FI119772B - Process för framställning av förgrenade kolväteföreningar - Google Patents

Process för framställning av förgrenade kolväteföreningar Download PDF

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FI119772B
FI119772B FI20075433A FI20075433A FI119772B FI 119772 B FI119772 B FI 119772B FI 20075433 A FI20075433 A FI 20075433A FI 20075433 A FI20075433 A FI 20075433A FI 119772 B FI119772 B FI 119772B
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Finland
Prior art keywords
oils
waxes
fish
animal
fats
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FI20075433A
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English (en)
Finnish (fi)
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FI20075433A0 (sv
FI20075433A (sv
Inventor
Pekka Knuuttila
Pekka Aalto
Eija Koivusalmi
Rami Piilola
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Neste Oil Oyj
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Publication of FI20075433A0 publication Critical patent/FI20075433A0/sv
Priority to FI20075433A priority Critical patent/FI119772B/sv
Priority to CA002689151A priority patent/CA2689151A1/en
Priority to PT87754693T priority patent/PT2155839E/pt
Priority to PCT/FI2008/050344 priority patent/WO2008152200A1/en
Priority to CN2008800194989A priority patent/CN101784638B/zh
Priority to RU2009149474/04A priority patent/RU2462499C2/ru
Priority to JP2010511671A priority patent/JP5616785B2/ja
Priority to AU2008263782A priority patent/AU2008263782B2/en
Priority to DK08775469.3T priority patent/DK2155839T3/en
Priority to BRPI0812565A priority patent/BRPI0812565B8/pt
Priority to ES08775469.3T priority patent/ES2514540T3/es
Priority to MX2009013185A priority patent/MX2009013185A/es
Priority to PL08775469T priority patent/PL2155839T3/pl
Priority to MYPI20095247A priority patent/MY145102A/en
Priority to KR1020107000426A priority patent/KR101302651B1/ko
Priority to EP08775469.3A priority patent/EP2155839B1/en
Publication of FI20075433A publication Critical patent/FI20075433A/sv
Application granted granted Critical
Publication of FI119772B publication Critical patent/FI119772B/sv
Priority to ZA200908398A priority patent/ZA200908398B/xx

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/011—Cloud point
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    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10N2020/015—Distillation range
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    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
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    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10N2020/04—Molecular weight; Molecular weight distribution
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    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10N2020/065—Saturated Compounds
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    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10N2020/071—Branched chain compounds
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Lubricants (AREA)

Claims (6)

1. Process för framställning av basoljor, kännetecknad därav, att processen omfattar steg där en rävara erhällna frän ett utgängsmaterial av biologiskt 5 ursprung, utsätts för ett kondensationssteg vald frän ketonisering, aldol- kondensation, alkoholkondensation och radikalreaktioner och därefter utsätts för ett kombinerat hydrodefunktionaliserings- och isomeriseringssteg, och ketoniseringen genomförs under ett tryck Iran 0 till 10 Mpa, vid en tempe-10 ratur frän 10 tili 500 °C, i närvaro av en uppburen metalloxidkatalysator och rävaran väljs frän fcttsyraestrar, fettsyraanhydrider, fettalkoholer, fett-aldehyder, naturliga vaxer, metallsalter av fcttsyror, dikarboxylsyror och polyoler, aldolkondensationen genomförs i närvaro av en homogen eller heterogen 15 aldolkondensationskatalysator vid en temperatur frän 80 tili 400 °C och rävaran väljs frän aldehyder, ketoner och hydroxyaldehyder, alkoholkondensationen genomförs i närvaro av en katalysator vald frän hydroxider och alkoxider av alkali och alkaliska jordartsmetaller och me-talloxider, i kombination med en cokatalysator omfattande en metall vid 20 en temperatur frän 200 tili 300 °C och rävaran väljs frän primära och/eller sekundära, mättade och/eller omättade alkoholer, radikalreaktionen genomförs vid en temperatur av 100 tili 300 °C i närvaro av en alkylperoxid-, peroxyester-, dialkylperoxid- eller peroxyketalkataly-sator och rävaran väljs frän mättade karboxylsyror och alfaolefmer i ett 25 molförhällande 1:1. 1 Process enligt patentkravet 1, kännetecknad därav, att det kombinerade hydrodefunktionaliserings- och isomeriseringssteget genomförs under ett tryck frän 0.1 tili 15 MPa, vid en temperatur av 100 tili 500 °C, i närvaro 30 av en bifunktionell katalysator omfattande ätminstone ett molekylärt säll valt frän aluminosilikater och silicoaluminofosfater och ätminstone en me- tall vald frän Grupp 6 och 8-10 metaller i Periodiska Tabellen over Grund-ämnen.
3. Process enligt patentkravet 2, kännetecknad därav, att strömnings- 5 hastigheten WHSV i det kombinerade hydrodefunktionaliserings- och isomeriseringssteget är frän 0,1 till 10 1/h och väte till vätska matningsför-hällendet är frän 1 till 5000 Nl/1.
4. Process enligt patentkravet 2 eller 3, kännetecknad därav, att den bifunk- 10 tionella katalysatom omfattar ätminstone ett molekylärt säll valt frän zeo- liter och silicoaluminofosfater, ätminstone en metall vald frän Grupp 9 eller 10 metaller i Periodiska Tabellen över Grundämnen och ett binde-medel.
5. Process enligt vilket som heist av patentkraven 1-4, kännetecknad där av, att efter det kombinerade hydrodefunktionaliserings- och isomerise-rings-steget genomförs ett valfritt hydrofinishing-steg, och produkten överförs tili en destillerings- och/eller separeringsenhet, i vilken produkt-komponenter som kokar över olika temperaturomräden separeras frän var-20 andra.
6. Process enligt vilket som heist av patentkraven 1-5, kännetecknad därav, att rävaran väljs frän en grupp bestäende av: a) växtfetter, växtoljor, växtvaxer; animaliska fetter, animaliska oljor, 25 animaliska vaxer; fiskfetter, fisko ljor, fiskvaxer, och b) fettsyror och fria fettsyror erhällna frän växtfetter, växtoljor, växtvaxer; animaliska fetter, animaliska oljor, animaliska vaxer; fiskfetter, fiskoljor, fiskvaxer, och blandningar därav genom hydrolys, transforestring eller pyrolys, och c) estrar erhällna fran växtfetter, växtoljor, växtvaxer; animaliska fetter, animaliska oljor, animaliska vaxer; fiskfetter, fiskoljor, fisk-vaxer, och blandningar därav genom transforestring, och d) metallsalter av fettsyror erhallna ffän växtfetter, växtoljor, växt- 5 vaxer; animaliska fetter, animaliska oljor, animaliska vaxer; fisk fetter, fiskoljor, fiskvaxer, och blandningar därav genom fortval-ning, och e) anhydrider av fettsyror ffän växtfetter, växtoljor, växtvaxer; animaliska fetter, animaliska oljor, animaliska vaxer; fiskfetter, fiskoljor, 10 fiskvaxer, och blandningar därav, och f) estrar erhällna genom förestring av ffia fettsyror av växt-, animal-och fiskursprung med alkoholer, och g) fettalkoholer eller aldehyder erhällna som reduktionsprodukter av fettsyror ffän växtfetter, växtoljor, växtvaxer; animaliska fetter, 15 animaliska oljor, animaliska vaxer; fiskfetter, fiskoljor, fiskvaxer, och blandningar därav, och h) ätervunna fetter och oljor av matkvalitet, och fetter, oljor och vaxer erhällna genom genteknik, i) dikarboxylsyror eller polyoler inkluderande dioler, hydroxyketo- 20 ner, hydroxyaldehyder, hydroxykarboxylsyror, och j) blandningar av nämnda utgängsmaterial. 25
FI20075433A 2007-06-11 2007-06-11 Process för framställning av förgrenade kolväteföreningar FI119772B (sv)

Priority Applications (17)

Application Number Priority Date Filing Date Title
FI20075433A FI119772B (sv) 2007-06-11 2007-06-11 Process för framställning av förgrenade kolväteföreningar
DK08775469.3T DK2155839T3 (en) 2007-06-11 2008-06-10 A process for the production of branched chain hydrocarbons
ES08775469.3T ES2514540T3 (es) 2007-06-11 2008-06-10 Proceso para producir hidrocarburos ramificados
PCT/FI2008/050344 WO2008152200A1 (en) 2007-06-11 2008-06-10 Process for producing branched hydrocarbons
CN2008800194989A CN101784638B (zh) 2007-06-11 2008-06-10 生产支链烃的方法
RU2009149474/04A RU2462499C2 (ru) 2007-06-11 2008-06-10 Способ получения разветвленных углеводородов
JP2010511671A JP5616785B2 (ja) 2007-06-11 2008-06-10 分枝状炭化水素の製造方法
AU2008263782A AU2008263782B2 (en) 2007-06-11 2008-06-10 Process for producing branched hydrocarbons
CA002689151A CA2689151A1 (en) 2007-06-11 2008-06-10 Process for producing branched hydrocarbons
BRPI0812565A BRPI0812565B8 (pt) 2007-06-11 2008-06-10 processo para produção de hidrocarbonetos ramificados
PT87754693T PT2155839E (pt) 2007-06-11 2008-06-10 Processo de produção de hidrocarbonetos ramificados
MX2009013185A MX2009013185A (es) 2007-06-11 2008-06-10 Proceso para producir hidrocarburos ramificados.
PL08775469T PL2155839T3 (pl) 2007-06-11 2008-06-10 Sposób wytwarzania węglowodorów rozgałęzionych
MYPI20095247A MY145102A (en) 2007-06-11 2008-06-10 Process for producing branched hydrocarbons
KR1020107000426A KR101302651B1 (ko) 2007-06-11 2008-06-10 측쇄 탄화수소를 제조하기 위한 방법
EP08775469.3A EP2155839B1 (en) 2007-06-11 2008-06-10 Process for producing branched hydrocarbons
ZA200908398A ZA200908398B (en) 2007-06-11 2009-11-26 Process for producing branched hydrocarbons

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EP2155839A4 (en) 2013-05-08
EP2155839B1 (en) 2014-09-24
RU2462499C2 (ru) 2012-09-27
RU2009149474A (ru) 2011-07-20
ZA200908398B (en) 2010-08-25
AU2008263782A1 (en) 2008-12-18
ES2514540T3 (es) 2014-10-28
MX2009013185A (es) 2010-01-20
MY145102A (en) 2011-12-30
KR101302651B1 (ko) 2013-09-03
FI20075433A0 (sv) 2007-06-11
CN101784638B (zh) 2013-09-18
BRPI0812565B1 (pt) 2018-06-12
JP5616785B2 (ja) 2014-10-29
KR20100036308A (ko) 2010-04-07
AU2008263782B2 (en) 2012-03-22
DK2155839T3 (en) 2014-12-15
JP2010529176A (ja) 2010-08-26
WO2008152200A1 (en) 2008-12-18
CN101784638A (zh) 2010-07-21
FI20075433A (sv) 2008-12-12
BRPI0812565B8 (pt) 2020-05-26
PT2155839E (pt) 2014-10-13
CA2689151A1 (en) 2008-12-18
EP2155839A1 (en) 2010-02-24
PL2155839T3 (pl) 2015-03-31

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