FI81107B - Foerfarande foer framstaellning av utvecklade epoxihartser innehaollande triazin- eller baode triazin- och oxazolingrupper. - Google Patents
Foerfarande foer framstaellning av utvecklade epoxihartser innehaollande triazin- eller baode triazin- och oxazolingrupper. Download PDFInfo
- Publication number
- FI81107B FI81107B FI854029A FI854029A FI81107B FI 81107 B FI81107 B FI 81107B FI 854029 A FI854029 A FI 854029A FI 854029 A FI854029 A FI 854029A FI 81107 B FI81107 B FI 81107B
- Authority
- FI
- Finland
- Prior art keywords
- groups
- group
- triazine
- epoxy
- mixture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/30—Only oxygen atoms
- C07D251/34—Cyanuric or isocyanuric esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/26—Di-epoxy compounds heterocyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3236—Heterocylic compounds
- C08G59/3245—Heterocylic compounds containing only nitrogen as a heteroatom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Epoxy Resins (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Tea And Coffee (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Claims (8)
1. Förfarande för framställning av konventiolla epoxikonstruktionshartser, vilka innehäller triazingrupper 5 eller triazin- och oxazolingrupper, känneteck- n a t därav, att man omsätter (A) (1) ätminstone en hydro-xiaromatisk oligomer, vilken innehäller minst en tri-azingrupp, eller (2) ätminstone en hydroxiaromatisk oligomer, vilken innehäller minst en triazingrupp och minst en 10 oxazolingrupp, eller (3) en blandning av (1) och (2), med (B) ätminstone ett ämne, vilket i genomsnitt innehäller mer än en 1,2-epoxigrupp per molekyl, varvid komponenterna är närvarande i sädana mängder, att förhällandet av feno-liska hydroxylgrupper tili epoxigrupper är 0,1:1-1:1. 15 2. Förfarande enligt patentkravet 1, känne- t e c k n a t därav, att epoxigrupperna i komponenten (B) utgörs av glycidyletergrupper och att komponenterna om-sätts i sädana mängder, att förhällandet av fenoliska hyd-roxylgrupper tili epoxigrupper är 0,1:1-0,5:1. 20 3. Förfarande enligt patentkravet 1, känne- t e c k n a t därav, att komponenten (B) utgörs av en di-glycidyleter av en förening, vilken innehäller flera fenoliska hydroxylgrupper.
4. Förfarande enligt patentkravet 3, känne-25 tecknat därav, att komponenten (B) utgörs av en gly-cidyleter med formeln IV, V eller VI, eller en blandning av dylika glycidyletrar 30 II 35 23 81 1 07 / _ OH x R °xch2 (R’)x (R’)x (Κ·)χ (R,)x 5 v· @-ch2-/^ (o)— ™\-^Q) 10 ? ? I ? ™2 \ CH2 / CH2 O^C-R" \ 0^C-R" / /C-R" ^CH2 \ XCH / °'-CH 1 n" l 15 VI*A Λ H2C-?_H2C-° tA~T“C -K^J- 0-CH2-C-CH2 R" R" Φ . ! /\ O-CH -C-CH 2 f 2 R" 25. vilka formler A är en tvävärdig hydroxigrupp med 1-12 kolatomer 0 0 0 o Il II II II -s-, -s-s-, -s-, -s-, -c-, -o-c-o-, -o-, II 30 ° if%0' W)r x R ym' R m R1 m- 35 /V\ \ J m' 24 81 1 07 varje R' betecknar självständigt väte en kolvätegrupp med 1-6 kolatomer eller halogen, företrädersvis klor, eller brom; varje R" betecknar självständigt väte eller en kol-vätegrupp med 1-3 kolatomer, x är 0-4, n är 0 eller 1; n" 5 är 0-100; och m' är 1-100.
5. Förfarande enligt patentkravet 4, känne- t e c k n a t därav, att komponenten (B) utgörs av en di-glycidyleter av bisfenol A.
6. Förfarande enligt patentkravet 1, känne-10 tecknad därav, att komponenten (A-l), ifall närva- rande, erhälls genom att i närvaro av en lämplig trimeri-seringskatalysator trimerisera en produkt, vilken fram-ställs genom att omsätta ett ämne, vilket innehäller i genomsnitt flera än en aromatisk hydroxylgrupp per mole-15 kyl, med minst 0,01 men högst 0,95 mol av en cyanhalogenid per aromatisk hydroxylgrupp i närvaro av en lämplig bas i en mängd av 0,01-1,1 mol per aromatisk hydroxylgrupp, att komponenten (A-2), ifall närvarande, framställs genom att i närvaro av en lämplig katalysator samoligomerisera ät-20 minstone ett ämne innehällande minst en 1,2-epoxigrupp per molekyl, och att den produkt, vilken erhälls genom reaktion av ett ämne innehällande i genomsnitt flera än en aromatisk hydroxylgrupp per molekyl, med minst 0,01 men högst 0,95 mol av en cyanhalogenid per aromatisk hyd-25 roxylrupp i närvaro av en lämplig bas i en mängd av 0,01- 1,1 mol per aromatisk hydroxylgrupp.
7. Förfarande enligt patentkravet 6, känne-t e c k n a t därav, att det material, vilket i genomsnitt innehäller flera än en fenolisk hydroxylgrupp per 30 molekyl utgörs av en förening med formeln I, II eller III, eller en blandning av dessa il 35 811 07 OH I. m—OH °« OH
11 R’ (A)n-*’ R R'
10 OH s 0H Je^Y—^-7" 'R1 « 15. vilka formler A, R' och n har sanuna betydelse som i pa-tentkravet 4, A' är en tvävärdig kolvätegrupp med 1-3 kol-atomer; R är väte, halogen, företrädesvis klor eller brom, en kolvätegrupp med 1-6 kolatomer eller en hydroxylgrupp; n' är 1,01-6 och m är 0-2 att det ämne, vilket i ge-20 nomsnitt innehäller flera är en epoxlgrupp per molekyl, utgörs av en förening med den i patentkrav 4 angivna for-meln IV, V eller VI, eller en av blandning av dessa; och att cyanhalogeniden används i en mängd av 0,05-0,55 mol per aromatisk hydroxylgrupp. 25 8. Förfarande enligt patentkravet 7, känne- t e c k n a d därav, att varje epoxiharts utgörs av en di-glycidyleter av bisfenol A och att cyanhalogeniden utgörs av cyanklorid. 30 35
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US58241584 | 1984-02-22 | ||
US06/582,415 US4506063A (en) | 1984-02-22 | 1984-02-22 | Advanced epoxy resins containing triazine or both triazine and oxazoline groups |
PCT/US1984/001722 WO1985003711A1 (en) | 1984-02-22 | 1984-10-25 | A process for preparing advanced epoxy resins containing triazine or both triazine and oxazoline groups |
US8401722 | 1984-10-25 |
Publications (4)
Publication Number | Publication Date |
---|---|
FI854029L FI854029L (fi) | 1985-10-16 |
FI854029A0 FI854029A0 (fi) | 1985-10-16 |
FI81107B true FI81107B (fi) | 1990-05-31 |
FI81107C FI81107C (sv) | 1990-09-10 |
Family
ID=24329059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FI854029A FI81107C (sv) | 1984-02-22 | 1985-10-16 | Förfarande för framställning av utvecklade epoxihartser innehållande t riazin- eller både triazin- och oxazolingrupper |
Country Status (17)
Country | Link |
---|---|
US (1) | US4506063A (sv) |
EP (1) | EP0153449B1 (sv) |
JP (1) | JPS61500124A (sv) |
KR (1) | KR880002237B1 (sv) |
AT (1) | ATE37035T1 (sv) |
AU (1) | AU555523B2 (sv) |
BR (1) | BR8407284A (sv) |
CA (1) | CA1236632A (sv) |
DE (1) | DE3473882D1 (sv) |
DK (1) | DK484985D0 (sv) |
ES (1) | ES8802168A1 (sv) |
FI (1) | FI81107C (sv) |
IL (1) | IL73358A (sv) |
NO (1) | NO163231C (sv) |
NZ (1) | NZ210041A (sv) |
WO (1) | WO1985003711A1 (sv) |
ZA (1) | ZA848469B (sv) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT380264B (de) * | 1984-10-22 | 1986-05-12 | Vianova Kunstharz Ag | Verfahren zur herstellung von bindemitteln fuer pigmentpasten fuer wasserverduennbare lacke |
US4546131A (en) * | 1985-01-15 | 1985-10-08 | The Dow Chemical Company | Polymer modified cyanate mixture and epoxy resins thereof |
US4665149A (en) * | 1985-11-08 | 1987-05-12 | The Dow Chemical Company | Triazine containing epoxy resins having improved thermal stability |
US4663398A (en) * | 1986-02-24 | 1987-05-05 | The Dow Chemical Company | Co-oligomerization product of a mixed cyanate and a polymaleimide and epoxy resins thereof |
US4661553A (en) * | 1986-02-24 | 1987-04-28 | The Dow Chemical Company | Vinyl esters of polyepoxides of polyphenol cyanate mixture and polymaleimide co-oligomers |
US5108270A (en) * | 1990-07-27 | 1992-04-28 | The Aro Corporation | Conductive plastic fluid handling equipment |
US5912308A (en) * | 1994-11-30 | 1999-06-15 | Alliedsignal Inc. | Multifunctional cyanate ester and epoxy blends |
WO2012017894A1 (ja) | 2010-08-05 | 2012-02-09 | 日産化学工業株式会社 | シアヌル酸骨格を有するエポキシ化合物の製造方法 |
CN111825829B (zh) * | 2020-01-07 | 2022-05-13 | 大连理工大学 | 一种含三嗪环结构的生物基环氧树脂及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2506486A (en) * | 1948-04-21 | 1950-05-02 | Union Carbide & Carbon Corp | Thermosetting resin from a diphenol and a diglycidyl ether of a diphenol |
US2810706A (en) * | 1953-07-01 | 1957-10-22 | American Cyanamid Co | Oxirane triazine resinous compositions and processes of preparing the same |
US2741607A (en) * | 1954-02-23 | 1956-04-10 | Shell Dev | Triglycidyl cyanurate and polymers thereof |
US2809942A (en) * | 1955-10-21 | 1957-10-15 | Devoe & Raynolds Co | Process for making polyglycidyl cyanurates |
US2864805A (en) * | 1955-12-05 | 1958-12-16 | Devoe & Raynolds Co | Epoxide resins |
US2971942A (en) * | 1956-10-01 | 1961-02-14 | Devoe & Raynolds Co | Epoxide resins |
NL225837A (sv) * | 1957-05-02 | |||
US3145207A (en) * | 1960-09-12 | 1964-08-18 | American Cyanamid Co | Process for preparing epoxy alkyloxymethylamino-s-triazines |
US3334110A (en) * | 1965-08-16 | 1967-08-01 | Baker Chem Co J T | Method for preparing epoxyoxazolidinones |
US3413377A (en) * | 1965-12-21 | 1968-11-26 | Baker Chem Co J T | Resins of poly(epoxyalkyl-2-oxazolidinone), phenolic based polyepoxides and monoepoxy compounds |
GB1243003A (en) * | 1967-10-26 | 1971-08-18 | Ciba Ltd | Epoxides containing nitrogen and sulphur, and processes for their production |
US3477990A (en) * | 1967-12-07 | 1969-11-11 | Shell Oil Co | Process for reacting a phenol with an epoxy compound and resulting products |
CH500247A (de) * | 1968-04-17 | 1970-12-15 | Ciba Geigy Ag | Verfahren zur Herstellung von neuen epoxidgruppenhaltigen Addukten aus Polyepoxidverbindungen und zweikernigen N-heterocyclischen Verbindungen |
US3676397A (en) * | 1970-10-12 | 1972-07-11 | Dow Chemical Co | Oxazolidinone-containing epoxy resins and process for their preparation |
DE2115854C3 (de) * | 1971-04-01 | 1978-10-05 | Henkel Kgaa, 4000 Duesseldorf | Verfahren zur Herstellung von noch vernetzungsfähigen Addukten aus Triglycidylisocyanurat |
JPS505649A (sv) * | 1973-05-25 | 1975-01-21 | ||
JPS5847422B2 (ja) * | 1977-10-04 | 1983-10-22 | 三菱電機株式会社 | 熱硬化性樹脂材料 |
JPS5626925A (en) * | 1979-08-10 | 1981-03-16 | Sumitomo Chem Co Ltd | Production of epoxy resin |
JPS5874720A (ja) * | 1981-10-30 | 1983-05-06 | Hitachi Ltd | 耐熱性樹脂の製法 |
US4393181A (en) * | 1982-06-30 | 1983-07-12 | Shell Oil Company | Polyfunctional phenolic-melamine epoxy resin curing agents |
-
1984
- 1984-02-22 US US06/582,415 patent/US4506063A/en not_active Expired - Fee Related
- 1984-10-25 KR KR1019850700265A patent/KR880002237B1/ko not_active IP Right Cessation
- 1984-10-25 WO PCT/US1984/001722 patent/WO1985003711A1/en active IP Right Grant
- 1984-10-25 AU AU35547/84A patent/AU555523B2/en not_active Ceased
- 1984-10-25 JP JP59503962A patent/JPS61500124A/ja active Granted
- 1984-10-25 BR BR8407284A patent/BR8407284A/pt unknown
- 1984-10-26 CA CA000466384A patent/CA1236632A/en not_active Expired
- 1984-10-30 IL IL73358A patent/IL73358A/xx unknown
- 1984-10-30 DE DE8484113038T patent/DE3473882D1/de not_active Expired
- 1984-10-30 NZ NZ210041A patent/NZ210041A/xx unknown
- 1984-10-30 ZA ZA848469A patent/ZA848469B/xx unknown
- 1984-10-30 EP EP84113038A patent/EP0153449B1/en not_active Expired
- 1984-10-30 AT AT84113038T patent/ATE37035T1/de not_active IP Right Cessation
- 1984-10-30 ES ES537221A patent/ES8802168A1/es not_active Expired
-
1985
- 1985-10-16 FI FI854029A patent/FI81107C/sv not_active IP Right Cessation
- 1985-10-21 NO NO85854180A patent/NO163231C/no unknown
- 1985-10-22 DK DK484985A patent/DK484985D0/da not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
DK484985A (da) | 1985-10-22 |
NZ210041A (en) | 1988-07-28 |
ZA848469B (en) | 1986-06-25 |
FI81107C (sv) | 1990-09-10 |
FI854029L (fi) | 1985-10-16 |
IL73358A (en) | 1988-02-29 |
US4506063A (en) | 1985-03-19 |
NO854180L (no) | 1985-10-21 |
DE3473882D1 (en) | 1988-10-13 |
WO1985003711A1 (en) | 1985-08-29 |
JPH0155655B2 (sv) | 1989-11-27 |
BR8407284A (pt) | 1986-02-18 |
EP0153449A3 (en) | 1985-12-27 |
EP0153449B1 (en) | 1988-09-07 |
AU555523B2 (en) | 1986-09-25 |
EP0153449A2 (en) | 1985-09-04 |
FI854029A0 (fi) | 1985-10-16 |
NO163231B (no) | 1990-01-15 |
JPS61500124A (ja) | 1986-01-23 |
ES537221A0 (es) | 1988-04-01 |
KR880002237B1 (ko) | 1988-10-20 |
ES8802168A1 (es) | 1988-04-01 |
DK484985D0 (da) | 1985-10-22 |
AU3554784A (en) | 1985-09-10 |
CA1236632A (en) | 1988-05-10 |
KR850700249A (ko) | 1985-12-26 |
IL73358A0 (en) | 1985-01-31 |
ATE37035T1 (de) | 1988-09-15 |
NO163231C (no) | 1990-04-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM | Patent lapsed |
Owner name: THE DOW CHEMICAL COMPANY |