FR2170899A2 - Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal - Google Patents

Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal

Info

Publication number
FR2170899A2
FR2170899A2 FR7204055A FR7204055A FR2170899A2 FR 2170899 A2 FR2170899 A2 FR 2170899A2 FR 7204055 A FR7204055 A FR 7204055A FR 7204055 A FR7204055 A FR 7204055A FR 2170899 A2 FR2170899 A2 FR 2170899A2
Authority
FR
France
Prior art keywords
contg
regeneration
pref
gas
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7204055A
Other languages
French (fr)
Other versions
FR2170899B2 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7141069A external-priority patent/FR2160269A1/en
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7204055A priority Critical patent/FR2170899A2/en
Priority to BE790431D priority patent/BE790431A/en
Priority to GB5238572A priority patent/GB1364616A/en
Priority to DE2255497A priority patent/DE2255497A1/en
Priority to GB2190473A priority patent/GB1364617A/en
Priority to DE2265608A priority patent/DE2265608C2/de
Priority to AR245130A priority patent/AR229665A1/en
Priority to EG468/72A priority patent/EG10731A/en
Priority to SE7214827A priority patent/SE394687B/en
Priority to ES408625A priority patent/ES408625A1/en
Priority to AT969272A priority patent/AT334492B/en
Priority to CA156,758A priority patent/CA980281A/en
Priority to NO4148/72A priority patent/NO137555C/en
Priority to IT31715/72A priority patent/IT974673B/en
Priority to NLAANVRAGE7215493,A priority patent/NL173764C/en
Priority to JP47115483A priority patent/JPS5248601B2/ja
Publication of FR2170899A2 publication Critical patent/FR2170899A2/en
Application granted granted Critical
Publication of FR2170899B2 publication Critical patent/FR2170899B2/fr
Priority to NO751262A priority patent/NO139608C/en
Priority to SE7506318A priority patent/SE408804B/en
Priority to US05/741,744 priority patent/US4133743A/en
Priority to US05/966,995 priority patent/US4210519A/en
Priority to US05/966,994 priority patent/US4233268A/en
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/10Catalytic reforming with moving catalysts
    • C10G35/12Catalytic reforming with moving catalysts according to the "moving-bed" method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • B01J38/44Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material and adding simultaneously or subsequently free oxygen; using oxyhalogen compound
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
    • B01J8/125Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow with multiple sections one above the other separated by distribution aids, e.g. reaction and regeneration sections

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The catalyst, consisting of 1 metal of gp. VIa, VIIa or VIII on a carrier, circulates through a reactor contg. >=2 catalytic zones arranged vertically above each other and is progressively drawn off from the last zone, regenerated and recycled to the other end so that the activity remains substantially constant at any point. Pref. the regenerated catalyst goes to the top of a second similar reactor in which the treatment of the hydrocarbon charge from the first is continued, is drawn off from the bottom and lifted to the top of the first reactor, through which it then circulates. Volume of the catalytic zones pref. increases in the direction in which the charge moves. Regeneration is pref. by combustion in O2 contg. gas, oxychlorination with gas contg. O2 and halogen, hydrogen halide or alkyl halide, treatment with O2-contg. gas and finally reduction in H2. The process is esp. suitable for reforming and and prodn. of aromatics from petrols obtained by pyrolysis, cracking, steam-cracking, catalytic reforming or from naphthenes. It permits continuous operation without interruption for catalyst regeneration.
FR7204055A 1971-11-16 1972-02-07 Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal Granted FR2170899A2 (en)

Priority Applications (21)

Application Number Priority Date Filing Date Title
FR7204055A FR2170899A2 (en) 1971-11-16 1972-02-07 Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal
BE790431D BE790431A (en) 1971-11-16 1972-10-23 METHOD AND APPARATUS FOR HYDROCARBON CONVERSION PROCESSES
GB5238572A GB1364616A (en) 1971-11-16 1972-11-13 Process for hydrocarbon conversion
DE2255497A DE2255497A1 (en) 1971-11-16 1972-11-13 METHOD AND DEVICE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS
GB2190473A GB1364617A (en) 1971-11-16 1972-11-13 Apparatus for hydrocarbon conversion
DE2265608A DE2265608C2 (en) 1971-11-16 1972-11-13
AR245130A AR229665A1 (en) 1971-11-16 1972-11-14 PROCEDURE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS IN THE PRESENCE OF A GRANULATED CATALYST CONTAINING A SUPPORT AND AT LEAST ONE METAL SELECTED BETWEEN THE GROUP MADE UP OF METALS FROM THE VIA, VIIA AND VIII GROUPS OF THE PERIODIC SYSTEM OF THE ELEMENTS AND APPARATUS FOR LA PUTAAC OF SUCH PROCEDURE
ES408625A ES408625A1 (en) 1971-11-16 1972-11-15 Moving bed catalytic process for hydrocarbon conversion
NO4148/72A NO137555C (en) 1971-11-16 1972-11-15 PROCEDURE AND APPARATUS FOR CONTINUOUS CONVERSION OF HYDROCARBONS
SE7214827A SE394687B (en) 1971-11-16 1972-11-15 PROCEDURE AND DEVICE FOR CONTINUOUS CONVERSION OF THE CARBON IN THE PRESENCE OF A GRAIN CATALYST, WHERE THE WHEAT AND THE CARBON ARE GUIDED THROUGH AT LEAST TWO CATALYTIC ELEMENT ZONES, WHICH ARE ESSENTIAL ...
EG468/72A EG10731A (en) 1971-11-16 1972-11-15 Process and apparatus for hydrocarbons conversion
AT969272A AT334492B (en) 1971-11-16 1972-11-15 METHOD AND DEVICE FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS
CA156,758A CA980281A (en) 1971-11-16 1972-11-15 Procede et appareillage pour procedes de conversions d'hydrocarbures
IT31715/72A IT974673B (en) 1971-11-16 1972-11-16 PROCESS AND EQUIPMENT FOR HYDROCARBON CONVERSION PROCESSES
NLAANVRAGE7215493,A NL173764C (en) 1971-11-16 1972-11-16 PROCESS FOR THE CONTINUOUS CONVERSION OF HYDROCARBONS.
JP47115483A JPS5248601B2 (en) 1971-11-16 1972-11-16
NO751262A NO139608C (en) 1971-11-16 1975-04-10 PROCEDURE FOR CATALYTIC CONVERSION OF HYDROCARBONS USING A DIVIDED STREAM OF CATALYST TRANSPORT RECYCLING HYDROGEN
SE7506318A SE408804B (en) 1971-11-16 1975-06-03 PROCEDURE FOR CONTINUOUS CONVERSION OF THE PISTON IN THE PRESENCE OF A GRAIN CATALYST, WHERE THE WHEAT AND THE PISTON ARE GUIDED THROUGH AT TWO CATALYTIC ELEMENTARY ZONES, WHICH ARE SIGNIFICANTLY VERTICAL ..
US05/741,744 US4133743A (en) 1971-11-16 1976-11-15 Moving bed catalytic process for hydrocarbon conversion
US05/966,994 US4233268A (en) 1971-11-16 1978-12-06 Apparatus for hydrocarbon conversion
US05/966,995 US4210519A (en) 1971-11-16 1978-12-06 Process and apparatus for hydrocarbon conversion

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7141069A FR2160269A1 (en) 1971-11-16 1971-11-16 Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal
FR7204055A FR2170899A2 (en) 1971-11-16 1972-02-07 Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal

Publications (2)

Publication Number Publication Date
FR2170899A2 true FR2170899A2 (en) 1973-09-21
FR2170899B2 FR2170899B2 (en) 1974-09-13

Family

ID=26216721

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7204055A Granted FR2170899A2 (en) 1971-11-16 1972-02-07 Catalytic conversion of hydrocarbons - using multiple zones in series with continuous circulation and regeneration of catal

Country Status (1)

Country Link
FR (1) FR2170899A2 (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Also Published As

Publication number Publication date
FR2170899B2 (en) 1974-09-13

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