FR2158681A5 - Nitro paraffins prepn - by reaction of propane with nitrogen peroxide - Google Patents

Nitro paraffins prepn - by reaction of propane with nitrogen peroxide

Info

Publication number
FR2158681A5
FR2158681A5 FR7138744A FR7138744A FR2158681A5 FR 2158681 A5 FR2158681 A5 FR 2158681A5 FR 7138744 A FR7138744 A FR 7138744A FR 7138744 A FR7138744 A FR 7138744A FR 2158681 A5 FR2158681 A5 FR 2158681A5
Authority
FR
France
Prior art keywords
propane
reaction
prepn
peroxide
nitrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7138744A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Azote et Produits Chimiques SA
Original Assignee
Azote et Produits Chimiques SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Azote et Produits Chimiques SA filed Critical Azote et Produits Chimiques SA
Priority to FR7138744A priority Critical patent/FR2158681A5/en
Application granted granted Critical
Publication of FR2158681A5 publication Critical patent/FR2158681A5/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/08—Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Nitroparaffins are prepd. in gaseous phase by nitration of butane or propane by pure nitrogen peroxide at 180-320 degrees C pref. 200-240 degrees C where the reaction mixt. contains 8-20 vol.% pref. 10% peroxide and 80-92 vol.% propane. 5-15 vol.% oxygen may be present as catalyst. By-product No is converted to the peroxide for recycling. The reduction in temp. from above 350 degrees C when using HNO3 reduces the formation of nitriles resulting in higher yields.
FR7138744A 1971-10-28 1971-10-28 Nitro paraffins prepn - by reaction of propane with nitrogen peroxide Expired FR2158681A5 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7138744A FR2158681A5 (en) 1971-10-28 1971-10-28 Nitro paraffins prepn - by reaction of propane with nitrogen peroxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7138744A FR2158681A5 (en) 1971-10-28 1971-10-28 Nitro paraffins prepn - by reaction of propane with nitrogen peroxide

Publications (1)

Publication Number Publication Date
FR2158681A5 true FR2158681A5 (en) 1973-06-15

Family

ID=9085014

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7138744A Expired FR2158681A5 (en) 1971-10-28 1971-10-28 Nitro paraffins prepn - by reaction of propane with nitrogen peroxide

Country Status (1)

Country Link
FR (1) FR2158681A5 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4313010A (en) * 1978-11-14 1982-01-26 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Process for making nitroparaffins by nitration of ethane in the gaseous phase
US4313009A (en) * 1979-04-10 1982-01-26 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Process and installation for making nitroparaffins by nitration of hydrocarbons in the gaseous phase
CN114685279A (en) * 2020-12-25 2022-07-01 南京理工大学 Preparation method of short-chain nitroalkane

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4313010A (en) * 1978-11-14 1982-01-26 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Process for making nitroparaffins by nitration of ethane in the gaseous phase
US4313009A (en) * 1979-04-10 1982-01-26 Societe Chimique De La Grande Paroisse, Azote Et Produits Chimiques Process and installation for making nitroparaffins by nitration of hydrocarbons in the gaseous phase
CN114685279A (en) * 2020-12-25 2022-07-01 南京理工大学 Preparation method of short-chain nitroalkane

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