FR2120573A5 - Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns - Google Patents

Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns

Info

Publication number
FR2120573A5
FR2120573A5 FR7100584A FR7100584A FR2120573A5 FR 2120573 A5 FR2120573 A5 FR 2120573A5 FR 7100584 A FR7100584 A FR 7100584A FR 7100584 A FR7100584 A FR 7100584A FR 2120573 A5 FR2120573 A5 FR 2120573A5
Authority
FR
France
Prior art keywords
units
unsatd
contg
cpds
polymns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7100584A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7100584A priority Critical patent/FR2120573A5/en
Priority to JP369872A priority patent/JPS5444712B1/ja
Priority to DD16016671A priority patent/DD99805A1/xx
Priority to DD16647571A priority patent/DD99586A1/xx
Priority to GB46372A priority patent/GB1366550A/en
Priority to DE19722200405 priority patent/DE2200405C2/en
Priority to IT1911472A priority patent/IT946364B/en
Application granted granted Critical
Publication of FR2120573A5 publication Critical patent/FR2120573A5/en
Priority to US05/429,209 priority patent/US3931242A/en
Priority to US05/539,825 priority patent/US4051172A/en
Priority to US05/539,823 priority patent/US3980730A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Title cpds. of formula: (H3-nXn)C-CO2.M(CO)m(Rp(L)q r (I), where X is a halogen gp. contg. not 1 F-atoms; n is 1, 2 or o; M is Mo or W; R is H or an alkyl, alkenyl, aralkyl, aryl or cycloalkyl residue L is a Lewis base contg. not 1 ether and/or alcohol and/or ketone grouping; m is 1, 2, 3 or 4; p and q are 1 or 2; and r is a whole number, pref. 1 or 2), are prepd. by reacting a Mo or W carbonyl with a fluoroacetic acid ester in the presence of a Lewis base L, are useful as catalysts for stereospecific (co)polymsn. of unsatd. hydrocarbons. In particular (I) are useful in the prodn. of polybutadienes contg. high proportions of cis 1,4 and 1,2 units and practically no trans 1,4 units. New polymers prepd. by linear polymsn. of 1,3-butadiene with (I) have 55 - 85% vinyl 1,2 units, 45- 15% cis 1,4 units and 3% trans 1,4 units; a transition temp. into the glassy state between -25 and -80 degrees C; and an intrinsic viscosity (in toluene at 30 degrees C) of 1.0 dl/g.
FR7100584A 1971-01-08 1971-01-08 Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns Expired FR2120573A5 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR7100584A FR2120573A5 (en) 1971-01-08 1971-01-08 Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns
JP369872A JPS5444712B1 (en) 1971-01-08 1971-12-28
DD16647571A DD99586A1 (en) 1971-01-08 1971-12-30
DD16016671A DD99805A1 (en) 1971-01-08 1971-12-30
GB46372A GB1366550A (en) 1971-01-08 1972-01-05 Molybdenum and tungsten compounds their manufacture and theiruse as catalysts in the stereospecific polymerisation of unsaturated organic compounds
DE19722200405 DE2200405C2 (en) 1971-01-08 1972-01-05 Process for the polymerization of butadiene (1,3) and its catalyst for carrying out this process
IT1911472A IT946364B (en) 1971-01-08 1972-01-07 COMPOUNDS OF MOLYBDENUM AND TUNG STENUM THEIR PREPARATION AND THEIR USE AS CATALYSTS OF PO STEREOSPECIFICATION OF UNSATURATED ORGANIC COMPOUNDS
US05/429,209 US3931242A (en) 1971-01-08 1973-12-28 New molybdenum and tungsten compounds, their manufacture and their use as catalysts in the stereospecific polymerisation of unsaturated organic compounds
US05/539,825 US4051172A (en) 1971-01-08 1975-01-09 Molybdenum and tungsten compounds, their manufacture and their use as catalysts in the stereospecific polymerization of unsaturated organic compounds
US05/539,823 US3980730A (en) 1971-01-08 1975-01-09 Molybdenum and tungsten compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7100584A FR2120573A5 (en) 1971-01-08 1971-01-08 Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns

Publications (1)

Publication Number Publication Date
FR2120573A5 true FR2120573A5 (en) 1972-08-18

Family

ID=9070034

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7100584A Expired FR2120573A5 (en) 1971-01-08 1971-01-08 Organic molybdenum and tungsten catalyst cpds - for unsatd hydrocarbon polymns

Country Status (1)

Country Link
FR (1) FR2120573A5 (en)

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Legal Events

Date Code Title Description
ST Notification of lapse