FR2103122A5 - Dehydrogenation/dehydrocyclisation catalyst - of nickel/platinum metal-carrier type modified with indium/gallium oxide - Google Patents

Dehydrogenation/dehydrocyclisation catalyst - of nickel/platinum metal-carrier type modified with indium/gallium oxide

Info

Publication number
FR2103122A5
FR2103122A5 FR7126559A FR7126559A FR2103122A5 FR 2103122 A5 FR2103122 A5 FR 2103122A5 FR 7126559 A FR7126559 A FR 7126559A FR 7126559 A FR7126559 A FR 7126559A FR 2103122 A5 FR2103122 A5 FR 2103122A5
Authority
FR
France
Prior art keywords
dehydrogenation
indium
nickel
gallium oxide
carrier type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7126559A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Application granted granted Critical
Publication of FR2103122A5 publication Critical patent/FR2103122A5/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C07C5/324—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Catalyst based on carrier(s) (e.g. Al2O3, opt. treated with HF or hydrolysed in flame, SiO2, MgO, ZrO2, Al silicate or aluminate spinel of group II metal) and 0.01-5 wt. % metal (oxide) (e.g. Ni, Pt, Ru, Pd, IR, Rh, Os) also contains 0.1-10 wt. % (w.r.t. carrier) activity modifier, e.g. In or Ga oxide. This is used in dehydrogenation and dehydrocyclisation of org. cods. contg. CH-CH group(s), esp. paraffins. Modifier imparts improved activity and active life.
FR7126559A 1970-07-24 1971-07-20 Dehydrogenation/dehydrocyclisation catalyst - of nickel/platinum metal-carrier type modified with indium/gallium oxide Expired FR2103122A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5817870A 1970-07-24 1970-07-24

Publications (1)

Publication Number Publication Date
FR2103122A5 true FR2103122A5 (en) 1972-04-07

Family

ID=22015181

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7126559A Expired FR2103122A5 (en) 1970-07-24 1971-07-20 Dehydrogenation/dehydrocyclisation catalyst - of nickel/platinum metal-carrier type modified with indium/gallium oxide

Country Status (3)

Country Link
BE (1) BE770391A (en)
DE (1) DE2136487A1 (en)
FR (1) FR2103122A5 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2358194A1 (en) * 1976-07-12 1978-02-10 Kogan Samson Paraffin dehydrogenation to olefins - using catalyst contg. gallium, indium and/or thallium, added to platinum and alkali metal on alumina
EP0149293A1 (en) * 1984-01-18 1985-07-24 Engelhard Corporation Improved electrocatalyst and fuel cell electrode using the same
EP0183861A1 (en) * 1981-11-05 1986-06-11 Uop Inc. Indium-Containing Dehydrogenation Catalyst
TR22533A (en) * 1984-12-03 1987-10-12 Uop Inc INDIUM CONTAINING DEHIDROGENACIAL CATALIZOERUE
EP0564328A1 (en) * 1992-04-02 1993-10-06 Institut Francais Du Petrole Process for the selective hydrogenation of hydrocarbons
EP0564329A1 (en) * 1992-04-02 1993-10-06 Institut Francais Du Petrole Catalyst containing group VIII metal and group IIIA metal on a support
FR2724926A1 (en) * 1994-09-23 1996-03-29 Indo French Centre For The Pro Improved process for conversion of alkane(s) to alkene(s)
EP1533029A1 (en) * 2003-11-18 2005-05-25 Rohm And Haas Company Catalyst systems for converting Alkanes to Alkenes and to their corresponding oxygenated products

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE126156C (en) * 1976-06-24 1900-01-01
CN108786801B (en) * 2018-04-28 2021-01-05 钦州学院 Pt-based dehydrogenation catalyst and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2358194A1 (en) * 1976-07-12 1978-02-10 Kogan Samson Paraffin dehydrogenation to olefins - using catalyst contg. gallium, indium and/or thallium, added to platinum and alkali metal on alumina
EP0183861A1 (en) * 1981-11-05 1986-06-11 Uop Inc. Indium-Containing Dehydrogenation Catalyst
EP0149293A1 (en) * 1984-01-18 1985-07-24 Engelhard Corporation Improved electrocatalyst and fuel cell electrode using the same
TR22533A (en) * 1984-12-03 1987-10-12 Uop Inc INDIUM CONTAINING DEHIDROGENACIAL CATALIZOERUE
EP0564328A1 (en) * 1992-04-02 1993-10-06 Institut Francais Du Petrole Process for the selective hydrogenation of hydrocarbons
EP0564329A1 (en) * 1992-04-02 1993-10-06 Institut Francais Du Petrole Catalyst containing group VIII metal and group IIIA metal on a support
FR2689517A1 (en) * 1992-04-02 1993-10-08 Inst Francais Du Petrole Process for the selective hydrogenation of hydrocarbons.
FR2689419A1 (en) * 1992-04-02 1993-10-08 Inst Francais Du Petrole Catalyst containing a group VIII metal and a group III metal deposited on a support, applicable to the selective hydrogenation of hydrocarbons.
US5356851A (en) * 1992-04-02 1994-10-18 Institut Francais Du Petrole Catalyst containing a group VIII metal and a group IIIA metal deposited on a support
US5364998A (en) * 1992-04-02 1994-11-15 Institut Francais Du Petrole Process for the selective hydrogenation of hydrocarbons
FR2724926A1 (en) * 1994-09-23 1996-03-29 Indo French Centre For The Pro Improved process for conversion of alkane(s) to alkene(s)
EP1533029A1 (en) * 2003-11-18 2005-05-25 Rohm And Haas Company Catalyst systems for converting Alkanes to Alkenes and to their corresponding oxygenated products

Also Published As

Publication number Publication date
DE2136487A1 (en) 1972-01-27
BE770391A (en) 1972-01-24

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