FI61642C - Vattenloesning vilken aer laemplig saosom samlarloesning vid tillvaratagning av koppar fraon sulfidmalmer - Google Patents
Vattenloesning vilken aer laemplig saosom samlarloesning vid tillvaratagning av koppar fraon sulfidmalmer Download PDFInfo
- Publication number
- FI61642C FI61642C FI752067A FI752067A FI61642C FI 61642 C FI61642 C FI 61642C FI 752067 A FI752067 A FI 752067A FI 752067 A FI752067 A FI 752067A FI 61642 C FI61642 C FI 61642C
- Authority
- FI
- Finland
- Prior art keywords
- solution
- thionocarbamate
- sodium
- compound
- aqueous solution
- Prior art date
Links
- 239000000725 suspension Substances 0.000 title 2
- 239000000243 solution Substances 0.000 claims description 51
- 239000007864 aqueous solution Substances 0.000 claims description 28
- 239000010949 copper Substances 0.000 claims description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 23
- 229910052802 copper Inorganic materials 0.000 claims description 23
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- -1 alkali metal salt Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 description 22
- 239000000203 mixture Substances 0.000 description 17
- 239000003153 chemical reaction reagent Substances 0.000 description 14
- RTXYXJGGTDHOGH-UHFFFAOYSA-N o-propan-2-yl n-methylcarbamothioate Chemical compound CNC(=S)OC(C)C RTXYXJGGTDHOGH-UHFFFAOYSA-N 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- RIJDNATVAMLZRB-UHFFFAOYSA-M sodium;oxido-propan-2-yloxy-propan-2-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)OP([O-])(=S)SC(C)C RIJDNATVAMLZRB-UHFFFAOYSA-M 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- 239000012991 xanthate Substances 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 7
- PVOYFKUVGNEGHT-UHFFFAOYSA-N o-(2-methylpropyl) n-methylcarbamothioate Chemical compound CNC(=S)OCC(C)C PVOYFKUVGNEGHT-UHFFFAOYSA-N 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 150000002898 organic sulfur compounds Chemical class 0.000 description 6
- 230000036515 potency Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005188 flotation Methods 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 150000003464 sulfur compounds Chemical class 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229940125904 compound 1 Drugs 0.000 description 4
- 229940125782 compound 2 Drugs 0.000 description 4
- 229940126214 compound 3 Drugs 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- KIACEOHPIRTHMI-UHFFFAOYSA-N o-propan-2-yl n-ethylcarbamothioate Chemical compound CCNC(=S)OC(C)C KIACEOHPIRTHMI-UHFFFAOYSA-N 0.000 description 4
- FOYPFIDVYRCZKA-UHFFFAOYSA-M sodium;bis(2-methylpropoxy)-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Na+].CC(C)COP([S-])(=S)OCC(C)C FOYPFIDVYRCZKA-UHFFFAOYSA-M 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- YZLQFRKSOZCHCJ-UHFFFAOYSA-M sodium;3-methylbutoxy-(3-methylbutylsulfanyl)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)CCOP([O-])(=S)SCCC(C)C YZLQFRKSOZCHCJ-UHFFFAOYSA-M 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229940125898 compound 5 Drugs 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 238000011176 pooling Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- VVTVDXPOGQYVFX-UHFFFAOYSA-M sodium;bis(2-methylpropoxy)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)COP([O-])(=S)OCC(C)C VVTVDXPOGQYVFX-UHFFFAOYSA-M 0.000 description 2
- ZKDDJTYSFCWVGS-UHFFFAOYSA-M sodium;diethoxy-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Na+].CCOP([S-])(=S)OCC ZKDDJTYSFCWVGS-UHFFFAOYSA-M 0.000 description 2
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- YIBBMDDEXKBIAM-UHFFFAOYSA-M potassium;pentoxymethanedithioate Chemical compound [K+].CCCCCOC([S-])=S YIBBMDDEXKBIAM-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- RZFBEFUNINJXRQ-UHFFFAOYSA-M sodium ethyl xanthate Chemical compound [Na+].CCOC([S-])=S RZFBEFUNINJXRQ-UHFFFAOYSA-M 0.000 description 1
- FLVLHHSRQUTOJM-UHFFFAOYSA-M sodium;2-methylpropoxymethanedithioate Chemical compound [Na+].CC(C)COC([S-])=S FLVLHHSRQUTOJM-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49394674 | 1974-08-01 | ||
| US493946A US3925218A (en) | 1974-08-01 | 1974-08-01 | Concentration of ore by flotation with solutions of aqueous dithiophosphates and thionocarbamate as collector |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI752067A7 FI752067A7 (enExample) | 1976-02-02 |
| FI61642B FI61642B (fi) | 1982-05-31 |
| FI61642C true FI61642C (fi) | 1982-09-10 |
Family
ID=23962377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI752067A FI61642C (fi) | 1974-08-01 | 1975-07-17 | Vattenloesning vilken aer laemplig saosom samlarloesning vid tillvaratagning av koppar fraon sulfidmalmer |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3925218A (enExample) |
| JP (1) | JPS5930467B2 (enExample) |
| BG (1) | BG24790A3 (enExample) |
| BR (1) | BR7504840A (enExample) |
| CA (1) | CA1026019A (enExample) |
| DE (1) | DE2534249A1 (enExample) |
| ES (1) | ES439926A1 (enExample) |
| FI (1) | FI61642C (enExample) |
| GB (1) | GB1510845A (enExample) |
| PH (1) | PH11134A (enExample) |
| SE (1) | SE415961B (enExample) |
| TR (1) | TR18738A (enExample) |
| ZA (1) | ZA754004B (enExample) |
| ZM (1) | ZM9075A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5821616Y2 (ja) * | 1978-11-15 | 1983-05-09 | ナショナル住宅産業株式会社 | 切断装置 |
| GB2106804A (en) * | 1981-10-08 | 1983-04-20 | American Cyanamid Co | Process for the beneficiation of metal sulfides and collector combinations therefor |
| US4530758A (en) * | 1982-05-17 | 1985-07-23 | Thiotech, Inc. | Ore flotation method |
| US4618461A (en) * | 1983-07-25 | 1986-10-21 | The Dow Chemical Company | O,O'-, O,S'- or S,S'-dithiodialkylene-bis(mono- or dihydrocarbyl carbamothioates) and S,S'-dithiodialkylene-bis(mono- or dihydrocarbyl carbamodithioates) and method of preparation thereof |
| US4689142A (en) * | 1985-03-22 | 1987-08-25 | Essex Industrial Chemicals, Inc. | Alkyl mercaptans as collector additives in froth flotation |
| US4702822A (en) * | 1985-07-12 | 1987-10-27 | The Dow Chemical Company | Novel collector composition for froth flotation |
| US4904374A (en) * | 1987-10-08 | 1990-02-27 | Sentrachem Limited | Froth flotation |
| ZA918140B (en) * | 1991-10-11 | 1992-07-29 | American Cyanamid Co | Recovery of platinum group metals and gold by synergistic reaction between allylalkylthionocarbamates and dithiophosphates |
| GB9600525D0 (en) * | 1996-01-11 | 1996-03-13 | Allied Colloids Ltd | Process for recovering minerals and compositions for use in this |
| US5599442A (en) * | 1996-06-14 | 1997-02-04 | Cytec Technology Corp. | Collector composition for flotation of activated sphalerite |
| AU2012326312B2 (en) | 2011-10-18 | 2016-09-01 | Cytec Technology Corp. | Froth flotation processes |
| EP2768617A2 (en) | 2011-10-18 | 2014-08-27 | Cytec Technology Corp. | Froth flotation processes |
| US9302274B2 (en) | 2011-10-18 | 2016-04-05 | Cytec Technology Corp. | Collector compositions and methods of using the same |
| AU2013218789B2 (en) * | 2012-02-06 | 2017-09-28 | Teebee Holdings Pty Ltd | Thionocarbamates and processes |
| MX389358B (es) * | 2014-07-14 | 2025-03-20 | Clariant Int Ltd | Composicion acuosa estable de colectores neutros y su uso en procedimientos de tratamiento de minerales. |
| US11612897B2 (en) * | 2017-05-24 | 2023-03-28 | Basf Se | Alkylated triphenyl phosphorothionates as selective metal sulphide collectors |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2029156A (en) * | 1928-11-01 | 1936-01-28 | American Cyanamid Co | Oxide flotation |
| US2043192A (en) * | 1934-05-09 | 1936-06-02 | American Cyanamid Co | Flotation reagent |
| US2206284A (en) * | 1939-10-21 | 1940-07-02 | American Cyanamid Co | Concentrated aqueous solutions of the ammonium salts of disubstituted dithiophosphoric acids |
| US2691635A (en) * | 1953-05-20 | 1954-10-12 | Dow Chemical Co | Process for the manufacture of dialkyl thionocarbamates |
| US3086653A (en) * | 1960-12-12 | 1963-04-23 | American Cyanamid Co | Concentrated aqueous solutions of alkali and alkaline earth metal salts of phospho-organic compounds |
-
1974
- 1974-08-01 US US493946A patent/US3925218A/en not_active Expired - Lifetime
-
1975
- 1975-06-20 CA CA229,754A patent/CA1026019A/en not_active Expired
- 1975-06-23 ZA ZA00754004A patent/ZA754004B/xx unknown
- 1975-06-27 PH PH17325A patent/PH11134A/en unknown
- 1975-07-10 BG BG030506A patent/BG24790A3/xx unknown
- 1975-07-10 GB GB29111/75A patent/GB1510845A/en not_active Expired
- 1975-07-14 ZM ZM90/75A patent/ZM9075A1/xx unknown
- 1975-07-17 TR TR18738A patent/TR18738A/xx unknown
- 1975-07-17 FI FI752067A patent/FI61642C/fi not_active IP Right Cessation
- 1975-07-29 BR BR7504840*A patent/BR7504840A/pt unknown
- 1975-07-31 DE DE19752534249 patent/DE2534249A1/de not_active Ceased
- 1975-07-31 JP JP50092655A patent/JPS5930467B2/ja not_active Expired
- 1975-08-01 ES ES439926A patent/ES439926A1/es not_active Expired
- 1975-08-01 SE SE7508748A patent/SE415961B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB1510845A (en) | 1978-05-17 |
| BR7504840A (pt) | 1976-08-03 |
| AU8249675A (en) | 1977-01-06 |
| JPS5930467B2 (ja) | 1984-07-27 |
| FI752067A7 (enExample) | 1976-02-02 |
| TR18738A (tr) | 1977-07-27 |
| BG24790A3 (bg) | 1978-05-12 |
| PH11134A (en) | 1977-10-27 |
| ZM9075A1 (en) | 1976-03-22 |
| ZA754004B (en) | 1976-06-30 |
| DE2534249A1 (de) | 1976-02-12 |
| US3925218A (en) | 1975-12-09 |
| JPS5140302A (enExample) | 1976-04-05 |
| SE415961B (sv) | 1980-11-17 |
| ES439926A1 (es) | 1977-06-16 |
| CA1026019A (en) | 1978-02-07 |
| FI61642B (fi) | 1982-05-31 |
| SE7508748L (sv) | 1976-02-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: AMERICAN CYANAMID COMPANY |