GB1111588A - Continuous process for producing gasoline hydrocarbons - Google Patents
Continuous process for producing gasoline hydrocarbonsInfo
- Publication number
- GB1111588A GB1111588A GB38675/65A GB3867565A GB1111588A GB 1111588 A GB1111588 A GB 1111588A GB 38675/65 A GB38675/65 A GB 38675/65A GB 3867565 A GB3867565 A GB 3867565A GB 1111588 A GB1111588 A GB 1111588A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst particles
- reaction zone
- increased
- temperature
- regeneration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 8
- 238000010924 continuous production Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 8
- 238000006243 chemical reaction Methods 0.000 abstract 8
- 239000003921 oil Substances 0.000 abstract 7
- 239000002245 particle Substances 0.000 abstract 7
- 230000008929 regeneration Effects 0.000 abstract 6
- 238000011069 regeneration method Methods 0.000 abstract 6
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- 239000000571 coke Substances 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000000567 combustion gas Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000004523 catalytic cracking Methods 0.000 abstract 1
- 239000012084 conversion product Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C10G11/187—Controlling or regulating
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A continuous process for producing gasoline hydrocarbons by the catalytic cracking of heavier hydrocarbon oils, wherein a hydrocarbon charge stream containing fresh oil and recylcle oil is subjected to a fluidized contacting of catalyst particles in a reaction zone, hydrocarbon conversion products are separated from the contacted catalyst particles, separated catalyst particles containing a coke deposit are subjected to a fluidized contacting of a free oxygen-containing gas stream in a separate regeneration zone with formation of combustion gases, the combustion gases are separated from hot regenerated catalyst particles, separated hot regenerated catalyst particles with a reduced coke content are returned to the reaction zone and the temperature of the reaction zone and the time of contact of the hydrocarbon charge stream with the catalyst particles therein are adjusted to effect on the catalyst particles in the reaction zone a coke deposition which provides in the regeneration zone a regeneration temperature above 621 DEG C. while after-burning in the upper portion of the regeneration zone is controlled by regulation of the supply of the oxygen-containing gas stream, is characterized in that upon attaining a regeneration temperature above 621 DEG C. an increased conversion into C4 and heavier hydrocarbons boiling within the gasoline range, measured as liquid volume per cent of the fresh oil, is brought about by obtaining an increased net production of coke, measured as weight per cent of the fresh oil, by the steps of using an increased catalyst circulation rate as well as an increased value of at least one of the conditions of (1) proportion of heavy recycle oil to fresh oil in hydrocarbon charge stream; (2) temperature in the reaction zone; and (3) temperature difference between the reaction zone and the regeneration zone. "Increased" means increased with respect to prior Specification 971,966. In examples the temperature in the dense phase of the regenerator is between 629 DEG C. and 649 DEG C., the corresponding temperature in the reactor dense phase varying between 489 DEG C. and 502 DEG C. Overall conversions of up to 78 volume per cent are produced. Low pressures, less than 2.1 kg/cm.2 are used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US413567A US3206393A (en) | 1964-11-24 | 1964-11-24 | Fluid catalytic cracking of hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1111588A true GB1111588A (en) | 1968-05-01 |
Family
ID=23637730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB38675/65A Expired GB1111588A (en) | 1964-11-24 | 1965-09-10 | Continuous process for producing gasoline hydrocarbons |
Country Status (10)
Country | Link |
---|---|
US (1) | US3206393A (en) |
AT (1) | AT268484B (en) |
BE (1) | BE672625A (en) |
CH (1) | CH474565A (en) |
CS (1) | CS176102B2 (en) |
DE (1) | DE1273101B (en) |
ES (1) | ES317389A1 (en) |
GB (1) | GB1111588A (en) |
NL (1) | NL6511901A (en) |
PL (1) | PL79138B1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0061137A1 (en) * | 1981-03-23 | 1982-09-29 | Ashland Oil, Inc. | Use of naphtha in carbo-metallic oil conversion |
EP0120096A1 (en) * | 1981-03-23 | 1984-10-03 | Ashland Oil, Inc. | Process for converting carbo-metallic oils, and addition of MgCl2 to the catalyst |
US4708785A (en) * | 1979-11-14 | 1987-11-24 | Ashland Oil, Inc. | Carbo-metallic oil conversion |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3410793A (en) * | 1966-06-27 | 1968-11-12 | Texaco Inc | Method and apparatus for controlling the regeneration of contaminated solids in a fluidized system |
US3394075A (en) * | 1966-07-05 | 1968-07-23 | Mobil Oil Corp | Utilization of superactive catalysts containing residual coke |
US3513087A (en) * | 1968-08-30 | 1970-05-19 | Continental Oil Co | Control system for fluid cat cracker |
US3850582A (en) * | 1969-12-10 | 1974-11-26 | Exxon Research Engineering Co | Apparatus for controlled addition of fluidized particles to a processing unit |
US3629097A (en) * | 1970-01-06 | 1971-12-21 | Continental Oil Co | Control system for fluid catalytic cracking process |
US4006075A (en) * | 1975-01-06 | 1977-02-01 | Exxon Research And Engineering Company | Method of regenerating a cracking catalyst with substantially complete combustion of carbon monoxide |
US4180454A (en) * | 1978-01-03 | 1979-12-25 | Exxon Research & Engineering Co. | Method for combusting carbon monoxide in a fluid catalytic cracking process |
US4243518A (en) * | 1979-07-18 | 1981-01-06 | Exxon Research & Engineering Co. | External method for reducing transverse oxygen gradients in FCCU regeneration |
US4243517A (en) * | 1979-07-18 | 1981-01-06 | Exxon Research & Engineering Co. | Internal method for reducing transverse oxygen gradients in FCCU regeneration |
US4354957A (en) * | 1980-10-03 | 1982-10-19 | Phillips Petroleum Company | Regenerator temperature control |
US6114265A (en) * | 1994-03-15 | 2000-09-05 | Exxon Research And Engineering Company | Combustion control in a fluid catalytic cracking regenerator |
US6012652A (en) | 1998-01-30 | 2000-01-11 | Mobil Oil Corporation | Atomizing nozzle and method of use thereof |
US6142457A (en) * | 1998-01-30 | 2000-11-07 | Mobil Oil Corporation | Atomizing feed nozzle |
CN113213656A (en) * | 2021-03-23 | 2021-08-06 | 高和平 | Novel system for treating coking wastewater by catalytic oxidation method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL283942A (en) * | 1962-06-29 |
-
1964
- 1964-11-24 US US413567A patent/US3206393A/en not_active Expired - Lifetime
-
1965
- 1965-09-09 AT AT827065A patent/AT268484B/en active
- 1965-09-10 CH CH1261765A patent/CH474565A/en not_active IP Right Cessation
- 1965-09-10 GB GB38675/65A patent/GB1111588A/en not_active Expired
- 1965-09-13 ES ES0317389A patent/ES317389A1/en not_active Expired
- 1965-09-13 NL NL6511901A patent/NL6511901A/xx unknown
- 1965-10-26 DE DEU12147A patent/DE1273101B/en active Pending
- 1965-11-18 PL PL1965111673A patent/PL79138B1/pl unknown
- 1965-11-22 BE BE672625A patent/BE672625A/xx unknown
- 1965-11-23 CS CS6997A patent/CS176102B2/cs unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4708785A (en) * | 1979-11-14 | 1987-11-24 | Ashland Oil, Inc. | Carbo-metallic oil conversion |
EP0061137A1 (en) * | 1981-03-23 | 1982-09-29 | Ashland Oil, Inc. | Use of naphtha in carbo-metallic oil conversion |
EP0120096A1 (en) * | 1981-03-23 | 1984-10-03 | Ashland Oil, Inc. | Process for converting carbo-metallic oils, and addition of MgCl2 to the catalyst |
Also Published As
Publication number | Publication date |
---|---|
US3206393A (en) | 1965-09-14 |
BE672625A (en) | 1966-03-16 |
CS176102B2 (en) | 1977-06-30 |
CH474565A (en) | 1969-06-30 |
PL79138B1 (en) | 1975-06-30 |
DE1273101B (en) | 1968-07-18 |
ES317389A1 (en) | 1966-03-01 |
AT268484B (en) | 1969-02-10 |
NL6511901A (en) | 1966-05-25 |
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