 2001-01-09 2002-07-18 Queen Mary & Westfield College Organopolysiloxanes containing phosphonic groups, methods for the production and use thereof
WO2004007073A1 (en) * 2002-07-10 2004-01-22 Johnson Matthey Plc Supported catalyst

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3837416A1 (en) * 1988-11-04 1990-05-10 Degussa ORGANOSILOXANAMINE COPOLY CONDENSATES, METHOD FOR THE PRODUCTION AND USE THEREOF (II)
DE3925360C1 (en) * 1989-07-31 1991-02-07 Degussa Ag, 6000 Frankfurt, De
DE4035033C1 (en) * 1990-11-03 1992-04-02 Degussa Ag, 6000 Frankfurt, De
DE4035032C1 (en) * 1990-11-03 1992-04-30 Degussa Ag, 6000 Frankfurt, De
JP5791040B2 (en) * 2011-03-09 2015-10-07 国立研究開発法人産業技術総合研究所 Phosphine compounds and phosphine-containing organic-inorganic composites and their use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1007333A (en) * 1961-05-30 1965-10-13 Midland Silicones Ltd Organosilicon compounds containing phosphorus

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1007333A (en) * 1961-05-30 1965-10-13 Midland Silicones Ltd Organosilicon compounds containing phosphorus

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002055587A1 (en) * 2001-01-09 2002-07-18 Queen Mary & Westfield College Organopolysiloxanes containing phosphonic groups, methods for the production and use thereof
US7064226B2 (en) 2001-01-09 2006-06-20 Phosphonics Limited Organopolysiloxanes containing phosphonic groups, method for the production and use thereof
WO2004007073A1 (en) * 2002-07-10 2004-01-22 Johnson Matthey Plc Supported catalyst

Also Published As

Publication number Publication date
FR2189463B1 (en) 1976-04-30
DE2330308A1 (en) 1974-01-03
JPS4952194A (en) 1974-05-21
IT985430B (en) 1974-11-30
BE800896A (en) 1973-12-14
CA1014967A (en) 1977-08-02
NL7308282A (en) 1973-12-18

Similar Documents

Publication Publication Date Title
NL182202B (en) PROCESS FOR THE AMMOXYDATION, OXYDATION OR OXYDATIVE DEHYDROGENATION OF A HYDROCARBON IN A REACTOR WITH A FLUIDIZED MOLYBIDE-CONDITIONING CATALYST.
ES448086A1 (en) Catalysts and catalyst components for polymerizing olefins
ES404351A1 (en) Olefin polymerization catalysts and method for preparation of same
FR2189463A1 (en) Polymeric catalyst precursor - comprising complex of a polysilsesquioxane and palladium or platinum
FR2330695B3 (en)
CA995246A (en) Process for preparing sulfited platinum on carbon catalysts
NL177129B (en) PROCESS FOR CATALYTIC TREATMENT OF HYDROCARBONS WITH HYDROGEN IN THE PRESENCE OF A FLUORUS-CONTAINING NICKEL-TUNGSTEN CATALYST ON ALUMINA AS A CARRIER.
AU472485B2 (en) Graft polymers of vinyl chloride on unsaturated olefinic elastomers
NL7505081A (en) METHOD OF TREATING A CATALYSIS USED FOR HYDROCARBONS CATALYSTIC REACTIONS DURING REMOVAL OF THE CATALYST.
NL168723C (en) PROCESS FOR PREPARING A CATALYST CONTAINING A METAL FROM THE PLATINUM GROUP FOR THE SELECTIVE HYDROGENATION OF AROMATIC CHLORONITRO- TO CHLOROAMIN COMPOUNDS.
YU348674A (en) Process for preparing a silver catalysts on a carrier,suitable in the catalytical oxidation of ethylene into ethylene oxide
FR2302133A1 (en) Catalyst compsns. - comprising a metal coordination complex grafta to a polysiloxane supported on a solvent-insol. mineral carrier
GB1269862A (en) Process for regenerating a hydrogenation catalyst
ES430511A1 (en) Process for the preparation of {60 -6-deoxytetracyclines
CA989381A (en) Catalyst or catalyst carrier for side reactions of catalytic cracking of hydrocarbons
NL180425C (en) PROCESS FOR PERFORMING EXOTHERMAL, CATALYTIC POLYMERIZATION, CONTROLLING THE POLYMERIZATION TEMPERATURE BY EVAPORATING PART OF THE REACTION MIXTURE.
NL173050C (en) PROCESS FOR WINNING BUTADIENE (1.3) FROM A TECHNICAL CŸ4 HYDROCARBON FLOW.
ES411107A1 (en) Purification of 1-nitroanthraquinone
GB1391868A (en) Process for the production of unsaturated organosilicon compounds
CA1003390A (en) Process for the regeneration of a deactivated hydrocarbon conversion catalyst
IE40017L (en) Catalytic process oxidation of unsaturated hydrocarbons.
FR2289239A1 (en) Selective dimerisation of diolefins into linear prods - using divalent nickel complex oligomerisation catalyst
FR2253561A2 (en) Catalyst esp. for automobile exhaust gas purificn. - dispersed on carrier using ionic bombardment process
CA978552A (en) Catalyst for the treatment of hydrocarbons, methods for preparing it and processes using said catalyst
FR2175689A1 (en) Organic hydroxyl derivs - by catalytic hydrocarbon oxidn with hydrazines as coreducers

Legal Events

Date Code Title Description
ST Notification of lapse