FI3418447T3 - Mikrofibrilloidun selluloosan käsittelyprosessi - Google Patents
Mikrofibrilloidun selluloosan käsittelyprosessi Download PDFInfo
- Publication number
- FI3418447T3 FI3418447T3 FIEP18184556.1T FI18184556T FI3418447T3 FI 3418447 T3 FI3418447 T3 FI 3418447T3 FI 18184556 T FI18184556 T FI 18184556T FI 3418447 T3 FI3418447 T3 FI 3418447T3
- Authority
- FI
- Finland
- Prior art keywords
- microfibrillated cellulose
- inorganic particulate
- water
- particulate material
- optionally
- Prior art date
Links
- 239000001913 cellulose Substances 0.000 title claims 19
- 229920002678 cellulose Polymers 0.000 title claims 19
- 238000000034 method Methods 0.000 title claims 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 12
- 239000011236 particulate material Substances 0.000 claims 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 5
- 239000005995 Aluminium silicate Substances 0.000 claims 4
- 235000012211 aluminium silicate Nutrition 0.000 claims 4
- 239000003139 biocide Substances 0.000 claims 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 3
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 2
- -1 alkaline earth metal carbonate Chemical class 0.000 claims 2
- 239000007900 aqueous suspension Substances 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- 230000006835 compression Effects 0.000 claims 2
- 238000007906 compression Methods 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- 239000008394 flocculating agent Substances 0.000 claims 2
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- YIEDHPBKGZGLIK-UHFFFAOYSA-L tetrakis(hydroxymethyl)phosphanium;sulfate Chemical compound [O-]S([O-])(=O)=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO YIEDHPBKGZGLIK-UHFFFAOYSA-L 0.000 claims 2
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 claims 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 claims 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims 1
- 239000005909 Kieselgur Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims 1
- 239000010427 ball clay Substances 0.000 claims 1
- 230000003115 biocidal effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 230000005484 gravity Effects 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 229910052621 halloysite Inorganic materials 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 239000011147 inorganic material Substances 0.000 claims 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 1
- 239000001095 magnesium carbonate Substances 0.000 claims 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 239000013618 particulate matter Substances 0.000 claims 1
- 239000010451 perlite Substances 0.000 claims 1
- 235000019362 perlite Nutrition 0.000 claims 1
- 229920002401 polyacrylamide Polymers 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/007—Modification of pulp properties by mechanical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/18—Highly hydrated, swollen or fibrillatable fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13290070 | 2013-03-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FI3418447T3 true FI3418447T3 (fi) | 2023-10-02 |
Family
ID=48083070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FIEP18184556.1T FI3418447T3 (fi) | 2013-03-15 | 2014-03-14 | Mikrofibrilloidun selluloosan käsittelyprosessi |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US10745857B2 (enExample) |
| EP (2) | EP3418447B1 (enExample) |
| JP (3) | JP6513037B2 (enExample) |
| CN (2) | CN110714359B (enExample) |
| BR (3) | BR122021020689B1 (enExample) |
| CA (1) | CA2906283C (enExample) |
| DK (2) | DK2971347T3 (enExample) |
| ES (2) | ES2959571T3 (enExample) |
| FI (1) | FI3418447T3 (enExample) |
| PL (1) | PL3418447T3 (enExample) |
| PT (1) | PT3418447T (enExample) |
| WO (1) | WO2014140275A1 (enExample) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103590283B (zh) | 2012-08-14 | 2015-12-02 | 金东纸业（江苏）股份有限公司 | 涂料及应用该涂料的涂布纸 |
| GB201304717D0 (en) | 2013-03-15 | 2013-05-01 | Imerys Minerals Ltd | Paper composition |
| BR122021020689B1 (pt) * | 2013-03-15 | 2023-01-10 | Imerys Minerals Limited | Processo para a produção de celulose microfibrilada com atributos aprimorados para a produção de um produto de papel |
| FI127124B2 (en) * | 2013-12-05 | 2021-02-15 | Upm Kymmene Corp | A process for making modified cellulosic products and a modified cellulosic product |
| ES2858631T3 (es) * | 2014-05-30 | 2021-09-30 | Borregaard As | Celulosa microfibrilada |
| CN104562823B (zh) * | 2014-12-11 | 2017-01-18 | 天津科技大学 | 同步法制备微纤化纤维素及其在纸张增强中的应用 |
| US9970159B2 (en) | 2014-12-31 | 2018-05-15 | Innovatech Engineering, LLC | Manufacture of hydrated nanocellulose sheets for use as a dermatological treatment |
| US9816230B2 (en) * | 2014-12-31 | 2017-11-14 | Innovatech Engineering, LLC | Formation of hydrated nanocellulose sheets with or without a binder for the use as a dermatological treatment |
| CN104863008B (zh) * | 2015-04-23 | 2018-04-17 | 中国制浆造纸研究院有限公司 | 一种采用微纤化纤维素改性填料提高纸张不透明度的方法 |
| CA3002729C (en) * | 2015-12-31 | 2020-12-29 | Teknologian Tutkimuskeskus Vtt Oy | Method of producing films from high consistency enzyme fibrillated nanocellulose |
| BR112018069541A2 (pt) | 2016-04-04 | 2019-01-29 | Fiberlean Tech Ltd | composições e métodos para fornecer resistência aumentada em produtos de teto, pavimento e construção |
| EP3828339B1 (en) | 2016-04-05 | 2023-11-29 | FiberLean Technologies Limited | Paper and paperboard products |
| US11846072B2 (en) | 2016-04-05 | 2023-12-19 | Fiberlean Technologies Limited | Process of making paper and paperboard products |
| KR102251141B1 (ko) * | 2016-04-22 | 2021-05-13 | 파이버린 테크놀로지스 리미티드 | 재분산된 미세섬유상 셀룰로오스 |
| PT3445900T (pt) * | 2016-04-22 | 2022-09-19 | Fiberlean Tech Ltd | Fibras compreendendo celulose microfibrilada e métodos de fibras e materiais não tecidos das mesmas |
| CN105952827B (zh) * | 2016-06-01 | 2018-05-01 | 江苏金麦穗新能源科技股份有限公司 | 一种废旧织物纤维刹车片摩擦材料生产工艺 |
| SE539786C2 (en) * | 2016-06-22 | 2017-11-28 | Stora Enso Oyj | Microfibrillated cellulose film |
| GB201612889D0 (en) * | 2016-07-26 | 2016-09-07 | Natural Resources (2000) Ltd | Moulding of articles |
| JP6470236B2 (ja) * | 2016-08-26 | 2019-02-13 | 大王製紙株式会社 | 水解性シート及び当該水解性シートの製造方法 |
| JP6211160B1 (ja) * | 2016-09-30 | 2017-10-11 | 大王製紙株式会社 | 水解性シート |
| CN106948213A (zh) * | 2017-02-13 | 2017-07-14 | 华南理工大学 | 一种碳酸钙高加填量纤维及其制备方法与应用 |
| CN110892111B (zh) * | 2017-04-21 | 2022-11-15 | 飞博林科技有限公司 | 具有增强特性的微纤化纤维素及其制备方法 |
| SE542671C2 (en) * | 2017-07-05 | 2020-06-23 | Stora Enso Oyj | Dosing of nanocellulose suspension in gel phase |
| WO2019076922A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| WO2019076909A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| WO2019076920A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| JP7252975B2 (ja) * | 2018-11-07 | 2023-04-05 | 日本製紙株式会社 | 微細繊維状セルロース分散体の製造方法 |
| US12049431B2 (en) | 2019-01-25 | 2024-07-30 | AMVAC Chemical Corporation (Subsidiary of American Vanguard Corporation) | Agricultural adjuvant comprising microfibrillated cellulose |
| KR20220035871A (ko) * | 2019-07-23 | 2022-03-22 | 파이버린 테크놀로지스 리미티드 | 인장 특성이 향상된 마이크로피브릴화 셀룰로스를 제조하기 위한 조성물 및 방법 |
| AU2021272255A1 (en) * | 2020-05-11 | 2022-12-08 | Suzano S.A. | Suspension stabilizer agent |
| SE545733C2 (en) * | 2020-09-01 | 2023-12-27 | Stora Enso Oyj | A method for producing a machine glazed paper comprising microfibrillated cellulose and a machine glazed paper |
| CN116157571A (zh) * | 2020-09-11 | 2023-05-23 | 菲博林科技有限公司 | 用于机械特性改善的纸和纸板应用的含微纤化纤维素和微孔无机颗粒复合材料的填料组合物 |
| US12385185B2 (en) | 2020-09-11 | 2025-08-12 | Fiberlean Technologies Limited | Microfibrillated cellulose containing pulp sheets with improved mechanical properties |
| EP4172409A1 (en) * | 2020-09-11 | 2023-05-03 | FiberLean Technologies Limited | Microfibrillated cellulose containing pulp sheets with improved mechanical properties |
| CN112695563A (zh) * | 2020-12-31 | 2021-04-23 | 江苏理文造纸有限公司 | 一种废纸纤维微纤化的处理工艺 |
| SE544871C2 (en) * | 2021-02-26 | 2022-12-20 | Stora Enso Oyj | Method and device for producing an mfc film |
| US12559887B2 (en) | 2023-01-13 | 2026-02-24 | Shree Krishna Paper Mills And Industries Limited | Unbleached natural brown copier paper and process thereof |
| SE2330162A1 (en) * | 2023-04-13 | 2024-10-14 | Stora Enso Oyj | A method for producing a microfibrillated cellulose film, and a microfibrillated cellulose film |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4374702A (en) | 1979-12-26 | 1983-02-22 | International Telephone And Telegraph Corporation | Microfibrillated cellulose |
| US4481076A (en) * | 1983-03-28 | 1984-11-06 | International Telephone And Telegraph Corporation | Redispersible microfibrillated cellulose |
| GB2275876B (en) | 1993-03-12 | 1996-07-17 | Ecc Int Ltd | Grinding alkaline earth metal pigments |
| JP3036354B2 (ja) | 1994-05-17 | 2000-04-24 | 特種製紙株式会社 | 微細フィブリル化セルロースの製造方法 |
| FR2730252B1 (fr) | 1995-02-08 | 1997-04-18 | Generale Sucriere Sa | Cellulose microfibrillee et son procede d'obtention a partir de pulpe de vegetaux a parois primaires, notamment a partir de pulpe de betteraves sucrieres. |
| US6183596B1 (en) | 1995-04-07 | 2001-02-06 | Tokushu Paper Mfg. Co., Ltd. | Super microfibrillated cellulose, process for producing the same, and coated paper and tinted paper using the same |
| FI105112B (fi) * | 1997-01-03 | 2000-06-15 | Megatrex Oy | Menetelmä ja laite kuitupitoisen materiaalin kuiduttamiseksi |
| CN1325725C (zh) * | 2002-07-18 | 2007-07-11 | 株式会社日本吸收体技术研究所 | 超微纤维素纤维的制造方法和制造装置 |
| DE102005025374A1 (de) * | 2005-05-31 | 2006-12-07 | Basf Ag | Polymer-Pigment-Hybride für die Papierherstellung |
| US8444808B2 (en) * | 2006-08-31 | 2013-05-21 | Kx Industries, Lp | Process for producing nanofibers |
| US7566014B2 (en) * | 2006-08-31 | 2009-07-28 | Kx Technologies Llc | Process for producing fibrillated fibers |
| CN102348948B (zh) | 2009-03-11 | 2014-12-10 | 鲍利葛股份公司 | 干燥微纤维化纤维素的方法 |
| HUE045496T2 (hu) * | 2009-03-30 | 2019-12-30 | Fiberlean Tech Ltd | Eljárás nano-fibrilláris cellulóz szuszpenziók elõállítására |
| PL2236545T3 (pl) * | 2009-03-30 | 2015-02-27 | Omya Int Ag | Sposób wytwarzania nanofibrylarnych żeli celulozowych |
| GB0908401D0 (en) * | 2009-05-15 | 2009-06-24 | Imerys Minerals Ltd | Paper filler composition |
| BR112012009802A2 (pt) | 2009-10-26 | 2016-11-22 | Stora Enso Oyj | processo para a produção de celulose microfibrilada e celulose microfibrilada produzida de acordo com o processo |
| GB201019288D0 (en) * | 2010-11-15 | 2010-12-29 | Imerys Minerals Ltd | Compositions |
| NO2683858T3 (enExample) * | 2011-03-08 | 2018-02-10 | ||
| FI127111B (en) * | 2012-08-20 | 2017-11-15 | Stora Enso Oyj | Process and intermediate for the production of highly refined or microfibrillated cellulose |
| BR122021020689B1 (pt) * | 2013-03-15 | 2023-01-10 | Imerys Minerals Limited | Processo para a produção de celulose microfibrilada com atributos aprimorados para a produção de um produto de papel |
-
2014
- 2014-03-14 BR BR122021020689-9A patent/BR122021020689B1/pt active IP Right Grant
- 2014-03-14 JP JP2015562195A patent/JP6513037B2/ja not_active Expired - Fee Related
- 2014-03-14 EP EP18184556.1A patent/EP3418447B1/en active Active
- 2014-03-14 CA CA2906283A patent/CA2906283C/en active Active
- 2014-03-14 US US14/775,519 patent/US10745857B2/en active Active
- 2014-03-14 BR BR112015022072-0A patent/BR112015022072B1/pt active IP Right Grant
- 2014-03-14 DK DK14711725.3T patent/DK2971347T3/en active
- 2014-03-14 PL PL18184556.1T patent/PL3418447T3/pl unknown
- 2014-03-14 ES ES18184556T patent/ES2959571T3/es active Active
- 2014-03-14 CN CN201910947938.7A patent/CN110714359B/zh not_active Expired - Fee Related
- 2014-03-14 DK DK18184556.1T patent/DK3418447T3/da active
- 2014-03-14 EP EP14711725.3A patent/EP2971347B1/en active Active
- 2014-03-14 ES ES14711725.3T patent/ES2688874T3/es active Active
- 2014-03-14 FI FIEP18184556.1T patent/FI3418447T3/fi active
- 2014-03-14 CN CN201480026782.4A patent/CN105229228B/zh not_active Expired - Fee Related
- 2014-03-14 PT PT181845561T patent/PT3418447T/pt unknown
- 2014-03-14 WO PCT/EP2014/055102 patent/WO2014140275A1/en not_active Ceased
- 2014-03-14 BR BR122021020683-0A patent/BR122021020683B1/pt active IP Right Grant
-
2019
- 2019-02-19 JP JP2019027341A patent/JP6966493B2/ja active Active
-
2020
- 2020-07-07 US US16/922,410 patent/US20200332465A1/en not_active Abandoned
-
2021
- 2021-10-21 JP JP2021172095A patent/JP2022003187A/ja active Pending
-
2022
- 2022-01-19 US US17/579,215 patent/US12018433B2/en active Active
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