CA2906283C - Process for treating microfibrillated cellulose - Google Patents
Process for treating microfibrillated cellulose Download PDFInfo
- Publication number
- CA2906283C CA2906283C CA2906283A CA2906283A CA2906283C CA 2906283 C CA2906283 C CA 2906283C CA 2906283 A CA2906283 A CA 2906283A CA 2906283 A CA2906283 A CA 2906283A CA 2906283 C CA2906283 C CA 2906283C
- Authority
- CA
- Canada
- Prior art keywords
- microfibrillated cellulose
- processed
- high shear
- water
- inorganic particulate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 229920002678 cellulose Polymers 0.000 title claims abstract description 415
- 239000001913 cellulose Substances 0.000 title claims abstract description 415
- 238000000034 method Methods 0.000 title claims abstract description 289
- 230000008569 process Effects 0.000 title claims abstract description 206
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 80
- 230000002708 enhancing effect Effects 0.000 claims abstract description 66
- 239000000203 mixture Substances 0.000 claims abstract description 55
- 239000011236 particulate material Substances 0.000 claims description 126
- 238000000227 grinding Methods 0.000 claims description 105
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 103
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 91
- 239000000835 fiber Substances 0.000 claims description 88
- 230000002829 reductive effect Effects 0.000 claims description 66
- 238000002156 mixing Methods 0.000 claims description 54
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 49
- 239000005995 Aluminium silicate Substances 0.000 claims description 39
- 235000012211 aluminium silicate Nutrition 0.000 claims description 39
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 37
- 239000002609 medium Substances 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 26
- 239000004927 clay Substances 0.000 claims description 23
- 238000010008 shearing Methods 0.000 claims description 20
- 230000001965 increasing effect Effects 0.000 claims description 19
- -1 alkaline earth metal carbonate Chemical class 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 238000012545 processing Methods 0.000 claims description 14
- 239000003139 biocide Substances 0.000 claims description 11
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 11
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 9
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 8
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- 239000000454 talc Substances 0.000 claims description 7
- 229910052623 talc Inorganic materials 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- 239000005909 Kieselgur Substances 0.000 claims description 6
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 6
- 239000010427 ball clay Substances 0.000 claims description 6
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 6
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000010459 dolomite Substances 0.000 claims description 6
- 229910000514 dolomite Inorganic materials 0.000 claims description 6
- 239000002657 fibrous material Substances 0.000 claims description 6
- 239000008394 flocculating agent Substances 0.000 claims description 6
- 239000010440 gypsum Substances 0.000 claims description 6
- 229910052602 gypsum Inorganic materials 0.000 claims description 6
- 229910052621 halloysite Inorganic materials 0.000 claims description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 6
- 239000001095 magnesium carbonate Substances 0.000 claims description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 6
- 235000019362 perlite Nutrition 0.000 claims description 6
- YIEDHPBKGZGLIK-UHFFFAOYSA-L tetrakis(hydroxymethyl)phosphanium;sulfate Chemical compound [O-]S([O-])(=O)=O.OC[P+](CO)(CO)CO.OC[P+](CO)(CO)CO YIEDHPBKGZGLIK-UHFFFAOYSA-L 0.000 claims description 6
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 claims description 5
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 5
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 5
- 230000003115 biocidal effect Effects 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 239000013618 particulate matter Substances 0.000 claims 13
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
- 229910052570 clay Inorganic materials 0.000 claims 2
- 230000001419 dependent effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 215
- 239000000047 product Substances 0.000 description 115
- 239000007787 solid Substances 0.000 description 54
- 239000002245 particle Substances 0.000 description 46
- 239000000523 sample Substances 0.000 description 26
- 239000000945 filler Substances 0.000 description 20
- 238000000576 coating method Methods 0.000 description 17
- 239000011248 coating agent Substances 0.000 description 16
- 239000008199 coating composition Substances 0.000 description 12
- 238000009826 distribution Methods 0.000 description 12
- 238000011068 loading method Methods 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- 239000011707 mineral Substances 0.000 description 9
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000012764 mineral filler Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002734 clay mineral Substances 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 238000002356 laser light scattering Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 239000000920 calcium hydroxide Substances 0.000 description 5
- 235000011116 calcium hydroxide Nutrition 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000003490 calendering Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000001238 wet grinding Methods 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 244000299507 Gossypium hirsutum Species 0.000 description 3
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 229940105329 carboxymethylcellulose Drugs 0.000 description 3
- 229910052622 kaolinite Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000011020 pilot scale process Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 244000166124 Eucalyptus globulus Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 240000006240 Linum usitatissimum Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- 244000082204 Phyllostachys viridis Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 241000209504 Poaceae Species 0.000 description 2
- 240000000111 Saccharum officinarum Species 0.000 description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000011805 ball Substances 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- 238000010960 commercial process Methods 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000012470 diluted sample Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 238000007885 magnetic separation Methods 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000010784 textile waste Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 239000003657 drainage water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000009895 reductive bleaching Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012858 resilient material Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003443 succinic acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/007—Modification of pulp properties by mechanical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/18—Highly hydrated, swollen or fibrillatable fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13290070 | 2013-03-15 | ||
| EP13290070.5 | 2013-03-15 | ||
| PCT/EP2014/055102 WO2014140275A1 (en) | 2013-03-15 | 2014-03-14 | Process for treating microfibrillated cellulose |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2906283A1 CA2906283A1 (en) | 2014-09-18 |
| CA2906283C true CA2906283C (en) | 2024-06-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CA2906283A Active CA2906283C (en) | 2013-03-15 | 2014-03-14 | Process for treating microfibrillated cellulose |
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| Country | Link |
|---|---|
| US (3) | US10745857B2 (enExample) |
| EP (2) | EP3418447B1 (enExample) |
| JP (3) | JP6513037B2 (enExample) |
| CN (2) | CN110714359B (enExample) |
| BR (3) | BR122021020683B1 (enExample) |
| CA (1) | CA2906283C (enExample) |
| DK (2) | DK3418447T3 (enExample) |
| ES (2) | ES2959571T3 (enExample) |
| FI (1) | FI3418447T3 (enExample) |
| PL (1) | PL3418447T3 (enExample) |
| PT (1) | PT3418447T (enExample) |
| WO (1) | WO2014140275A1 (enExample) |
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| CN103590283B (zh) | 2012-08-14 | 2015-12-02 | 金东纸业（江苏）股份有限公司 | 涂料及应用该涂料的涂布纸 |
| GB201304717D0 (en) | 2013-03-15 | 2013-05-01 | Imerys Minerals Ltd | Paper composition |
| ES2959571T3 (es) * | 2013-03-15 | 2024-02-27 | Fiberlean Tech Ltd | Procedimiento de tratamiento de la celulosa microfibrillada |
| FI127124B2 (en) | 2013-12-05 | 2021-02-15 | Upm Kymmene Corp | A process for making modified cellulosic products and a modified cellulosic product |
| CN106661833B (zh) * | 2014-05-30 | 2019-02-12 | 鲍利葛公司 | 微原纤化纤维素 |
| CN104562823B (zh) * | 2014-12-11 | 2017-01-18 | 天津科技大学 | 同步法制备微纤化纤维素及其在纸张增强中的应用 |
| US9970159B2 (en) | 2014-12-31 | 2018-05-15 | Innovatech Engineering, LLC | Manufacture of hydrated nanocellulose sheets for use as a dermatological treatment |
| US9816230B2 (en) * | 2014-12-31 | 2017-11-14 | Innovatech Engineering, LLC | Formation of hydrated nanocellulose sheets with or without a binder for the use as a dermatological treatment |
| CN104863008B (zh) * | 2015-04-23 | 2018-04-17 | 中国制浆造纸研究院有限公司 | 一种采用微纤化纤维素改性填料提高纸张不透明度的方法 |
| WO2017115020A1 (en) * | 2015-12-31 | 2017-07-06 | Teknologian Tutkimuskeskus Vtt Oy | Method of producing films from high consistency enzyme fibrillated nanocellulose |
| CN109071346B (zh) * | 2016-04-04 | 2022-06-14 | 菲博林科技有限公司 | 用于在天花板、地板和建筑产品中提供增加的强度的组合物和方法 |
| EP3440259B1 (en) | 2016-04-05 | 2021-02-24 | FiberLean Technologies Limited | Paper and paperboard products |
| US11846072B2 (en) | 2016-04-05 | 2023-12-19 | Fiberlean Technologies Limited | Process of making paper and paperboard products |
| ES2929232T3 (es) * | 2016-04-22 | 2022-11-25 | Fiberlean Tech Ltd | Método para mejorar las propiedades físicas y/o mecánicas de celulosa microfibrilada redispersada |
| PT3445900T (pt) * | 2016-04-22 | 2022-09-19 | Fiberlean Tech Ltd | Fibras compreendendo celulose microfibrilada e métodos de fibras e materiais não tecidos das mesmas |
| CN105952827B (zh) * | 2016-06-01 | 2018-05-01 | 江苏金麦穗新能源科技股份有限公司 | 一种废旧织物纤维刹车片摩擦材料生产工艺 |
| SE1650900A1 (en) * | 2016-06-22 | 2017-11-28 | Stora Enso Oyj | Microfibrillated cellulose film |
| GB201612889D0 (en) * | 2016-07-26 | 2016-09-07 | Natural Resources (2000) Ltd | Moulding of articles |
| JP6470236B2 (ja) * | 2016-08-26 | 2019-02-13 | 大王製紙株式会社 | 水解性シート及び当該水解性シートの製造方法 |
| JP6211160B1 (ja) * | 2016-09-30 | 2017-10-11 | 大王製紙株式会社 | 水解性シート |
| CN106948213A (zh) * | 2017-02-13 | 2017-07-14 | 华南理工大学 | 一种碳酸钙高加填量纤维及其制备方法与应用 |
| CN110892111B (zh) * | 2017-04-21 | 2022-11-15 | 飞博林科技有限公司 | 具有增强特性的微纤化纤维素及其制备方法 |
| SE542671C2 (en) * | 2017-07-05 | 2020-06-23 | Stora Enso Oyj | Dosing of nanocellulose suspension in gel phase |
| WO2019076922A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| WO2019076909A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| WO2019076920A1 (en) * | 2017-10-16 | 2019-04-25 | Microtherm Nv | TISSUE DISPERSION INJECTION EQUIPMENT AND METHOD FOR PRODUCING TISSUE CONTAINING NANOSTRUCTURE PARTICLE POWDER |
| JP7252975B2 (ja) * | 2018-11-07 | 2023-04-05 | 日本製紙株式会社 | 微細繊維状セルロース分散体の製造方法 |
| MX2021008904A (es) | 2019-01-25 | 2021-08-19 | Amvac Hong Kong Ltd | Celulosa microfibrilada como modificador de la reologia en formulaciones agricolas de alta resistencia ionica. |
| KR20220035871A (ko) * | 2019-07-23 | 2022-03-22 | 파이버린 테크놀로지스 리미티드 | 인장 특성이 향상된 마이크로피브릴화 셀룰로스를 제조하기 위한 조성물 및 방법 |
| WO2021226694A1 (en) * | 2020-05-11 | 2021-11-18 | Suzano S.A. | Suspension stabilizer agent |
| SE545733C2 (en) * | 2020-09-01 | 2023-12-27 | Stora Enso Oyj | A method for producing a machine glazed paper comprising microfibrillated cellulose and a machine glazed paper |
| US12385185B2 (en) | 2020-09-11 | 2025-08-12 | Fiberlean Technologies Limited | Microfibrillated cellulose containing pulp sheets with improved mechanical properties |
| CA3189808A1 (en) * | 2020-09-11 | 2022-03-17 | Fiberlean Technologies Limited | Microfibrillated cellulose containing pulp sheets with improved mechanical properties |
| EP4185748A1 (en) * | 2020-09-11 | 2023-05-31 | FiberLean Technologies Limited | Filler compositions comprising microfibrillated cellulose and microporous inorganic particulate material composites for paper and paperboard application with improved mechanical properties |
| CN112695563A (zh) * | 2020-12-31 | 2021-04-23 | 江苏理文造纸有限公司 | 一种废纸纤维微纤化的处理工艺 |
| SE544871C2 (en) * | 2021-02-26 | 2022-12-20 | Stora Enso Oyj | Method and device for producing an mfc film |
| US20240240404A1 (en) | 2023-01-13 | 2024-07-18 | Shree Krishna Paper Mills And Industries Limited | Unbleached natural brown copier paper and process thereof |
| SE2330162A1 (en) * | 2023-04-13 | 2024-10-14 | Stora Enso Oyj | A method for producing a microfibrillated cellulose film, and a microfibrillated cellulose film |
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| US4374702A (en) | 1979-12-26 | 1983-02-22 | International Telephone And Telegraph Corporation | Microfibrillated cellulose |
| US4481076A (en) * | 1983-03-28 | 1984-11-06 | International Telephone And Telegraph Corporation | Redispersible microfibrillated cellulose |
| GB2275876B (en) | 1993-03-12 | 1996-07-17 | Ecc Int Ltd | Grinding alkaline earth metal pigments |
| JP3036354B2 (ja) | 1994-05-17 | 2000-04-24 | 特種製紙株式会社 | 微細フィブリル化セルロースの製造方法 |
| FR2730252B1 (fr) | 1995-02-08 | 1997-04-18 | Generale Sucriere Sa | Cellulose microfibrillee et son procede d'obtention a partir de pulpe de vegetaux a parois primaires, notamment a partir de pulpe de betteraves sucrieres. |
| US6183596B1 (en) | 1995-04-07 | 2001-02-06 | Tokushu Paper Mfg. Co., Ltd. | Super microfibrillated cellulose, process for producing the same, and coated paper and tinted paper using the same |
| FI105112B (fi) * | 1997-01-03 | 2000-06-15 | Megatrex Oy | Menetelmä ja laite kuitupitoisen materiaalin kuiduttamiseksi |
| CN1325725C (zh) * | 2002-07-18 | 2007-07-11 | 株式会社日本吸收体技术研究所 | 超微纤维素纤维的制造方法和制造装置 |
| DE102005025374A1 (de) * | 2005-05-31 | 2006-12-07 | Basf Ag | Polymer-Pigment-Hybride für die Papierherstellung |
| US8444808B2 (en) | 2006-08-31 | 2013-05-21 | Kx Industries, Lp | Process for producing nanofibers |
| US7566014B2 (en) * | 2006-08-31 | 2009-07-28 | Kx Technologies Llc | Process for producing fibrillated fibers |
| CA2754988C (en) | 2009-03-11 | 2017-11-07 | Borregaard Industries Limited, Norge | Method for drying microfibrillated cellulose |
| HUE035151T2 (en) * | 2009-03-30 | 2018-05-02 | Fiberlean Tech Ltd | Process for the preparation of nano-fiber cellulose gels |
| PT2236664E (pt) * | 2009-03-30 | 2016-03-04 | Omya Int Ag | Processo para a produção de suspensões de celulose nanofibrilar |
| GB0908401D0 (en) | 2009-05-15 | 2009-06-24 | Imerys Minerals Ltd | Paper filler composition |
| US8747612B2 (en) | 2009-10-26 | 2014-06-10 | Stora Enso Oyj | Process for the production of microfibrillated cellulose in an extruder and microfibrillated cellulose produced according to the process |
| GB201019288D0 (en) * | 2010-11-15 | 2010-12-29 | Imerys Minerals Ltd | Compositions |
| NO2683858T3 (enExample) * | 2011-03-08 | 2018-02-10 | ||
| FI127111B (en) * | 2012-08-20 | 2017-11-15 | Stora Enso Oyj | Process and intermediate for the production of highly refined or microfibrillated cellulose |
| ES2959571T3 (es) * | 2013-03-15 | 2024-02-27 | Fiberlean Tech Ltd | Procedimiento de tratamiento de la celulosa microfibrillada |
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2014
- 2014-03-14 ES ES18184556T patent/ES2959571T3/es active Active
- 2014-03-14 EP EP18184556.1A patent/EP3418447B1/en active Active
- 2014-03-14 PL PL18184556.1T patent/PL3418447T3/pl unknown
- 2014-03-14 WO PCT/EP2014/055102 patent/WO2014140275A1/en not_active Ceased
- 2014-03-14 ES ES14711725.3T patent/ES2688874T3/es active Active
- 2014-03-14 US US14/775,519 patent/US10745857B2/en active Active
- 2014-03-14 DK DK18184556.1T patent/DK3418447T3/da active
- 2014-03-14 BR BR122021020683-0A patent/BR122021020683B1/pt active IP Right Grant
- 2014-03-14 PT PT181845561T patent/PT3418447T/pt unknown
- 2014-03-14 EP EP14711725.3A patent/EP2971347B1/en active Active
- 2014-03-14 CA CA2906283A patent/CA2906283C/en active Active
- 2014-03-14 FI FIEP18184556.1T patent/FI3418447T3/fi active
- 2014-03-14 BR BR122021020689-9A patent/BR122021020689B1/pt active IP Right Grant
- 2014-03-14 CN CN201910947938.7A patent/CN110714359B/zh active Active
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- 2014-03-14 DK DK14711725.3T patent/DK2971347T3/en active
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- 2014-03-14 CN CN201480026782.4A patent/CN105229228B/zh active Active
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2020
- 2020-07-07 US US16/922,410 patent/US20200332465A1/en not_active Abandoned
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2021
- 2021-10-21 JP JP2021172095A patent/JP2022003187A/ja active Pending
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