FI964099A0 - Olefiinipolymeerien ja aromaattisten monovinylideenipolymeerien sopeutepitoinen seos - Google Patents

Olefiinipolymeerien ja aromaattisten monovinylideenipolymeerien sopeutepitoinen seos

Info

Publication number
FI964099A0
FI964099A0 FI964099A FI964099A FI964099A0 FI 964099 A0 FI964099 A0 FI 964099A0 FI 964099 A FI964099 A FI 964099A FI 964099 A FI964099 A FI 964099A FI 964099 A0 FI964099 A0 FI 964099A0
Authority
FI
Finland
Prior art keywords
olefin
interpolymer
polymers
polymer blend
weight
Prior art date
Application number
FI964099A
Other languages
English (en)
Swedish (sv)
Other versions
FI964099A (fi
Inventor
Chung P Park
George P Clingerman
Francis J Timmers
James C Stevens
David E Henton
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of FI964099A publication Critical patent/FI964099A/fi
Publication of FI964099A0 publication Critical patent/FI964099A0/fi

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
FI964099A 1994-04-12 1996-10-11 Olefiinipolymeerien ja aromaattisten monovinylideenipolymeerien sopeutepitoinen seos FI964099A0 (fi)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/226,533 US5460818A (en) 1994-04-12 1994-04-12 Compatibilized blend of olefinic polymers and monovinylidene aromatic polymers
PCT/US1995/004314 WO1995027755A1 (en) 1994-04-12 1995-04-12 Compatibilized blend of olefinic polymers and monovinylidene aromatic polymers

Publications (2)

Publication Number Publication Date
FI964099A FI964099A (fi) 1996-10-11
FI964099A0 true FI964099A0 (fi) 1996-10-11

Family

ID=22849299

Family Applications (1)

Application Number Title Priority Date Filing Date
FI964099A FI964099A0 (fi) 1994-04-12 1996-10-11 Olefiinipolymeerien ja aromaattisten monovinylideenipolymeerien sopeutepitoinen seos

Country Status (14)

Country Link
US (1) US5460818A (fi)
EP (1) EP0755418B1 (fi)
JP (1) JPH09512038A (fi)
KR (1) KR970702324A (fi)
CN (1) CN1146211A (fi)
AT (1) ATE182913T1 (fi)
AU (1) AU2281195A (fi)
BR (1) BR9507455A (fi)
CA (1) CA2187640A1 (fi)
DE (1) DE69511258T2 (fi)
ES (1) ES2136846T3 (fi)
FI (1) FI964099A0 (fi)
RU (1) RU2144549C1 (fi)
WO (1) WO1995027755A1 (fi)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
TW408155B (en) * 1989-08-31 2000-10-11 Dow Chemical Co Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers
US6087447A (en) * 1989-08-31 2000-07-11 The Dow Chemical Company Blends of substantially random interpolymers with vinyl or vinylidene aromatic polymers
US5869591A (en) * 1994-09-02 1999-02-09 The Dow Chemical Company Thermoset interpolymers and foams
US6884480B2 (en) 1995-05-19 2005-04-26 Cryovac, Inc. Film containing alpha-olefin/vinyl aromatic copolymer
ES2151244T3 (es) 1996-03-05 2000-12-16 Dow Chemical Co Composicion de moldeo que contiene un polimero vinilaromatico sindiotactico.
TW412560B (en) * 1996-09-04 2000-11-21 Dow Chemical Co Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape
ZA977908B (en) * 1996-09-04 1999-03-03 Dow Chemical Co Blends of alpha-olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers
BR9612724A (pt) * 1996-09-04 2002-05-21 Dow Chemical Co Misturas contendo um interpolìmero de alfa-olefina e produtos obtidos destas
BR9712009A (pt) * 1996-09-04 2000-01-18 Dow Chemical Co Revestimento para piso, parede ou teto.
US5741857A (en) * 1996-10-15 1998-04-21 The Dow Chemical Company Blends of elastomer block copolymer and aliphatic α-olefin/monovinylidene aromatic monomer and/or hindered aliphatic vinylidene monomer interpolymer
US5739200A (en) * 1996-12-17 1998-04-14 The Dow Chemical Company Plasticizied α-olefin/vinylidene aromatic monomer of hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers
US5973049A (en) * 1997-06-26 1999-10-26 The Dow Chemical Company Filled polymer compositions
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US5889069A (en) * 1997-07-15 1999-03-30 The Dow Chemical Company High temperature syndiotactic styrene polymer foam
CA2305380A1 (en) * 1997-09-29 1999-04-22 National Research Council Of Canada Trivalent thrombin inhibitor
US6136923A (en) * 1997-10-15 2000-10-24 The Dow Chemical Company Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride
CN1276812A (zh) 1997-10-17 2000-12-13 陶氏化学公司 α－烯烃单体与一种或多种乙烯基或亚乙烯基芳族单体的共聚体的组合物
US6027800A (en) * 1997-12-19 2000-02-22 Basf Corporation High impact resistant, high gloss, and high environmental stress crack resistant thermoplastic manufactured articles
US6380305B1 (en) 1997-12-19 2002-04-30 Basf Corporation High impact resistant, high gloss, and high environmental stress crack resistant polymeric compositions
AU2746599A (en) * 1998-03-09 1999-09-27 Denki Kagaku Kogyo Kabushiki Kaisha Medical material and medical supply
US6329450B1 (en) 1998-03-11 2001-12-11 The Dow Chemical Company Thermoplastic compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers blended with engineering thermoplastics
AU2854299A (en) * 1998-03-23 1999-10-18 Denki Kagaku Kogyo Kabushiki Kaisha Resin composition
US6124406A (en) 1998-03-31 2000-09-26 The B. F. Goodrich Company Blocky chlorinated polyolefins, process for making and use as impact modifier compatibilizer for PVC or CPVC
US6069183A (en) * 1998-04-07 2000-05-30 Tenneco Packaging Inc. Foamable composition using high density polyethylene
US6225363B1 (en) 1998-04-07 2001-05-01 Pactiv Corporation Foamable composition using high density polyethylene
BR9913436A (pt) * 1998-08-28 2001-05-22 Dow Chemical Co Espuma de mistura de polìmeros
DE19983482B4 (de) * 1998-09-09 2006-09-28 Asahi Kasei Chemicals Corp. Verwendung von kompatibilisierten Harzzusammensetzungen für Flüssigkeitsbehälter eines Gefrierschutzsystems
US6231795B1 (en) * 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
CA2372217A1 (en) * 1999-04-30 2000-11-09 Wenbin Liang Film with enhanced performance properties
US6365658B1 (en) 1999-08-12 2002-04-02 The Dow Chemical Company Polymer compositions
US6277915B1 (en) 1999-09-29 2001-08-21 Pmd Holdings Corporation Block chlorinated polyolefins for use as impact modifier enhancers for PVC or CPVC
US6417276B2 (en) 2000-01-07 2002-07-09 The Dow Chemical Company Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil
WO2001053410A1 (en) * 2000-01-19 2001-07-26 The Dow Chemical Company Acoustical insulating foam from compatibilized blends of vinyl aromatic polymers and alpha-olefin polymers
CN100432127C (zh) 2000-03-17 2008-11-12 陶氏环球技术公司 大孔声学泡沫及其用途
KR20030028805A (ko) 2000-07-20 2003-04-10 다우 글로벌 테크놀로지스 인크. 알케닐 방향족 중합체와 알파-올레핀/비닐 또는 비닐리덴방향족 인터폴리머와의 블렌드로부터의 발포체 조성물
US20020111389A1 (en) * 2000-08-14 2002-08-15 Chaudhary Bharat I. Dimenssionally stable foam made from compatiblized blends of poly (vinly aromatic) polymers and poly (alpha-olefin) polymers for cushion packaging applications
US20020061976A1 (en) * 2000-09-15 2002-05-23 Krabbenborg Franciscus J.T. Propylene polymer composition
EP1370607A2 (en) * 2001-02-27 2003-12-17 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
US6894102B2 (en) * 2002-05-20 2005-05-17 General Electric Syndiotactic polystyrene blends
US7045556B2 (en) * 2002-07-02 2006-05-16 Pactiv Corporation Polyolefin foams made with isopentane-based blowing agents
US7166248B2 (en) * 2003-01-03 2007-01-23 Pactiv Corporation Reduced VOC emission alkenyl aromatic polymer foams and processes
EP1612239B1 (en) * 2003-04-04 2012-04-25 Sekisui Plastics Co., Ltd. Expandable styrene-modified olefin resin particles, pre-expanded particles, and method for producing an expanded molded article
US7358282B2 (en) 2003-12-05 2008-04-15 Kimberly-Clark Worldwide, Inc. Low-density, open-cell, soft, flexible, thermoplastic, absorbent foam and method of making foam
US7361694B2 (en) * 2004-02-27 2008-04-22 Dow Global Technologies Inc. Durable foam of olefin polymers, methods of making foam and articles prepared from same
US7291382B2 (en) 2004-09-24 2007-11-06 Kimberly-Clark Worldwide, Inc. Low density flexible resilient absorbent open-cell thermoplastic foam
US8158689B2 (en) 2005-12-22 2012-04-17 Kimberly-Clark Worldwide, Inc. Hybrid absorbent foam and articles containing it
ES2467467T3 (es) * 2007-02-07 2014-06-12 Lg Chem, Ltd. Composición de resina de estireno de bajo brillo superficial y elemento laminar de bajo brillo superficial y artículo compuesto fabricado a base de la misma
US8202528B2 (en) * 2007-06-05 2012-06-19 Abbott Cardiovascular Systems Inc. Implantable medical devices with elastomeric block copolymer coatings
WO2011131322A1 (en) * 2010-04-21 2011-10-27 Basell Polyolefine Gmbh Polymer blend having improved mechanical properties
WO2011143014A2 (en) * 2010-05-13 2011-11-17 Dow Global Technologies Llc Styrene-acrylonitrile copolymer foam with minimal yellowing
US20130087361A1 (en) * 2011-10-11 2013-04-11 Hitachi Cable, Ltd. Foamed resin composition, wire and cable
ES2688532T3 (es) 2013-01-18 2018-11-05 Basf Se Composiciones de recubrimiento a base de dispersión acrílica

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3117946A (en) * 1960-01-04 1964-01-14 Union Carbide Corp Compositions comprising ethylene homopolymer and ethylene-styrene copolymer and method of preparing same
US3117945A (en) * 1960-01-04 1964-01-14 Union Carbide Corp Compositions comprising styrene homopolymer and styrene-ethylene copolymer and method therefor
US4031166A (en) * 1970-01-29 1977-06-21 Badische Anilin- & Soda-Fabrik Aktiengesellschaft Impact-resistant polystyrene, α-olefin, block copolymer blends
BE776346A (fr) * 1970-12-12 1972-06-07 Basf Ag Matieres a mouler thermoplastiques
FR2120302A5 (fi) * 1970-12-29 1972-08-18 Aquitaine Total Organico
JPS5327744B2 (fi) * 1971-09-30 1978-08-10
US3851015A (en) * 1972-02-17 1974-11-26 Aquitaine Petrole Method for copolymerizing monomers of different types
JPS4928637A (fi) * 1972-07-12 1974-03-14
US4020025A (en) * 1973-05-08 1977-04-26 Basf Aktiengesellschaft Extrudable foamable composition comprising an olefin polymer, a styrene polymer and a hydrogenated styrene butadiene block copolymer
US4188432A (en) * 1978-03-30 1980-02-12 Shell Oil Company Articles resistant to attack by fatty substances, made from polystyrene blends, and compositions
JPS5636534A (en) * 1979-09-03 1981-04-09 Asahi Chem Ind Co Ltd Thermoplastic resin composition
JPS5638338A (en) * 1979-09-06 1981-04-13 Asahi Chem Ind Co Ltd Thermoplastic resin composition
US4386187A (en) * 1980-06-11 1983-05-31 Sweetheart Plastics, Inc. Thermoformable polymer blend composition comprising styrene polymer, olefin polymer and block copolymer
US4386188A (en) * 1981-01-16 1983-05-31 Sweetheart Plastics, Inc. Thermoformable polymer blend composition
IT1167713B (it) * 1981-03-12 1987-05-13 Montefina Sa Gomma termoplastica costituita da miscela di polipropilene, polistirene antiurto e copolimero a blocchi stirene/diene
IT1167712B (it) * 1981-03-12 1987-05-13 Montefina Sa Materiale polimerico costituito da una miscela di polistirene antiurto, polietilene alta densita' e copolimero a blocchi stirene/diene
US4690976A (en) * 1983-08-01 1987-09-01 The Dow Chemical Company Blends of olefinic and monovinylidene aromatic polymers
US4716197A (en) * 1986-04-21 1987-12-29 The Dow Chemical Company Polyethylene/EPDM-graft polystyrene blends
CA2028120A1 (en) * 1989-03-20 1990-09-21 Toshinori Tazaki Styrene copolymer and process for production thereof

Also Published As

Publication number Publication date
ATE182913T1 (de) 1999-08-15
EP0755418B1 (en) 1999-08-04
FI964099A (fi) 1996-10-11
AU2281195A (en) 1995-10-30
RU2144549C1 (ru) 2000-01-20
KR970702324A (ko) 1997-05-13
DE69511258T2 (de) 1999-12-02
CN1146211A (zh) 1997-03-26
WO1995027755A1 (en) 1995-10-19
CA2187640A1 (en) 1995-10-19
JPH09512038A (ja) 1997-12-02
EP0755418A1 (en) 1997-01-29
DE69511258D1 (de) 1999-09-09
US5460818A (en) 1995-10-24
ES2136846T3 (es) 1999-12-01
BR9507455A (pt) 1997-09-02

Similar Documents

Publication Publication Date Title
FI964099A0 (fi) Olefiinipolymeerien ja aromaattisten monovinylideenipolymeerien sopeutepitoinen seos
GB2319985B (en) Microcellular foam plank
IE811283L (en) Thermoformable polymer blend composition
MY130853A (en) Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin /vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
KR910018420A (ko) 프로필렌 공중합체를 상온 성형시키는 방법
DE60116490D1 (de) Heisssiegelbare polyethylenfolie und verfahren zu ihrer herstellung
NO970117D0 (no) Dynamisk vulkaniserbare polyolefinmaterialer og fremgangsmåte for fremstilling av slike
AU3457589A (en) Process for making 1,3-dioxane derivatives
DE3172306D1 (en) Expandable polyolefin compositions and polyolefin foam preparation process
EP0841354A4 (en) MODIFIED POLYPROPYLENE RESIN FOAM AND PROCESS FOR PRODUCING THE SAME
GB867468A (en) Flame retardant and/or self-extinguishing polymers and method for their production
US4331777A (en) Foaming synthetic resin compositions stabilized with certain naphthyl amine compounds
MY115606A (en) Molding compositions containing syndiotactic monovinylidene aromatic polymer
FI990459A (fi) Alfa-olefiinin kopolymeeriä sisältäviä seoksia
DK0602262T3 (da) Baneformede skumplastplader af polyolefiner
HU9201897D0 (en) Method for producing plastic foams having spatial net structure
ATE134675T1 (de) Expandierbare styrolpolymerisate und daraus hergestellte aromatenbeständige schaumstoffe
EP0753529A3 (en) Cross-linked atactic or amorphous propylene polymers
ES2042100T3 (es) Polimeros de estireno expansibles y procedimiento para su fabricacion.
EP0014539A3 (en) Controlled tackiness in epm/ldpe blends
CA2056248A1 (en) Process for making molded polymeric product with multipass expansion of polymer bead with low blowing agent content
GB1013378A (en) Foamable and foamed thermoplastic styrene polymers
TH24051A (fi)
MX9602709A (es) Polimeros de propileno atacticos o amorfos, reticulados.
CA2237914A1 (en) Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof