FI113166B - Synteettisen isopentaanin muodostumisen kontrollointi amyleenien alkyloinnin aikana - Google Patents
Synteettisen isopentaanin muodostumisen kontrollointi amyleenien alkyloinnin aikana Download PDFInfo
- Publication number
- FI113166B FI113166B FI943297A FI943297A FI113166B FI 113166 B FI113166 B FI 113166B FI 943297 A FI943297 A FI 943297A FI 943297 A FI943297 A FI 943297A FI 113166 B FI113166 B FI 113166B
- Authority
- FI
- Finland
- Prior art keywords
- isopentane
- alkylation
- feed
- amylenes
- synthetic
- Prior art date
Links
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 title claims abstract description 235
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 title claims abstract description 117
- 238000005804 alkylation reaction Methods 0.000 title claims abstract description 90
- 230000029936 alkylation Effects 0.000 title claims abstract description 46
- 230000015572 biosynthetic process Effects 0.000 title claims description 27
- 230000033228 biological regulation Effects 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 40
- 239000000463 material Substances 0.000 claims abstract description 5
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 34
- 239000003054 catalyst Substances 0.000 claims description 31
- 230000008569 process Effects 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 25
- 239000001282 iso-butane Substances 0.000 claims description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 8
- 230000002152 alkylating effect Effects 0.000 claims description 7
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 127
- 238000006243 chemical reaction Methods 0.000 description 34
- 239000000047 product Substances 0.000 description 23
- 239000000126 substance Substances 0.000 description 21
- 150000001336 alkenes Chemical class 0.000 description 18
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- 229930195733 hydrocarbon Natural products 0.000 description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 15
- 230000008859 change Effects 0.000 description 11
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 10
- 239000007858 starting material Substances 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000003674 animal food additive Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- 238000007323 disproportionation reaction Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 238000006276 transfer reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- -1 amines olefins Chemical class 0.000 description 3
- 235000013844 butane Nutrition 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 150000005673 monoalkenes Chemical class 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 238000007086 side reaction Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical class CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 238000003442 catalytic alkylation reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 238000010511 deprotection reaction Methods 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012526 feed medium Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1206—Hydrogen fluoride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/088,942 US5382744A (en) | 1993-07-12 | 1993-07-12 | Control of synthetic isopentane production during alkylation of amylenes |
| US8894293 | 1993-07-12 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI943297A0 FI943297A0 (fi) | 1994-07-11 |
| FI943297L FI943297L (fi) | 1995-01-13 |
| FI113166B true FI113166B (fi) | 2004-03-15 |
Family
ID=22214422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI943297A FI113166B (fi) | 1993-07-12 | 1994-07-11 | Synteettisen isopentaanin muodostumisen kontrollointi amyleenien alkyloinnin aikana |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5382744A (da) |
| EP (1) | EP0634382B1 (da) |
| JP (1) | JP2886090B2 (da) |
| KR (1) | KR100278082B1 (da) |
| AT (1) | ATE172705T1 (da) |
| AU (1) | AU659778B2 (da) |
| CA (1) | CA2122377C (da) |
| DE (1) | DE69414193T2 (da) |
| DK (1) | DK0634382T3 (da) |
| ES (1) | ES2122100T3 (da) |
| FI (1) | FI113166B (da) |
| SG (1) | SG50562A1 (da) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5583275A (en) * | 1994-08-19 | 1996-12-10 | Stratco, Inc. | Alkylation of olefins utilizing mixtures of isoparaffins |
| US5489727A (en) * | 1994-10-28 | 1996-02-06 | Phillips Petroleum Company | Isopentane disproportionation |
| US5684220A (en) * | 1995-03-23 | 1997-11-04 | Phillips Petroleum Company | Process for reducing the vapor pressure of gasoline by removing amylenes therefrom and enhancing the octane thereof |
| US5629466A (en) * | 1995-03-23 | 1997-05-13 | Phillips Petroleum Company | Method for removing amylenes from gasoline and alkylating such amylene and other olefins while minimizing synthetic isopentane production |
| US6429349B1 (en) * | 1996-08-12 | 2002-08-06 | Bp Corporation North America Inc. | Co-alkylation for gasoline RVP reduction |
| US6395945B1 (en) | 2000-03-31 | 2002-05-28 | Phillips Petroleum Company | Integrated hydroisomerization alkylation process |
| US7838708B2 (en) * | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| US20050171393A1 (en) * | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
| JP2007525477A (ja) * | 2003-07-15 | 2007-09-06 | ジーアールティー インコーポレイテッド | 炭化水素の合成 |
| US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US7674941B2 (en) * | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
| US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US7371918B2 (en) * | 2004-12-15 | 2008-05-13 | Uop Llc | Alkylation process with settler effluent recycle |
| AP2673A (en) | 2006-02-03 | 2013-05-23 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
| SG187456A1 (en) * | 2006-02-03 | 2013-02-28 | Grt Inc | Separation of light gases from halogens |
| EA017229B1 (ru) * | 2007-05-14 | 2012-10-30 | Грт, Инк. | Способ конверсии углеводородного сырья с электролитическим извлечением галогенов |
| MX2009012581A (es) | 2007-05-24 | 2010-03-15 | Grt Inc | Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible. |
| US7920027B2 (en) * | 2008-04-07 | 2011-04-05 | Qualcomm Incorporated | Amplifier design with biasing and power control aspects |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| US8273929B2 (en) * | 2008-07-18 | 2012-09-25 | Grt, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
| US20100270167A1 (en) * | 2009-04-22 | 2010-10-28 | Mcfarland Eric | Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| US10059639B2 (en) | 2016-09-02 | 2018-08-28 | Chevron U.S.A. Inc. | Alkylation of refinery pentenes with isobutane |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2403649A (en) * | 1942-01-13 | 1946-07-09 | Phillips Petroleum Co | Hydrocarbon reconstruction |
| US2662103A (en) * | 1945-12-18 | 1953-12-08 | Phillips Petroleum Co | Production of paraffins |
| US3679771A (en) * | 1970-05-12 | 1972-07-25 | Phillips Petroleum Co | Conversion of hydrocarbons |
| AU530515B2 (en) * | 1978-04-24 | 1983-07-21 | Uop Inc. | Improved hf alkylation process |
| US4262155A (en) * | 1979-07-03 | 1981-04-14 | Phillips Petroleum Company | Maximization of isoparaffin utilization in alkylation of hydrocarbons |
| US4429173A (en) * | 1982-03-09 | 1984-01-31 | Phillips Petroleum Company | Production of high-octane, unleaded motor fuel by alkylation of isobutane with isoamylenes obtained by dehydrogenation of isopentane |
-
1993
- 1993-07-12 US US08/088,942 patent/US5382744A/en not_active Expired - Lifetime
-
1994
- 1994-04-28 CA CA002122377A patent/CA2122377C/en not_active Expired - Fee Related
- 1994-07-05 AU AU66143/94A patent/AU659778B2/en not_active Ceased
- 1994-07-11 FI FI943297A patent/FI113166B/fi not_active IP Right Cessation
- 1994-07-11 KR KR1019940016669A patent/KR100278082B1/ko not_active Expired - Fee Related
- 1994-07-11 JP JP6158916A patent/JP2886090B2/ja not_active Expired - Fee Related
- 1994-07-12 EP EP94110813A patent/EP0634382B1/en not_active Expired - Lifetime
- 1994-07-12 ES ES94110813T patent/ES2122100T3/es not_active Expired - Lifetime
- 1994-07-12 AT AT94110813T patent/ATE172705T1/de not_active IP Right Cessation
- 1994-07-12 DE DE69414193T patent/DE69414193T2/de not_active Expired - Fee Related
- 1994-07-12 DK DK94110813T patent/DK0634382T3/da active
- 1994-07-12 SG SG1996005011A patent/SG50562A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2886090B2 (ja) | 1999-04-26 |
| AU659778B2 (en) | 1995-05-25 |
| EP0634382B1 (en) | 1998-10-28 |
| DE69414193D1 (de) | 1998-12-03 |
| JPH07145085A (ja) | 1995-06-06 |
| FI943297A0 (fi) | 1994-07-11 |
| ES2122100T3 (es) | 1998-12-16 |
| KR960014074A (ko) | 1996-05-22 |
| CA2122377C (en) | 1998-10-13 |
| DE69414193T2 (de) | 1999-04-01 |
| FI943297L (fi) | 1995-01-13 |
| AU6614394A (en) | 1995-01-19 |
| SG50562A1 (en) | 1998-07-20 |
| CA2122377A1 (en) | 1995-01-13 |
| EP0634382A1 (en) | 1995-01-18 |
| DK0634382T3 (da) | 1999-07-05 |
| KR100278082B1 (ko) | 2001-01-15 |
| US5382744A (en) | 1995-01-17 |
| ATE172705T1 (de) | 1998-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MA | Patent expired |